Sem. 1 Final Exam – Flashcards
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| Relatively slow rates of chemical reation are associated with which of the following? |
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| Strong bonds in reactant molecules |
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| Standard enthalpy change for Na2O + H2O= 2NaOH |
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| -150 kJ |
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| Planar configuration |
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| BCl3 |
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| N2 + 3H3= 2NH3 |
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| change in G, H, and S are negative |
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| change in H for I2 + 3Cl2= 2ICl3 |
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| -390 kJ |
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| two unshared pairs of electrons on central atom |
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| H2S |
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| Molecule with only one double bond |
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| C2H4 |
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| Molecule with the largest dipole moment |
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| H2O |
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| trigonal pyramidal geometry |
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| PH3 |
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| change in H for 3C2H2= C6H6 |
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| -607 kJ |
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| most ionic compound |
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| CaCl2 |
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| NH4SCN |
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| change in G negative, change in H and S positive |
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| most positive oxidation number |
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| SO2 |
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| compound that shows resonance |
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| SO2 |
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| PF5 does not have |
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| d2sp3 hybridization |
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| decrease in entropy |
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| formation of a crystalline solid from a supersaturated solution |
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| electrons shared by hydrogen and oxygen |
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| spend more time around oxygen |
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| decreasing bond polarity |
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| HF HCl HBr HI HAt |
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| most ionic elements |
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| CsF |
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| number of structures for NO3- |
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| 3 |
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| molecule that violates octet rule |
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| SF4 |
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| number of electrons on FCl3 |
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| 6 |
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| bond energy for CH4 + 4F2= CF4 + 4HF |
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| -1924 kJ |
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| shape of AX5 with one nonbonding pair of electrons |
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| square pyramidal |
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| shape of AX3 with two lone pairs of electrons |
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| T-shaped |
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| shapes of NH3 and BF3 |
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| trigonal pyramidal and trigonal planar |
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| molecule that is nonpolar |
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| CF4 |
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| polar molecule |
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| PCl4F |
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| square planar hybridization |
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| sp3d2 |
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| PCl5 hybridization |
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| sp3d |
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| negative change in S |
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| compressing one mole of Ne at constant temperature from .5 to 1.5 atm |
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| first law of thermodynamics |
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| energy cannot be created or destroyed but must be conserved |
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| second law of thermodynamics |
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| entropy of the universe is increasing |
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| specific heat capacity |
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| amount of energy required to raise one gram of a substance one degree Celsius |
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| heat released when 9.25 moles of Fe is reacted with oxygen |
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| -3820 kJ |
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| change in H for P4O10 + 6PCl5 =10Cl3PO |
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| -610 kJ |
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| formula for P2O5 |
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| diphosphorus pentoxide |
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| kinetic molecular theory does not say |
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| gas particles move at speeds close to the speed of light |
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| Cu65 isotope in nature |
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| 25% |
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| Average atomic or molecular speed closest to N2 molecules at 0 C and 1 Atm |
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| CO |
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| greatest density at 0 C and 1 Atm |
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| Xe |
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| Values that decrease when ideal gas is cooled by 25 degrees |
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| average distance between molecules and average speed of molecules |
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| percent of CaCO3 by mass in limestone |
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| 35% |
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| safest and most effective way to treat an acid splash on skin |
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| flush affected area with water and then with a dilute NaHCO3 |
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| moles of HI needed to produce 2.5 moles of I2 |
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| 5 |
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| why does water boil at a lower temperature on a mountain |
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| equilibrium water vapor pressure equal the atmospheric pressure at a lower temperature |
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| partial pressures of gasses |
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| He less than Ne less than Ar |
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| gas that deviates most form ideal behavior |
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| SO2 |
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| the a coefficient in van der Waals equation |
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| forces of attraction between molecules |
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| how many protons, neutrons, and electrons are in Sr-90 |
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| 38, 52, 38 |
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| Quantum numbers of ground-state gallium |
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| 4,1,1,1/2 |
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| pauli exclusion principle |
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| indicates that an atomic orbital can hold no more than two electrons |
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| dissolves in water to form a colorless solution |
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| ZnCl2 |
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| not true about halogens |
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| iodine liberates free bromine from a solution of bromide ion |
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| barium sulfate is least soluble in a .01 molar solution of what |
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| Al2(SO4)3 |
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| what color is the flame when a solution of sodium chloride is vaporized in a flame |
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| yellow |
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| use of a visible-light spectrophotometer |
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| determining the concentration of a solution of Cu(NO3)2 |
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| based on ionization energies in chart, element X is what |
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| Al |
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| what happens to atomic radius as atomic number increases from 11-17 |
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| decreases |
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| Rutherford's gold atom experiment |
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| neutrons are at the center of an atom |
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| yellow precipitate forms when NaI is added to what |
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| Pb |
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| not soluble in water but soluble in dilute hydrochloric acid |
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| Mg(OH)2 |
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| what will separate Pb from other ions |
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| dilute HCl solution |
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| contains exactly two unpaired electrons |
