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Boltzmann’s definition of the entropy was a breakthrough in understanding statistical thermodynamics. What is the best definition of Boltzmann’s entropy? A) The Boltzmann entropy is a count of the accessible energy levels at a given temperature. B) The Boltzmann entropy is a measure of the randomness of an ensemble. C) The Boltzmann entropy is a count of the total distinct microstates in a system. D) The Boltzmann entropy is a measure of the useful work available in an ensemble.
C) The Boltzmann entropy is a count of the total distinct microstates in a system.
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What are the two failures of classical thermodynamics?
1. Black body radiation 2. The photoelectric effect
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Why do we spend so much time focusing on microscopic degrees of freedom when studying bulk thermodynamics? A) We can only calculate bulk thermodynamic quantities as ensemble averages over the microscopic states. B) Intermolecular forces determine the state of the material and are therefore crucial to calculating bulk thermodynamics. C) Quantum effects play an important role in determining the bulk thermodynamics of a system. D) The bulk thermodynamics is heavily dependent upon how energy is distributed among the microscopic degrees of freedom.
D) The bulk thermodynamics is heavily dependent upon how energy is distributed among the microscopic degrees of freedom.
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. Location of specific biomes can be predicted based on A. The Coriolis Effect B. The 2nd Law of Thermodynamics C. Precipitation and temperature D. Seasonal variations in sunspots E. Large landforms in the area
C. Precipitation and temperature
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2nd Law of Thermodynamics
entropy of the universe is always increasing
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The third law of thermodynamics
A perfect crystal has zero entropy at a temperature of absolute zero.
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laws of thermodynamics
The physical laws that define the basic properties and behavior of energy
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Relate the determinants of heat transfer to the 2nd law of thermodynamics.
2nd Law of Thermodynamics •Amt of heat transferred is directly proportional to temp gradient between agent & skin/ body surface •Amt of heat transferred is directly proportional to duration of application
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Write the fundamental equation of chemical thermodynamics
dG=-SdT+VdP+sum(mudni)
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What is the third law of thermodynamics?
The entropy of a perfect crystal is zero.
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