All Solutions
Page 778: Practice Problems
$$
rho_{free}=frac{2times N_A rho}{M}
$$
$$
rho_{free}=frac{2times 6.023times 10^{23}times 7.13}{65.37}=boxed{1.31times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}}
$$
rho_{free}=1.31times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}
$$
$$
rho_{free}=frac{rho N_A }{M}
$$
$$
rho_{free}=frac{6.023times 10^{23}times 10.49}{107.87}=boxed{0.59times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}}
$$
rho_{free}=0.59times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}
$$
$$
rho_{free}=1timesfrac{rho N_A }{M}
$$
$$
rho_{free}=frac{6.022times 10^{23}times 19.32}{196.97}=boxed{0.59times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}}
$$
rho_{free}=0.59times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}
$$
$$
rho_{free}=3timesfrac{rho N_A }{M}
$$
$$
rho_{free}=3timesfrac{6.022times 10^{23}times 2.7}{26.92}=boxed{1.81times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}}
$$
rho_{free}=1.81times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}
$$
$$
rho_{free}=3timesfrac{6.022times 10^{23}times 2.7}{26.92}=1.81times 10^{23}frac{textrm{e}^-}{textrm{cm}^{3}}
$$
$$
V=frac{m}{rho}=frac{2835}{2.7}=1050textrm{ cm}^3
$$
$$
N=rho_{free}times V=1.81times 10^{23}times 1050=boxed{1.9times 10^{26}textrm{ e}^-}
$$
N=1.9times 10^{26}textrm{ e}^-
$$
$$
rho_{free}=n_{atom}frac{rho N_A}{M}
$$
From where we see that
$$
n_{atom}=frac{rho_{free}M}{rho N_A}
$$
$$
n_{atom}=frac{2.25times 10^{13}times 72.6}{5.23times 6.022times 10^{23}}=boxed{5.19times 10^{-10} frac{textrm{e}^-}{textrm{atom}}}
$$
n_{atom}=5.19times 10^{-10} frac{textrm{e}^-}{textrm{atom}}
$$
$$
rho_{free}=n_{atom}frac{rho N_A}{M}
$$
From where we see that
$$
n_{atom}=frac{rho_{free}M}{rho N_A}
$$
$$
n_{atom}=frac{1.89times 10^{5}times 28.09}{2.33times 6.022times 10^{23}}=boxed{3.8times 10^{-18} frac{textrm{e}^-}{textrm{atom}}}
$$
$$
T_C=T_K-273=200-273=boxed{-73^circ textrm{ C}}
$$
n_{atom}=3.8times 10^{-18} frac{textrm{e}^-}{textrm{atom}}
$$
$$
T_C=-73^circ textrm{ C}
$$
$$
rho_{free}=n_{atom}frac{rho N_A}{M}
$$
From where we see that
$$
n_{atom}=frac{rho_{free}M}{rho N_A}
$$
$$
n_{atom}=frac{9.23times 10^{-10}times 28.09}{2.33times 6.022times 10^{23}}=boxed{1.8times 10^{-32} frac{textrm{e}^-}{textrm{atom}}}
$$
$$
T_C=T_K-273=100-273=boxed{-173^circ textrm{ C}}
$$
n_{atom}=1.8times 10^{-32} frac{textrm{e}^-}{textrm{atom}}
$$
$$
T_C=-173^circ textrm{ C}
$$
$$
rho_{free}=n_{atom}frac{rho N_A}{M}
$$
From where we see that
$$
n_{atom}=frac{rho_{free}M}{rho N_A}
$$
$$
n_{atom}=frac{1.16times 10^{10}times 72.6}{5.23times 6.022times 10^{23}}=boxed{2.7times 10^{-13} frac{textrm{e}^-}{textrm{atom}}}
$$
n_{atom}=2.7times 10^{-13} frac{textrm{e}^-}{textrm{atom}}
$$
$$
rho_{free}=n_{atom}frac{rho N_A}{M}
$$
From where we see that
$$
n_{atom}=frac{rho_{free}M}{rho N_A}
$$
$$
n_{atom}=frac{3.47times 72.6}{5.23times 6.022times 10^{23}}=boxed{8times 10^{-23} frac{textrm{e}^-}{textrm{atom}}}
$$
n_{atom}=8times 10^{-23} frac{textrm{e}^-}{textrm{atom}}
$$
$$
frac{N_{As}}{N_{Si}}=10^4times frac{N_{freeSi}}{N_{Si}}
$$
where $N_{freeSi}$ and $N_{Si}$ represent the number of silicon free electrons and atoms per a cubic centimeter, respectively.
