Chemistry EOC Study Guide PREP – Flashcards
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scientific method
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a logical, systematic approach to the solution of a scientific problem
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steps of the scientific method
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1. Define the problem 2. Research the problem 3. Form a hypothesis 4. Perform an experiment (Test hypothesis) 5. Analyze data 6. Communicate results
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independent variable
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variable that is manipulated
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dependent variable
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the factor that is being measured or controlled during the experiment
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scientific theory
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a hypothesis that is supported by experimental evidence over a long period of time
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scientific law
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a concise statement that summarizes the results of many observations and experiments
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extensive properties
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a property that depends on the amount of matter
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mass
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the amount of matter that an object contains
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volume
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the amount of space occupied by an object
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solid
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a form of matter that has a definite shape and volume
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liquid
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a form of matter that has a definite volume, but not a definite shape
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gas
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a form of matter that does not have a definite shape or volume
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physical change
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a process where some properties of a material change, but the composition of the material stays the same
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reversible
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usually when matter changes states such as from a solid to a liquid the change can be reversed
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irreversible
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usually when matter changes so that it cannot be reversed, ex: cutting or cracking an egg
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mixture
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a physical blend of two or more components
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heterogeneous mixture
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a mixture that is not uniform in composition, ex: chicken noodle soup
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homogeneous mixture
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a mixture in which the composition is uniform (also called a solution), ex: vinegar, oil
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filtration
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a process that separates a solid from a liquid in a heterogeneous mixture, ex: colander separating water from pasta
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distillation
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boiling liquid to produce a vapor then condensing the liquid to separate a homogeneous mixture, ex: removing salt from salt water
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element
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the simplest form of matter that has a unique set of properties
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compound
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a substance that contains two or more elements chemically combined in a fixed proportion
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chemical change
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a change that produces matter with a different composition than the original matter
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chemical property
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the ability of a substance to undergo a specific chemical change
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chemical reaction
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a process that involves the rearrangement of the molecular or ionic structure of a substance as opposed to a change in a physical form or a nuclear reaction
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ways to recognize chemical changes
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1. Transfer of energy 2. A change in color 3. The production of a gas 4. The formation of a precipitate
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precipitate
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a solid that forms and settles out of a liquid mixture
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Law of Conservation of Mass
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states that in any physical change or chemical reaction mass is conserved, mass is neither created nor destroyed
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During any chemical reaction the mass of the products is ALWAYS equal to the mass of the reactants.
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true
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measurement
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is a quantity that has both a number and a unit, a fundamental process to the experimental sciences
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scientific notation
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a given number is written as the product of two numbers: a coefficient and a 10 raised to a power, ex: 602,000,000,000,000,000,000,000 = 6.02 x 10^23
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accepted value
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the correct value based on reliable references
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experimental value
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the value measured in the lab
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error
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the difference between the accepted value and the experimental value , error = experimental value - accepted value
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percent error
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the absolute value of the error divided by the accepted value, multiplied by 100%, percent error = error/accepted value x 100%
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significant figures
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all of the digits that are known, plus the last digit that is estimated
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rules for significant figures
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1. Every non zero digit is considered significant, ex: 1,2,3 2. Zeroes occurring between non zero digits are significant, ex: 101 = 3 significant digits 3. Leftmost zeroes occurring to the left of non zero digits are NOT significant, ex: 0.0021 has 2 significant digits 4. Zeroes at the end of a number and RIGHT of a decimal point are significant, ex: 43.00 has 4 significant figures 5. Zeroes at the rightmost end of a measurement that lie to the LEFT of a decimal point are not significant, ex: 7000 has one significant figure
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International System of Units (SI)
