Answers on Chapter 11 Flashcards
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how many bonds does carbon always make? |
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four |
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what is the exception to carbon always making four bonds? |
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co |
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two reasons carbon is so special: |
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can form 4 covalent bonds and bonds with other carbon atoms in a straight chain or ring |
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what kind of bonds do organic molecules form? |
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covalent or polar-covalent |
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what kind of bonds do organic molecules never form? |
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ionic |
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can carbon form quadrupal bonds? |
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no, just single, double and triple |
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other elements commonly found in organic molecules? |
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hydrogen, nitrogen and oxygen |
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each central atom has a specific |
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3-d shape |
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what was the first synthesized organic molecule? |
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urea |
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who synthesized urea? |
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frederick wohler |
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what makes carbon able to form four equivelent bonds? |
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hybridization |
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what does hybridization allow carbon to do? |
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form long chains and rings structures |
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isomers |
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same molecular formula different compounds |
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why do structuralisomers have different physical properties? |
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because they are connected in a different order |
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another name for structural isomers? |
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constitutional isomers |
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functional groups |
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structural elements with characteristic arrangement of atoms and similar chemical properties |
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what determines the characteristics of organic molecules? |
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functional groups |
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three types of structural formulas? |
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molecular, lewis structures, condensed structural formulas |
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hydrocarbons contain only |
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carbon and hydrogen |
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four most simple types of hydrocarbons: |
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alkanes, alkenes, alkynes, aromatics |
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alkanes |
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only single bonds |
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alkenes |
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at least one double bonds |
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alkynes |
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at least one triple bond |
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aromatics |
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six carbon rings |
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alkanes only contain |
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carbon and hydrogen |
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what is possible if an alkane has more than three carbons |
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constitutional isomers |
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branches and straight chain alkanes are |
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constitutional isomers |
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isomers have different |
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configurations |
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configuration |
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bonds must be broken to change shape |
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conformations |
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different structures of the same compounds |
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can you twist a double bond? |
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no only a single bond |
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are conformations malleable |
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yes, different conformations are achieved by rotating around single bonds |
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configurations are not changeable unless |
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bonds are broken and reformed |
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prefixes denote |
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the number and identity of attached groups |
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root word denotes |
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longest carbon chain |
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ending denotes |
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functional class (alkane, alkene, etc) |
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how can main groups be modified? |
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by the addition of substituents |
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during modification you lose an atom but the (blank) is maintained |
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bond |
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first step when naming organic molecules |
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find and name the longest contiual carbon chain |
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the main chain is what part of the name? |
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the root |
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which carbon is number one? |
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the carbon closest to a branch |
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second step when naming organic molecules |
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identify each substituent |
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number each substituent according to |
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where it is attached to the main chain |
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if there are two or more substituents attahed to the same carbon of the main chain... |
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they each get the same number |
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will you find metal in organic compounds |
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no |
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why are alkanes saturated? |
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the max number of carbons are attached |
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general formula for cycloalkanes |
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C(n) H(2n) |
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the smallest cycloalkanes have (blank) carbons |
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three |
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why are three and four carbon rings strained? |
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because the bond angles are less than 110 degrees |
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what do you include in line structures of cyclalkanes? |
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bonds and elements beside carbon and hydrogen |
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how do you decide which carbon is number one on the cycloalkane? |
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start alphabetically |
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is free rotation possible in a cyclic compound? |
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no |
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two commonly seen conformations of cyclohexane |
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chair and boat |
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which is the more stable cycloalkane, the chair or the boat? |
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the chair |
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what are the bond angles in a cyclohexane? |
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about 110 degrees |
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because rings have fixed structures it is possible for substituents to |
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be on different sides |
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to distinguish whether or not the substituents are on the same side, you use these two prefixes |
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cis and trans |
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are alkanes polar or nonpolar |
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nonpolar |
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are alkanes soluble in water |
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no |
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alkanes density more or less than water |
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less |
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physical properties of alkanes |
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colorless, tasteless |
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are alkanes toxic |
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no |
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are alkanes flammable |
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yes |
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are alkanes reactive |
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nor very |
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alkane intermolecular forces are |
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london dispersion |
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combustion |
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the rapid reaction of another compound with oxygen that produces heat and light |
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the products of combustion are always |
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water and carbon dioxide |
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hybrid orbital |
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a combination of the 2s and 2p orbitals that allows carbon to make four bonds that are equivelent |
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structural formulas show all |
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covalent bonds |
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what are the simplest of all organic compounds? |
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hydrocarbons |
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another word for saturated hydrocarbons |
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alkanes |
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three types of unsaturated hydrocardbons |
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alkenes, alkynes, and aromatics |
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what kind of hydrocarbons are not common in the human body? |
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alkanes |
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general formula for alkanes |
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C(2)H(2n+2) |
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what is the simplest alkane |
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methane |
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what are the bond angles of a tetrahedral? |
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110 degrees |
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two types of alkanes |
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normal and branched |
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what does the prefix n mean? |
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indicates that all carbons form an unbranched chain |
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alkyl groups |
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a collection of atoms that can be thought of as an alkane minus one hydrogen atom |
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why do alkanes have a lower melting and boiling point than other organic molecules |
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because they have very weak nonpolar bonds |
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homologous series |
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any series of compounds in which each member differs from the previous member only be having an additional CH2 unit |
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dispersion forces increase as (blank) increases |
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molecular weight |
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one to four carbons |
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gas |
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five to twenty carbons |
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liquid |
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more than twenty carbons |
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waxy solid |
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what are the least reactive of all organic compounds? |
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alkanes |
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what are the products of incomplete combustion |
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co and c |
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what causes incomplete combustion |
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lack of oxygen |