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| S |
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| contains only one electron in the highest occupied energy sublevel |
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| Ga |
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| purple in aqueous solution |
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| KMnO4 |
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| white and soluble in water |
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| KCl |
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| isoelectronic elements |
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| Mg, Ca, Sr |
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| greatest percentage of which compound can be recovered by cooling a saturated solution of that compound from 90 degrees C to 30 C |
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| KNO3 |
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| which property decreases across the periodic table form sodium to chlorine |
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| atomic radius |
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| why is there a different nuclear charge on Na and Ne |
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| Na has a higher neutron-to-proton ratio than Ne |
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| sodium chloride is least soluble in what |
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| CCl4 |
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| all halogens are |
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| diatomic |
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| least soluble in water |
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| BaCO3 |
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| with chart, which ions could be present in solution at a concentration of .1 M |
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| Na |
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| what pure white crystalline solid dissolves in water to yeild a base and liberate gas when acid is added to it |
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| K2CO3 |
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| mixture is made by adding AgNO3 to Na2CrO4, what does it look like |
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| yellow before, red precipitate |
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| precipitate made when AgNO3 is added to Na2CrO4 |
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| Ag2CrO4 |
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| compare Cl zero and Cl negative |
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| Cl zero atom contains fewer electrons than the Cl negative ion |
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| increasing atomic radius |
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| Na, K, Rb |
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| quantum numbers for 3d^4 |
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| 3,2,-1,1/2 |
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| greatest difference between its first and second ionization energies |
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| potassium |
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| frequency of blue light |
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| 7.5 times 10 to the 14 |
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| wavelength of sodium light |
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| 5.9 times 10 to the -7 |
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| energy of photon of red light |
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| 2.84 times 10 to the -19 |
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| ionic equation for NaCl +AgNO3= NaNO3+ AgCl |
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| Ag + Cl= AgCl |
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| insoluble in water |
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| CaCO3 |
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| soluble in water |
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| K2S |
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| precipitate formed from ammonium phosphate and calcium sulfate |
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| Ca3(PO4)2 |
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| orbital designation for an electron with n=4 and L=3 |
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| 4f |
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| electron configuration that isn't possible |
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| 1s^2 2s^2 2p^6 3s^3 3p^4 |
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| not possible configuration for an atom in excited state |
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| 1s^2 2s^2 2p^6 3s^2 3p^6 3d^10 4s^2 |
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| increasing atomic size |
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| Br, As, V, Sc, K |
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| electron affinity equation |
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| atom + electron= ion |
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| metallic elements |
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| low ionization energies |
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| formula for Hg2Cl2 |
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| mercury 1 chloride |
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| not a correct formula |
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| KCr2O7 |
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| sulfate polyatomic ion |
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| SO4 negative 2 |
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| empirical formula of CH2 and mass of 83.5 what is molecular formula |
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| C6H12 |
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| empirical formula for compound made of carbon and hydrogen that is 14.3% H |
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| CH2 |
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| gram molar mass of Al(NO3)3 |
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| 213 |
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| 2 L container will hold 4g of what |
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| CO2 |
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| 8g of N2H4 and 92g of N2O2 mixed, how much H2O is made |
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| 9 grams |
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| propane burns in excess oxygen, what is coefficient of O2 |
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| 7 |
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| volume of H2 when excess Mg is added to .4 M HCl |
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| 448 mL |
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| volume of O2 required to react with excess CS2 to make 4 L of CO2 |
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| 12 L |
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| mass of CuSO4 with water required to make .1 M copper sulfate |
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| 6.2 grams |
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| compound with 1.1 mole of K, .55 moles of Te and 1.65 moles of O |
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| K2TeO3 |
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| partial pressure of SO2 in flask |
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| 160 mmHg |
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| greatest rate of effusion through pinhole |
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| Ne |
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| mass ratio of chromium to oxygen closest to 1.6 to 1 |
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| CrO2 |
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| pressure of gas at 27 C |
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| .6 Atm |
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| change the boiling point of a liquid |
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| smaller container, more moles, higher altitude |
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| info needed to calculate molarity |
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| molar mass of sucrose |
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| formula for hydrocarbon with 1.88 density |
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| CH2 |
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| with info, density of sample is |
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| 2 grams per cm |
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| what gas effuses at half rate of NH3 |
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| Cl2 |
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| mass of Au made when .05 moles of Au2S3 is reduced with excess H2 |
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| 19.7 grams |
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| coefficient of O2 for C10H12O4S +O2= CO2 + H2O |
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| 12 |
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| what happens to gas in tank when more oxygen is added |
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| volume of gas increases |
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| empirical formula for 62.2% Hf and 37.4% Cl |
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| HfCl3 |
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| pressure of flask of NH4NO3 at 400 K |
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| 1 Atm |
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| percent water in hydrate Na2Co3 times 10H2O |
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| 63% |
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| height of column of water of barometer |
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| 33.9 |
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| object moves from moon to Earth |
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| mass will stay same and weight will increase |
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| formula for Hydrogen arsenide |
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| H3As |
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| when real gas is most like ideal gas |
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| low pressure and high temperature |
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| ideal gases |
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| have no volume or attractive forces between them |