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a revised version of the metric system, adopted by the international community in 1960
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most common units used by chemists
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1. Meter(m)- length 2. Kilogram(kg)- mass 3. Kelvin(K)- temperature 4. Second(s)- time 5. Mole(mol)- amount of substance 6. Liter(L)- volume of a substance 7. Joule(J)- unit of energy
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commonly used prefixes
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Mega(M)- 1 million times larger Deci(d)- 10 times smaller Kilo(k)- 1000 times larger Centi(c)- 100 times smaller Hecto(h)- 100 times larger Milli(m)- 1000 times smaller Deka(da)- 10 times larger Micro - 1 mil times smaller
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weight
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a force that measures the pull on on a given mass by gravity
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common metric units of volume
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liter, milliliter, cubic centimeter (cm3) and microliter, one cubic centimeter = 1 milliliter
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Celsius scale
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sets the freezing temperature of water at 0 and boiling temperature at 100, Celsius = Kelvin - 273
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Kelvin scale
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does NOT use degrees and sets 0 at absolute zero which is equal to -273.15 Celsius, Kelvin = Celsius + 273
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energy
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the capacity to do work or to produce heat, measured in joule (J), 1 joule = 0.2390 cal
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calorie
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the quantity of heat that raises the temperature of 1 g of pure water by 1 degree Celsius, 1 calorie = 4.184 J
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conversion factor
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a ratio of equivalent measurements ex. 100cm/1m or 1m/100cm
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dimensional analysis
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is a way to analyze and solve problems using the units, or dimension, of the measurements
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density
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ratio of the mass of an object to its volume, density= mass/volume
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atom
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the smallest particle of an element that retains its identity in a chemical reaction
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Democritus
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believed that atoms were indivisible and indestructible
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Dalton's Atomic Theory
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1. States all elements are composed of tiny indivisible particles called atoms 2. Atoms of the same element are identical. Atoms from one element are different from atoms from another element 3. Atoms of different elements can physically mix together or can chemically combine in simple whole-number ratios to form compounds 4. Chemical reactions occur when atoms are separated, joined, or rearranged. Atoms of one element, however, are never changed into atoms of another element as a result of a chemical reaction
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subatomic particles
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atoms can be broken down into smaller objects, which are called subatomic particles
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three types of subatomic particles
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proton, neutron, electron
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Cathode Ray Experiment
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In 1897 J.J Thompson passed electric currents through gasses at low pressure. He sealed gas in a tube and used oppositely charged electrodes that produced a glowing beam that traveled from one end to the other. This led to the discovery of the electron
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Rutherford's Gold Foil Experiment
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1911; Fired alpha particles (Helium atoms without electrons) into a sheet of gold foil, most of the alpha particles went straight through, some deflected at large angles, led to the discovery of the nucleus
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relative atomic mass
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? since the actual mass of an atom is so small we use relative atomic mass which is seen on the periodic table ? since hydrogen is the smallest atom (having a mass of 8.275 x 10^-25) we say that hydrogen has a relative atomic mass of 1 ? example: carbon has a mass 12 times larger than hydrogen, therefore, it has a relative mass of 12
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atomic mass
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? Atomic mass is based on a Carbon-12 isotope. ? An atomic mass unit (amu) is used to describe the mass of an atom ? An atomic mass unit (amu) is defined as one twelfth of the mass of a carbon-12 atom.
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neutron
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subatomic particles with no charge that are located in the nucleus of an atom, discovered by Chadwick in 1932
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Thompson's Theory
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Thompson's theory that subatomic particles were evenly distributed throughout the nucleus of an atom, later proven to be inncorrect
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proton
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positively charged subatomic particles, that are located in the nucleus of an atom, discovered by Goldstein in 1886
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atomic model
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states that the nucleus is the central core of an atom and is composed of protons and neutrons. The electrons are distributed around the nucleus and occupy almost all of the volume of an atom, improved the plum pudding model but was still incomplete
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isotope
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atoms that have the same number of protons but a different number of neutrons, since isotopes will have a differing number of neutrons, their mass will be different as well
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periodic table of elements
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an arrangement of elements in which the elements are separated into groups based on a set of repeating properties ? each horizontal row is called a period ? each vertical row is called a group or family
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Dalton's Model
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John Dalton proposed that all matter is composed of very small things which he called atoms. This was not a completely new concept as the ancient Greeks (notably Democritus) had proposed that all matter is composed of small, indivisible (cannot be divided) objects. When Dalton proposed his model, electrons and the nucleus were unknown.
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Thompson's "Plum Pudding" Model
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The electron was discovered by J.J. Thomson in 1897. However, the atomic nucleus had not been discovered yet and so the "plum pudding model" was put forward in 1904. In this model, the atom is made up of negative electrons that float in a "soup" of positive charge. However, even with the Plum Pudding Model, there was still no understanding of how these electrons in the atom were arranged.
