Final Exam Chem 1211 – Flashcards
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Hydrogen Peroxide |
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H2O2 |
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Hydrogen Chloride |
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HCl |
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Sulfuric Acid |
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HNO3 |
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Acetic Acid |
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CH3COOH |
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Ammonia |
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NH3 |
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Sulfur Dioxide |
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SO2 |
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Sulfur Trioxide |
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SO3 |
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Carbon Monoxide |
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CO |
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Carbon Dioxide |
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CO2 |
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Methane |
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CH4 |
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Ethane |
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C2H6 |
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Propane |
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C3H8 |
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Butane |
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C4H10 |
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Pentane |
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C5H12 |
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Benzene |
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C6H6 |
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Methanol |
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CH3OH |
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Ethanol |
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CH3CH2OH |
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Acetone |
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CH3COCH3 |
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Ether |
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CH3CH2OCH2CH3 |
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Avagadro's number |
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6.022E23 |
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*C-->*F |
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*F=(1.8x*C)+32 |
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heat energy q= |
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q=m x c x ^T (^T=change in temp) |
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mole/volume relation |
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M1V1=M2V2 |
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Davy |
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passed electricity through compounds |
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Faraday |
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amount of reaction during electrolysis is proportional the the electrical current |
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Thompson |
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Determined e/m ratio, "discoverer of electrons" Cathode ray with positive and negative plates on either side |
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Millikan |
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Determined charge and mass of electron Container with hole, electrons drop through |
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Goldstein |
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observed canal rays |
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Geiger and Marsden |
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Shot gamma rays at piece of foil, most went straight through, some bounced back |
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Rutherford |
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analyzed Geiger and Marsden's experiment, found that atoms have very small, dense (+) centers |
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Chadwick |
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discovered neutrons |
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metallic characteristics |
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|<--- |
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Ampere |
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1A=1E-10m |
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velocity/c/wavelength(~) |
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V=c/~ |
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Energy/h/c/~ |
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E=(hc)/~ |
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Planck's constant |
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h=6.626E-34 J*s |
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how to find wavelength moving from one energy level to another |
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(1/~)=R[{1/(n1)2}-{1/(n2)2}] |
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Rydberg's constant |
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R=1.097E7 m-1 |
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speed of light through a vacuum |
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c=3.00E8 m/s |
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s orbital |
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l=0 m(l)=0 |
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p orbital |
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l=1 m(l)=-1,0,+1 |
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d orbital |
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l=2 m(l)=-2,-1,0,+1,+2 |
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f orbital |
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l=3 m(l)=-3,-2,-1,0,+1,+2,+3 |
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electron capacity of subshell |
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4(l)+2 |
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electron capacity of a shell |
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2n^2 |
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atomic radii |
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|<--- |
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first ionization energy |
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^---> except 3A<2A and 6A<5A |
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electron negativity |
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--->- ^ |
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Electronegativity-ionic/(non)polar covalent |
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^EN>1.7 ionic 0.4<^EN<1.7 polar covalent ^EN<0.4 nonpolar covalent |
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acidic |
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---> ^ |
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Strong acids |
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HCl HBr HI HNO3 H2SO4 HClO4 |
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Weak acids |
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HF CH3COOH HCN HNO2 H2CO3 H2SO3 H3PO4 (COOH)2 |
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Strong bases |
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1A oxides 2A oxides LiOH Ca(OH)2 NaOH Sr(OH)2 KOH Ba(OH)2 RbOH CsOH |
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2 ternary acids with same central nonmetal |
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hypo-stem-ous=2 lower ox -ous=1 lower ox -ic=1 higher ox per-stem-ic=2 higher ox |
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covalent bond |
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2 nonmetals |
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ionic bond |
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metal+nonmetal |
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Ternary acids |
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H+nonmetal+O |
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acid+base |
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-->salt +H2O never redox |
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Formal Charge |
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group# - (#of bonds + #unshared e-) the lewis dot structure with all closest to 0 is best |
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linear e. geo |
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AB2 nonpolar |
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trig. planar e. geo |
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AB3 nonpolar |
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tetrahedral e. geo nonpolar |
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AB4 nonpolar |
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tetrahedral e. geo polar |
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AB3U, AB3U2, UBU3 polar |
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trigonal bipyramidal e. geo |
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AB5, AB4U, AB3U2, AB2U3 nonpolar no octet rule |
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octahedral e. geo |
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AB6, AB5U, AB4U2 nonpolar |
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every double bond has... |
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1o, 1pi |
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every triple bond has... |
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1o, 2pi |
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every single bond has... |
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1o, 0pi |
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*C --> K |
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K= *C+273 |
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combined gas law |
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[(P1V1)/T1]=[(P2V2)/T2] |
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STP |
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0*C 1 atm 22.4 L |
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pressure, temperature, volume equation |
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PV=nRT |
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universal gas constant |
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R=0.0821 (Latm/molK) |
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total pressure |
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Ptot=P1+P2+P3... |
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atm to torr |
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1atm=760 torr |
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diffusion |
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mixing one substance with another |
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effuse |
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gas in container with porous walls |
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van der Waals equation |
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[P+{(n^2)a/v^2}*{V-nb)=nrt |
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exothermic |
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releases energy |
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endothermic |
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absorbs energy |
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Thermochemical standards |
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298.15 K 1 atm |
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electron affinity equation |
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x(g)+e(-) --> X(-)(g) |
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strong acid-strong base reactions equation |
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H+(aq)+OH-(aq) --> H2O(l) |