Energy & Environment – Flashcards

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World Energy use (2009)
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500 quadrillion
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Predicted world energy use (2030)
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678 quadrillion btu
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Refrigerant naming
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number is: C-1, H+1, F. Openings are filled with Cl.

Alternatively, add 90 to number and the resulting # is C-H-F.
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Methyl Isocyanate (MIC)
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CH3-N=C=O
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trans1234ze
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[image]
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Henry's Law
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yi*P = xi*Hi,w

use near infinite dilution
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Raoult's Law
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yi*P = xi*Pi,sat
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Energy costs per kWhr
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nuclear < coal < natural gas = wind < solar
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How much of US energy comes from:

Petroleum?
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39%
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How much of US energy comes from:

Natural gas?
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23%
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How much of US energy comes from:

Coal?
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22%
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How much of US energy comes from:

Nuclear
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8%
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How much of US energy comes from:

Renewable?
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8%
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Halon-1211
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CBrClF2
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Montreal Protocol
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Banned CFC's. Restrict & eventually ban other molecules with high ODP (HCFC's).
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1234yf
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[image]
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Toxicology
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no harmless substances, only harmless ways of using substances
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Entry Routes for toxicants
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Ingestion, inhalation, injection, dermal absorption
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Exit routes for toxicants
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excretion, detoxification, storage
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TLV
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Threshold limit value:

concentrations at which no adverse affects are expected during a worker's lifetime (max. allowable concentration)
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TLV-TWA
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TLV- Time Weighted Average:

allowable exposure if workers is exposed 8hrs/day
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TLV-STEL
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TLV-Short Term Exposure Limit:

max. concentration to which workers can be exposed to for 15 minutes continuously.
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TLV-C
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TLV-Ceiling: Should never be exceeded
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PEL
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Permissible Exposure Level:

OSHA's threshold dose
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IDLH
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Immediately Dangerous to Life & Health
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NOAEL
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No Observed Adverse Effect Level
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individual risk =
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exposure*slopefactor/(weight of person)
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# of cases =
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individual risk*exposed population
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PCB
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http://upload.wikimedia.org/wikipedia/commons/4/49/Polychlorinated_biphenyl_structure.svg
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OSHA
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Occupational Safety and Health Administration:

Hazard education, inspections
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ACGIH
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American Conference of Governmental Industrial Hygienists
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Chemicals on the CAA
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CO, Pb, NO2, O3, PM10, PM25, SO2
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PM10 or PM25
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Particulate Matter
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NPDES
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National Pollutant Discharge Elimination System:

CWA permit program
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POTW
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Publicly Owned Treatment Works:

CWA construction program
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Hazardous waste is:...
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ignitable, corrosive, reactive, or toxic
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NPL
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National Priority List

Used for the Superfund (CERCLA)
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PRP
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Potentially Responsible Party:

This relates to the Superfund (CERCLA)
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bioaccumulation potential
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log(Kow)
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high bioaccumulation potential
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log(Kow)>=8
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Low bioaccumulation potential
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log(Kow)<=3.5
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TSCA
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Toxic Substances Control Act:

Toxic inventory
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PMN
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Pre-manufacturing Notice:

required for TSCA
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FIFRA
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FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT:

Key purpose is to asses risk and control usage of pesticides
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NAAQS
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National Ambient Air Quality Standards:

CAA standards
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SIP
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state implementation plan:

plan to implement CAA
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NSPS
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New Source Performance Standards:

More restrictions placed on new sources per CAA
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HAP
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Hazardous Air Pollutant:

CAA
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MACT
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Max. Achievable Degree of Control (technology):

CAA requires the best technology to be used to cut emissions
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BACT
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Best Available Control Technology:

CWA pretreatment standards require this for discharge
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RCRA
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Resource Conservation & Recovery Act:

"cradle to grave"
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TSDF
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treatment, storage and disposal facilities:

RCRA - last resort
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CERCLA
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COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT:

Love canal - superfund
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SARA
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Superfund Amendments & Reauthorization Act:

CERLCA got more money
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EPCRA
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The Emergency Planning and Community Right to Know Act:

develop plan to clean accident & inform public
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TRI
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Toxic Release Inventory:

EPCRA requires emitters to report to EPA
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PPA
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Pollution Prevention Act:

Source Reduction, recycle, treat, disposal, release
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EISA
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Energy Independence and Security Act:

energy efficiency & alternative energy research funding
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Vadose Zone
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unsaturated zone
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aquifer
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has ground water flow
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LNAPL
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Light non-aqueous phase liquid:

less dense than water
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DNAPL
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Dense non-aqueous phase liquid:

more dense than water
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Sorption
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remediation technique - using granular activated carbon to absorb
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SVE
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Soil Vapor extraction:

for remediation
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AS
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air sparging:

pump air into ground water so chemical bubbles up
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bioventing
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pumping air into the ground
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Most abundant U
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U-238
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U used for nuclear energy
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U-235
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% of U-235 needed for commercial nuclear fuel
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3-5%
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