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Rutherford's Model
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His new model described the atom as a tiny, dense, positively charged core called a nucleus surrounded by lighter, negatively charged electrons. A simplified picture of this is shown alongside. This model is sometimes known as the planetary model of the atom.
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Bohr's Model
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There were, however, some problems with Rutherford's model: for example it could not explain the very interesting observation that atoms only emit light at certain wavelengths or frequencies. Niels Bohr solved this problem by proposing that the electrons could only orbit the nucleus in certain special orbits at different energy levels around the nucleus.
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James Chadwick
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James Chadwick discovered the neutron in 1932.
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Quantum Mechanical Model
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The Quantum Mechanical Model determines the allowed energies an electron can have and how likely it is to find the electron in various locations around the nucleus.
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atomic orbitals
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? a region of space in which there is a high ? ? ? probability of finding an electron ? each energy sublevel corresponds to an orbital of a different shape, which describes where the electron is likely to be found ? three sublevels: s,d,p,f S- spherical P- dumbbell shaped D- cloverleaf shaped F- more complicated "D" orbital
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electron configuration
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the way in which electrons are arranged into various orbitals around the nuclei of atoms
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rules to find electron configuration (there are exceptions)
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1. Aufbau Principle 2. Pauli Exclusion Principle 3. Hund's Rule
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Aufbau Principle
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electrons occupy the orbitals of lowest energy first
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Pauli Exclusion Principle
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an atomic orbital may contain at most two electrons (must have opposite spins)
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Hund's Rule
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states that each orbital must have at least one electron with the same spin before being able to move on to the next orbital
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amplitude
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the height of a wave
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wavelength
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the distance between the crests (peaks)
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frequency
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the number of wave cycles to pass a given point per unit of time (cycles per second), the SI unit of frequency is the hertz
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frequency vs. wavelength
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the frequency and wavelength of light are inversely proportional to each other
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energy vs. frequency
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energy and frequency are directly related
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electromagnetic wave speed
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all electromagnetic waves travel in a vacuum at a speed of 2.998 x 10^8 m/s
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speed of light formula
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speed of light (c) = frequency (v) x wavelength (?)
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electromagnetic radiation
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includes radio waves, microwaves, visible light, ultraviolet waves, x-rays, and gamma rays.
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spectrum
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range of wavelengths of electromagnetic radiation (red has the longest wavelength and longest frequency, violet has the shortest wavelength and shortest frequency)
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electron absorption
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atoms absorb energy that raises electrons into higher energy levels and then lose the energy by emitting light when electrons return to lower energy levels
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atomic emission spectrum
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the pattern formed when light passes through a prism or diffraction grating to separate it into the different frequencies of light it contains, useful in identifying elements (ex. what stars are made of) (No two elements have the same emission spectrum)
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ground state
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lowest possible energy of the electron, quantum number (n) = 1, a quantum of light in the form of light is emitted when the electron drops from a higher energy level to a lower energy level
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Heisenberg Uncertainty Principle
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states that it is impossible to know exactly both the velocity and the position of a particle at the same time
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Dmitri Mendeleev
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published the first version of what is now known as the periodic table in order of increasing atomic mass
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Henry Moseley
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assigned atomic numbers to the elements and the periodic table was reordered into increasing atomic number in 1913
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Periodic Law
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when elements are arranged in order of increasing atomic number, there is a periodic repetition of their physical and chemical properties
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reactivity of metals
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metals are more reactive on the left side of the periodic table, metals are more reactive towards the bottom of the periodic table
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reactivity of nonmetals
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nonmetals are more less reactive on the left side of the periodic table, nonmetals are more reactive towards the top of the periodic table
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metals
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good conductors of heat and electric current, make up 80% of all elements
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nonmetals
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poor conductors of heat and electric current (carbon is an exception)
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metalloids
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properties of both metals and nonmetals
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alkali metals
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very reactive, group 1A on the periodic table of elements
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alkaline earth metals
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reactive, group 2A on the periodic table
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grouping based on electron configuration
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elements can be sorted into noble gases, representative elements, transition elements, or inner transition metals based on electron configuration
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noble gas
