Answers on Chapter 11 Flashcards
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| how many bonds does carbon always make? |
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| four |
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| what is the exception to carbon always making four bonds? |
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| co |
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| two reasons carbon is so special: |
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| can form 4 covalent bonds and bonds with other carbon atoms in a straight chain or ring |
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| what kind of bonds do organic molecules form? |
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| covalent or polar-covalent |
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| what kind of bonds do organic molecules never form? |
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| ionic |
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| can carbon form quadrupal bonds? |
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| no, just single, double and triple |
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| other elements commonly found in organic molecules? |
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| hydrogen, nitrogen and oxygen |
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| each central atom has a specific |
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| 3-d shape |
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| what was the first synthesized organic molecule? |
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| urea |
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| who synthesized urea? |
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| frederick wohler |
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| what makes carbon able to form four equivelent bonds? |
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| hybridization |
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| what does hybridization allow carbon to do? |
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| form long chains and rings structures |
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| isomers |
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| same molecular formula different compounds |
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| why do structuralisomers have different physical properties? |
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| because they are connected in a different order |
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| another name for structural isomers? |
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| constitutional isomers |
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| functional groups |
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| structural elements with characteristic arrangement of atoms and similar chemical properties |
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| what determines the characteristics of organic molecules? |
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| functional groups |
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| three types of structural formulas? |
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| molecular, lewis structures, condensed structural formulas |
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| hydrocarbons contain only |
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| carbon and hydrogen |
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| four most simple types of hydrocarbons: |
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| alkanes, alkenes, alkynes, aromatics |
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| alkanes |
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| only single bonds |
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| alkenes |
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| at least one double bonds |
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| alkynes |
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| at least one triple bond |
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| aromatics |
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| six carbon rings |
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| alkanes only contain |
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| carbon and hydrogen |
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| what is possible if an alkane has more than three carbons |
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| constitutional isomers |
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| branches and straight chain alkanes are |
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| constitutional isomers |
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| isomers have different |
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| configurations |
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| configuration |
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| bonds must be broken to change shape |
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| conformations |
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| different structures of the same compounds |
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| can you twist a double bond? |
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| no only a single bond |
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| are conformations malleable |
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| yes, different conformations are achieved by rotating around single bonds |
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| configurations are not changeable unless |
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| bonds are broken and reformed |
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| prefixes denote |
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| the number and identity of attached groups |
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| root word denotes |
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| longest carbon chain |
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| ending denotes |
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| functional class (alkane, alkene, etc) |
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| how can main groups be modified? |
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| by the addition of substituents |
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| during modification you lose an atom but the (blank) is maintained |
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| bond |
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| first step when naming organic molecules |
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| find and name the longest contiual carbon chain |
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| the main chain is what part of the name? |
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| the root |
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| which carbon is number one? |
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| the carbon closest to a branch |
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| second step when naming organic molecules |
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| identify each substituent |
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| number each substituent according to |
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| where it is attached to the main chain |
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| if there are two or more substituents attahed to the same carbon of the main chain... |
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| they each get the same number |
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| will you find metal in organic compounds |
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| no |
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| why are alkanes saturated? |
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| the max number of carbons are attached |
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| general formula for cycloalkanes |
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| C(n) H(2n) |
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| the smallest cycloalkanes have (blank) carbons |
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| three |
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| why are three and four carbon rings strained? |
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| because the bond angles are less than 110 degrees |
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| what do you include in line structures of cyclalkanes? |
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| bonds and elements beside carbon and hydrogen |
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| how do you decide which carbon is number one on the cycloalkane? |
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| start alphabetically |
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| is free rotation possible in a cyclic compound? |
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| no |
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| two commonly seen conformations of cyclohexane |
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| chair and boat |
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| which is the more stable cycloalkane, the chair or the boat? |
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| the chair |
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| what are the bond angles in a cyclohexane? |
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| about 110 degrees |
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| because rings have fixed structures it is possible for substituents to |
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| be on different sides |
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| to distinguish whether or not the substituents are on the same side, you use these two prefixes |
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| cis and trans |
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| are alkanes polar or nonpolar |
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| nonpolar |
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| are alkanes soluble in water |
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| no |
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| alkanes density more or less than water |
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| less |
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| physical properties of alkanes |
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| colorless, tasteless |
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| are alkanes toxic |
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| no |
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| are alkanes flammable |
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| yes |
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| are alkanes reactive |
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| nor very |
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| alkane intermolecular forces are |
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| london dispersion |
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| combustion |
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| the rapid reaction of another compound with oxygen that produces heat and light |
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| the products of combustion are always |
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| water and carbon dioxide |
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| hybrid orbital |
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| a combination of the 2s and 2p orbitals that allows carbon to make four bonds that are equivelent |
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| structural formulas show all |
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| covalent bonds |
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| what are the simplest of all organic compounds? |
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| hydrocarbons |
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| another word for saturated hydrocarbons |
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| alkanes |
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| three types of unsaturated hydrocardbons |
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| alkenes, alkynes, and aromatics |
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| what kind of hydrocarbons are not common in the human body? |
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| alkanes |
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| general formula for alkanes |
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| C(2)H(2n+2) |
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| what is the simplest alkane |
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| methane |
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| what are the bond angles of a tetrahedral? |
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| 110 degrees |
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| two types of alkanes |
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| normal and branched |
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| what does the prefix n mean? |
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| indicates that all carbons form an unbranched chain |
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| alkyl groups |
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| a collection of atoms that can be thought of as an alkane minus one hydrogen atom |
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| why do alkanes have a lower melting and boiling point than other organic molecules |
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| because they have very weak nonpolar bonds |
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| homologous series |
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| any series of compounds in which each member differs from the previous member only be having an additional CH2 unit |
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| dispersion forces increase as (blank) increases |
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| molecular weight |
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| one to four carbons |
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| gas |
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| five to twenty carbons |
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| liquid |
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| more than twenty carbons |
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| waxy solid |
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| what are the least reactive of all organic compounds? |
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| alkanes |
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| what are the products of incomplete combustion |
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| co and c |
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| what causes incomplete combustion |
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| lack of oxygen |