Energy & Environment – Flashcards
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World Energy use (2009) |
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500 quadrillion |
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Predicted world energy use (2030) |
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678 quadrillion btu |
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Refrigerant naming |
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number is: C-1, H+1, F. Openings are filled with Cl. Alternatively, add 90 to number and the resulting # is C-H-F. |
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Methyl Isocyanate (MIC) |
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CH3-N=C=O |
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trans1234ze |
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[image] |
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Henry's Law |
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yi*P = xi*Hi,w use near infinite dilution |
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Raoult's Law |
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yi*P = xi*Pi,sat |
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Energy costs per kWhr |
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nuclear < coal < natural gas = wind < solar |
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How much of US energy comes from: Petroleum? |
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39% |
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How much of US energy comes from: Natural gas? |
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23% |
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How much of US energy comes from: Coal? |
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22% |
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How much of US energy comes from: Nuclear |
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8% |
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How much of US energy comes from: Renewable? |
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8% |
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Halon-1211 |
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CBrClF2 |
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Montreal Protocol |
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Banned CFC's. Restrict & eventually ban other molecules with high ODP (HCFC's). |
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1234yf |
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[image] |
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Toxicology |
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no harmless substances, only harmless ways of using substances |
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Entry Routes for toxicants |
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Ingestion, inhalation, injection, dermal absorption |
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Exit routes for toxicants |
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excretion, detoxification, storage |
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TLV |
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Threshold limit value: concentrations at which no adverse affects are expected during a worker's lifetime (max. allowable concentration) |
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TLV-TWA |
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TLV- Time Weighted Average: allowable exposure if workers is exposed 8hrs/day |
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TLV-STEL |
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TLV-Short Term Exposure Limit: max. concentration to which workers can be exposed to for 15 minutes continuously. |
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TLV-C |
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TLV-Ceiling: Should never be exceeded |
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PEL |
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Permissible Exposure Level: OSHA's threshold dose |
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IDLH |
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Immediately Dangerous to Life & Health |
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NOAEL |
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No Observed Adverse Effect Level |
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individual risk = |
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exposure*slopefactor/(weight of person) |
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# of cases = |
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individual risk*exposed population |
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PCB |
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http://upload.wikimedia.org/wikipedia/commons/4/49/Polychlorinated_biphenyl_structure.svg |
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OSHA |
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Occupational Safety and Health Administration: Hazard education, inspections |
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ACGIH |
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American Conference of Governmental Industrial Hygienists |
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Chemicals on the CAA |
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CO, Pb, NO2, O3, PM10, PM25, SO2 |
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PM10 or PM25 |
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Particulate Matter |
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NPDES |
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National Pollutant Discharge Elimination System: CWA permit program |
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POTW |
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Publicly Owned Treatment Works: CWA construction program |
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Hazardous waste is:... |
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ignitable, corrosive, reactive, or toxic |
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NPL |
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National Priority List Used for the Superfund (CERCLA) |
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PRP |
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Potentially Responsible Party: This relates to the Superfund (CERCLA) |
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bioaccumulation potential |
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log(Kow) |
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high bioaccumulation potential |
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log(Kow)>=8 |
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Low bioaccumulation potential |
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log(Kow)<=3.5 |
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TSCA |
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Toxic Substances Control Act: Toxic inventory |
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PMN |
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Pre-manufacturing Notice: required for TSCA |
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FIFRA |
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FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT: Key purpose is to asses risk and control usage of pesticides |
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NAAQS |
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National Ambient Air Quality Standards: CAA standards |
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SIP |
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state implementation plan: plan to implement CAA |
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NSPS |
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New Source Performance Standards: More restrictions placed on new sources per CAA |
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HAP |
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Hazardous Air Pollutant: CAA |
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MACT |
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Max. Achievable Degree of Control (technology): CAA requires the best technology to be used to cut emissions |
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BACT |
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Best Available Control Technology: CWA pretreatment standards require this for discharge |
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RCRA |
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Resource Conservation & Recovery Act: "cradle to grave" |
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TSDF |
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treatment, storage and disposal facilities: RCRA - last resort |
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CERCLA |
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COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT: Love canal - superfund |
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SARA |
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Superfund Amendments & Reauthorization Act: CERLCA got more money |
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EPCRA |
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The Emergency Planning and Community Right to Know Act: develop plan to clean accident & inform public |
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TRI |
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Toxic Release Inventory: EPCRA requires emitters to report to EPA |
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PPA |
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Pollution Prevention Act: Source Reduction, recycle, treat, disposal, release |
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EISA |
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Energy Independence and Security Act: energy efficiency & alternative energy research funding |
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Vadose Zone |
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unsaturated zone |
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aquifer |
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has ground water flow |
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LNAPL |
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Light non-aqueous phase liquid: less dense than water |
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DNAPL |
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Dense non-aqueous phase liquid: more dense than water |
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Sorption |
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remediation technique - using granular activated carbon to absorb |
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SVE |
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Soil Vapor extraction: for remediation |
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AS |
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air sparging: pump air into ground water so chemical bubbles up |
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bioventing |
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pumping air into the ground |
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Most abundant U |
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U-238 |
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U used for nuclear energy |
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U-235 |
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% of U-235 needed for commercial nuclear fuel |
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3-5% |