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not very reactive at all, elements in group 8A of the periodic table
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representative elements
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groups 1A and 7A because they display a wide range of physical and chemical properties
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transition metal
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one of the group B elements where the s sublevel and d sublevel contain electrons
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inner transition metal
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highest s sublevel and a f sublevel are occupied by electrons
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trends in atomic size
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increases to the right and down the periodic table, the atomic size of an element will increase with the atomic number Cations are always smaller than the atoms from which they form (they lose electrons, of course they are going to be smaller) Anions are always larger than the atoms from which they form (they gain electron, therefore, they will be larger)
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atomic radius
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one half of the distance between the nuclei of two atoms of the same element with the atoms are joined
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ions
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an atom or a group of atoms with a positive or negative charge, form when electrons are transferred between atoms
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cation
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ion with a positive charge, atoms that tend to lose a valence electron become a positive ion (cation)
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anion
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ion with a negative charge, atoms that tend to gain a valence electron become a negative ion (anion) and usually end in -ide
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ionization energy
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the energy required to remove an electron from an atom
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trends in ionization energy
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increases from bottom to top and from left to right on the periodic table
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shielding effect
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describes the attraction between an electron and the nucleus in any atom with more than one electron shell
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Why does ionization energy increase as you either move up, or move to the right on the periodic table?
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The smaller the atomic radius the closer the electrons are to the nucleus. As you recall the nucleus is positively charged. This means it is going to require more energy to remove that electron.
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trends in electronegativity
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increases up and to the right of the periodic table (excluding noble gases)
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electronegativity
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the ability of an atom of an element to attract electrons when the atom is in a compound
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What is the relationship between atomic radius and electronegativity? Why?
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The smaller the atomic radius the more electronegativity the atom has. The smaller the atomic radius indicates that the atom has fewer energy levels meaning that the valence electrons are closer to the positively charged nucleus. This allow the positively charged nucleus to have a larger impact on attracting electrons from other atoms.
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valence electrons
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the electrons in the highest occupied energy level of an element's atoms, they correspond with the group numbers on the periodic table, usually the only ones used in chemical bonds
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Lewis (electron) Dot Structures
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diagrams that show valence electrons as dots
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Octet Rule
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when forming compounds, atoms tend to achieve the electron, configuration of a noble gas (which has eight valence electrons)
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metallic atoms vs nonmetallic atoms
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metallic atoms tend to lose their valence electrons, while most nonmetals tend to gain valence electrons to form an octet
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transition metal charges
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? charges of cations can vary ? some metals like silver do not reach the electron configuration of a gas ? charges above positive three are very uncommon
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hallide ions
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ions formed when halogens gain an electron
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ionic compounds
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compounds formed of cations and ions, are electrically neutral, generally form a metal and nonmetal
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ionic bonds
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the electrostatic forces that hold ions together in ionic compounds
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chemical formula
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show the kinds and numbers of atoms in the smallest representative unit of a substance
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formula unit
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the lowest whole number ration of ions in an ionic compound, ex: H12O6 = H2O
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properties of ionic compounds
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usually solid crystals at room temperature, generally have high melting/boiling points, can conduct electric current when melted or dissolved in water/aqueous solution, brittle
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properties of covalent compounds
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exist as solids, liquids or gases, low melting/boiling points, don't conduct electricity at any state, don't dissolve in water
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metallic bonds
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consist of the attraction of the free-floating valence electrons, for the positively charged metal ions (sea of moving electrons), these are the bonds that hold metals together, metals are arranged in very compact/orderly patterns
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metallic bonding characteristics
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high melting/boiling point, high conductivity, malleable, ductile and have luster
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alloys
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mixtures composed of two or more elements, at least on is a metal, ex: sterling silver, bronze, steel
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covalent bond
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atoms held together by sharing electrons
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molecule
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an electrically neutral group of atoms joined together by covalent bonds
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diatomic molecules
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molecule consisting of two atoms
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molecular compound
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a compound composed of molecules, tend to have low melting/boiling points
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molecular formula