$$
frac{N_{As}}{N_{Si}}=10^4times frac{1.45times 10^{10}}{4.99times 10^{22}}=boxed{2.9times 10^{-9}}
$$
frac{N_{As}}{N_{Si}}=2.9times 10^{-9}
$$
$$
frac{N_{As}}{N_{Ge}}=5times10^3times frac{N_{freeGe}}{N_{Ge}}=5times10^3 times n_{atom}
$$
where $N_{freeGe}$ and $N_{Ge}$ represent the number of germanium free electrons and atoms per cubic centimeter, respectively which give a ratio of the free electrons per atom.
[n_{atom}=frac{rho_{free}M}{rho N_A}=frac{2.25times 10^{13}times 72.6}{5.23times 6.022times 10^{23}}=5.19times 10^{-10} frac{textrm{e}^-}{textrm{atom}}]
$$
frac{N_{As}}{N_{Ge}}=5times 10^3times 5.19times 10^{-10}=boxed{2.6times 10^{-6}}
$$
frac{N_{As}}{N_{Ge}}=2.6times 10^{-6}
$$
$$
frac{N_{As}}{N_{Ge}}=frac{N_{freeAs}}{N_{freeGe}}times frac{N_{freeGe}}{N_{Ge}}=frac{N_{freeGe}}{N_{freeAs}}times n_{atom}
$$
where $N_{freeGe}$ and $N_{Ge}$ represent the number of germanium free electrons and atoms per cubic centimeter, respectively which give a ratio of the free electrons per atom.
$$
frac{N_{freeAs}}{N_{freeGe}}=frac{N_{Ge}}{N_{As}}times frac{1}{n_{atom}}
$$
[n_{atom}=frac{rho_{free}M}{rho N_A}=frac{1.13times 10^{15}times 72.6}{5.23times 6.022times 10^{23}}=2.62times 10^{-8} frac{textrm{e}^-}{textrm{atom}}]
[frac{N_{freeAs}}{N_{freeGe}}=frac{1}{10^6}times frac{1}{2.62times 10^{-10}}=boxed{38}]
frac{N_{freeAs}}{N_{freeGe}}=boxed{38}
$$
$$
frac{N_{As}}{N_{Si}}=frac{N_{freeAs}}{N_{freeSi}}times frac{N_{freeSi}}{N_{Si}}=frac{N_{freeSi}}{N_{freeAs}}times n_{atom}
$$
where $N_{freeSi}$ and $N_{Si}$ represent the number of silicon free electrons and atoms per cubic centimeter, respectively which give a ratio of the free electrons per atom.
$$
frac{N_{freeAs}}{N_{freeSi}}=frac{N_{Si}}{N_{As}}times frac{1}{n_{atom}}
$$
[n_{atom}=frac{rho_{free}M}{rho N_A}=frac{4.54times 10^{12}times 28.09}{2.33times 6.022times 10^{23}}=9.09times 10^{-11} frac{textrm{e}^-}{textrm{atom}}]
[frac{N_{freeAs}}{N_{freeGe}}=frac{1}{10^6}times frac{1}{9.09times 10^{-11}}=boxed{11times 10^3}]
frac{N_{freeAs}}{N_{freeGe}}=11times 10^3
$$