CHM Final UCF – Flashcards

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Change of State
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-no change in bonding
-solid to liquid to gas, etc
(ice melts, liquid boils)
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Bond formation releases/takes energy?
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Bond formation = releases energy
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Law of Mass Conservation
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In a chemical process, mass is neither created nor destroyed
(mass of reactants = mass of products)
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Chemical Change
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-bonds are broken & rearranged
-molecular idenity is changed
(Na+CL -> NaCl)
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Bond breaking releases/takes energy?
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Bond breaking = takes energy
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Exothermic reaction
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releases energy into the environment
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Endothermic
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Reaction takes in energy from the environment
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Electronegativity
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The ability of an atom to pull electrons from other atoms.
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Covalent Bond
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equal share of electrons
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Polar Covalent Bond
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-unequal sharing of electrons
-when atoms that differ significantly in electronegativity share electrons
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Ionic Bond
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an electron is transferred (electric force of attraction between two oppositely charged ions)
-formed between non-metallic & metallic elements
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Dipole Moment
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a measure of the polarity in a chemical bond or molecule, equal to the product of one charge and the distance between the charges
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Polar Bond/Polar molecule
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a chemical bond or molecule that has a dipole
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For molecules w. B, Si, Ge, & C as the central atom:
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-if atoms bonded to central atom are identical = non-polar
-if bonded atoms are not identical & at least one is from group 15,16, or 17 = polar molecule
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For neutral molecules w. N, P, As, O, S, & Se as central atom:
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Polar molecules
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Avogadro's Constant
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6.02x10^23
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Molar Mass
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grams/mole?
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Positive Entropy Change
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-going from a solid or liquid or gaseous product
-increase # of product molecules vs. # of reactant molecules
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Negative Entropy Change
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-going from a liquid or gas to a solid product
-decrease in # of product molecules
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What accepts protons?
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Base
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What donates protons?
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Acids
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pH=
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-log[H30+]
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Amphoteric Substance
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substance whose ability to act as an acid is about the same as it's ability to act as a base
EX = water
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Neralization Reaction
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the reaction between an acid & base
-strong acid + weak base
-weak acid + strong base
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What is the oxidation state of S in Na2SO4?
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+6
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Allotrope
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A structurally differentiated form of an element
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Hydrocarbon
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simplest organic compound (contains only hydrogen & carbon)
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Configuration
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specific way in which the atoms of a molecule are connected to each other
(configuration = connection)
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Conformation
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same connectivity, but bonds have been rotated
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Hydrocarbon Functional Group
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Methyl, Ethyl, Propyl, & Butyl
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Monomer & Polymer
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monomers join together to form a polymer
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Addition polymerization
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-monomers have double bond
-formula mass = sum of monomers
-name often ends in -ene (indicating presence of double bond in monomer)
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Condensation polymerization
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-monomer unit join there is a loss of a small molecule (often water)
-formula mass = less than sum of monomers
-name of polymer often gives a clue that is formed by a condensation reaction
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Vulcanization
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disulfide cross-links, stretched w. great tendency to snap back
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Heteroatom Functional Groups
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=combo of atoms that behave as a singl unit containing at least one atom that is not C or H
-add mass
-create polar bonds
-provide sites for intermolecular interation (hydrogen bonding & reaction)
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Carbohydrates
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-body converts carbs into glucose
=polymers of sugars (glucose)
-main energy source
-excess is stored as glycogen
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Carbohydrate Metabolism
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Carbohydrate metabolism denotes the various biochemical processes responsible for the formation, breakdown and interconversion of carbohydrates in living organisms.
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Glycemic Index
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1.A system that ranks foods on a scale from 1 to 100 based on their effect on blood-sugar levels
-HI GI = break down carbs fast
-LOW GI = break down carbs & release glucose into bloodstream slowly
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Transfats
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=fatty acids w/trans double bonds
-not recognized b normal processing mechanisms in body
-remain in bloodstream longer
-more prone to arterial deposit
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Fat Metabolism
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a metabolic process that breaks down ingested fats into fatty acids and glycerol and then into simpler compounds that can be used by cells of the body
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Low-Density Lipoproteins
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"bad cholesterol"
-forms plaque & gets clots
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High-Density Lipoproteins
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"good cholesterol"
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Omega-3 Fatty Acids
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-protective of heart health
-impede VLSL sythnethis in liver
-render LDL particles larger and less sticky
-stabilize plaue formations
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Problem w/ Partially-Hydrogenated Oils
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carbon-carbon double bonds rearrange into "trans" form
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Polypeptide
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amino acids linked together in a chain forming a protein
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Restriction Enzyme
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can cut both strands of DNA
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Genetic Engineering
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-production of human proteins in bacteria
In future: treatment for cancer & diseases, trasnplants & graphs from genetically motified animals, help agriculture by shortening time to evolve improved traits, improve productivity & cut time
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Polymers of Amindo Acids
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Proteins, Enzymes, & Hormones
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Scientific Method
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Observations, Questions, Hypothesis, Predictions, Tests
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Scienfitic Law
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Concise summary of data, generalizes specific observations
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Sceintific Theory
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Explanation of why a Law exists
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Confidence grows
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based on consistency of observations made by independent groups
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Diatomic Molecules
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H,N,O,F,Cl,Br,I,At
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structural isomer
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same molecular formula, different structures
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hydrocarbons come from
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fossil fuels
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