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shows the kinds and numbers of atoms present in a molecule or compound, not necessarily lowest whole number ratios
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nature of covalent bonding
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when forming covalent bonds, electron sharing tends to occur so that atoms, with shared electrons included, attain the electron configuration of noble gases ? as you increase the number of bonds, the bond length decreases and the bond strength decreases
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single covalent bonds
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atoms share one electron each
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double covalent bonds
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when atoms share two electrons each
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triple covalent bonds
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each atom shares three electrons
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bond length
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the average distance between nuclei of two bonded atoms in a molecule
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bond strength
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the degree to which each atom is joined to another in a chemical bond
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dissociation energy
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the amount of energy required to break a bond, the higher the dissociation energy the stronger the bond
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electron dot diagram
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show bonding by a way of dots
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structural formuala
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shows bonding using dashes
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unshared pair
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a pair of valence electrons that is not shared between atoms
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resonance structure
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a structure that occurs when it is possible to write two or more valid electron dot formulas that have the same number of electron pairs for a molecule or ion
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exceptions to the Octet Rule
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octet rule cannot be satisfied in molecules whose total number of valence electrons is an odd number, molecules in which an atom has fewer or more than a complete octet of valence electrons
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molecular orbitals
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the model that shows that when two atoms combine, their atomic orbitals overlap
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sigma bond
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bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting two atomic nuclei (caused by attraction of nuclei and electrons)
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pi bonds
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are side by side overlap of atomic p orbitals
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VSEPR Theory
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explains the three dimensional shape of a structure
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linear (VSEPR shape)
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3 atoms, 180 degree angle
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bent (VSEPR shape)
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3 atoms, 120 degree angle
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lone pair of electrons
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refers to a pair of valence electrons that are not shared with another atom and is sometimes called a non-bonding pair
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trigonal planar (VSEPR shape)
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4 atoms, 120 degree angle
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pyramidal (VSEPR shape)
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unshared pair of electrons, 4 atoms, 109 degree angle
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tetrahedral (VSEPR shape)
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4 atoms, 109.5 degrees
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t shaped (VSEPR shape)
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4 atoms, 2 unshared pairs of electrons
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square planar (VSEPR shape)
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5 atoms, 2 unshared pairs of electrons
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nonpolar covalent bond
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when atoms in a covalent bond pull equally, the bonding electrons are shared equally
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polar covalent bond
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a covalent bond between atoms in which the electrons are shared unequally, the more electronegative atom attracts electrons more strongly and gains a slightly negative charge, the less electronegative atom has a slightly positive charge
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polar molecule
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one end of the molecule is going to be slightly positive and the other end will be slightly negative
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dipole
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a molecule that has two poles, when polar molecules are placed between oppositely charged plates, they tend to become oriented with respect to the positive and negative plate, attraction between molecules are weaker than ionic and covalent bonds
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dipole interactions
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occur when polar molecules are attracted to one other
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London dispersion forces
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occur when moving electrons happen to be momentarily move on the side of a molecule closest to the neighboring molecule (very weak)
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hydrogen bonds
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attractive forces in which a hydrogen bond covalently bonded to a very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atom
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order of strength of intermolecular forces
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1. hydrogen bonding 2. dipole 3. London dispersion forces
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criteria for a chemical change
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1. precipitate formation 2. evolution of a gas 3. changes in energy
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types of chemical reactions
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1. synthesis 2. decomposition 3. single replacement 4. double replacement 5. combustion
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synthesis
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a chemical change in which two or more substances react to form a single new substance
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decomposition
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a chemical change in which a single compound is broken down into two or more simpler products
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single replacement
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a chemical change in which one element replaces a second element in a compound
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double replacement
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a chemical change that involves an exchange of positive ions between two compounds, anions and cations switch places
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combustion
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a chemical change in which an element or a compound reacts with oxygen, often producing energy in the form of heat and light
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chemical equations
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a representative of a chemical reaction, the reactants are on the left are connected by an arrow with the formulas of the products on the right
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catalyst
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a substance that speeds up a chemical reaction, written above the arrow in a chemical reaction, is neither a reactant or a product
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coefficients
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small whole numbers that are placed in front of the formulas in an equation in order to balance it
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balanced equation
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each side of the equation has the same number of atoms of each element and mass is conserved
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skeleton equation
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simplest form of a chemical equation that does not have coefficients
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rules on predicting products
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1. the compounds that form must be neutral in charge 2. DO NOT carry any subscripts over from the reactant side 3. balance your equation last
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displacement recations
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? metals will not always replace other metals in a reaction due to their reactivity ? in order for one metal to replace another, the other metal must be more reactive than the one that is replacing (the same rule applies for halogens)
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endothermic vs exothermic
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? If the element is MORE reactive than the one it is trying to replace then the reaction will occur and it will be exothermic ? If the element is LESS reactive than the one it is trying to replace then there will be no reaction and it will be endothermic
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rules for double replacement reactions
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? not all double displacement reactions occur ? in order for a double replacement reaction to occur, both reactants must be soluble in water (if only one of the ions in a compound is soluble the compound will be at least moderately soluble) ? one product must be soluble, one product must be insoluble (the insoluble product is the precipitate and the precipitate will usually be a solid)
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spectator ion
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an ion that appears on both sides of an equation and is not directly involved in the reaction
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mole
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the amount of a substance that contains 6.022 x 10^23 representative particles of that substance
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Avogadro's number
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the number of representative particles contained in one mole of a substance (6.022 x 10^23)
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molar mass
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term used to refer to the mass of a mole of any substance
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mole ratio
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a conversion factor deprived from the coefficients of a balanced chemical equation interpreted in terms of moles
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stoichiometry
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the calculation of quantities in chemical reactions (the coefficients of a balanced equation indicates the relative number of moles of reactants and products in a chemical reaction)
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stoichiometry steps
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1. balance the chemical equation 2. identify the given chemical ; measure and the unknown (to be found) chemical and measure 3. change the measure of the given chemical into moles 4. use the balanced chemical coefficients to form a ratio with the coefficient of the unknown chemical in the numerator, and the coefficient of the given chemical in the denominator, multiply the given moles by this ratio to find the moles of unknown chemical 5. change the unknown number of moles to the measure that was requested
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standard temperature and pressure (STP)
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the conditions under which the volume of a gas is usually measured (1 mole of any gas at STP occupies a volume of 22.4 L)
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limiting reagent
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determines the amount of product that can be formed in a reaction, the reaction occurs until the limiting reagent is up
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excess reagent
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the reactant that is not completely used up in a reaction
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compressiblity
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a measure of how much the volume of matter decreases under pressure (gases are more easily compressed than solid or liquids because of the space between their particles)
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variables used to describe a gas
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1. pressure KPa (kilopascals) 2. volume L (liters) 3. temperature K (Kelvin) 4. number of moles (n)
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kinetic molecular theory
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1. The volume occupied by the individual particles of a gas is negligible compared to the volume of the gas itself. 2. The particles of an ideal gas exert no attractive forces on each other or their surroundings. 3. Gas particles are in a constant state of random motion and move in straight lines until they collide with another body. 4. The collisions exhibited by gas particles are completely elastic; when two molecules collide, total kinetic energy is conserved. 5. The average kinetic energy of gas molecules is directly proportional to absolute temperature only; this implies that all molecular motion ceases if the temperature is reduced to absolute zero.
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gas laws
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1. Boyle's Law 2. Charles' Law 3. Gay-Lussac's Law 4. Dalton's Law 5. Ideal Gas Law
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Boyle's Law
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states that for a given mass of gas at constant temperature, the volume of gas varies INVERSELY with pressure (equation: P1V1 = P2V2)
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Charles' Law
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states that the volume of a fixed mass of gas is directly proportional to its Kelvin temperature (equation: V1/V2 = V2/T2)
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Gay-Lussac's Law
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states that the pressure of a gas is directly proportional to the Kelvin temperature if the volume remains constant (equation: P1/T1 = P2/T2)
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Combined Gas Law
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allows calculations to be done when gas is constant (equation: P1 x (V1/T1) = P2 x (V2/T2)
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Ideal Gas Law
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law stating that allows problems involving pressure, temperature and volume to be solved (equation: PV = nRT)
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ideal gas
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a hypothetical gas whose molecules exhibit no interaction and