Chem Chap 18 – Flashcards

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question
Ethylmethylamine is a tertiary amine T/F
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false
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amines do not ionize in water
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false
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in what form are amine-containing drugs often administered?
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ammonium salt
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The compound CH3CH2NHCH3 is classified as a
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secondary amine
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Crack cocaine is produced by the neutralization and extraction of cocaine from its hydrochloride salt.
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true
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Amides are derivatives of __________ and __________
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amines and carboxylic acids
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The odor of an amine can be neutralized with
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acids
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what relation does the boiling point of an amine have to a similar hydrocarbon?
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higher
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Aminobenzene is properly known as
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aniline
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Heterocyclic amines contain a nitrogen atom in a ring T/F
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true
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What functional group is always found in alkaloids (such as caffeine, nicotine, and digitalis)?
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amine
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what prefix is used to show that a small alkyl group is attached to the nitrogen of aniline and not to the aromatic ring?
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N-
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aniline is a(n)
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primary aromatic amine
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amines are
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bronsted-lowry acids
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Neurotransmitters are chemicals that transmit a nerve impulse T/F
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true
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Hydrogen bonds in amines are weaker than those in alcohols. T/F
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true
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Which of the following compounds cannot form hydrogen bonds with water?
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CH3CH2CH3
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Amides having fewer than __________ carbons are generally water soluble.
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6
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Amines act as weak acids by accepting protons from water. T/F
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false
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Pyrimidine derivatives are found in DNA. T/F
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true
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Procaine® and Lidocaine® were developed by modifying the structure of
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cocaine
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The compound CH3CH2NH2 is classified as a
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primary amine
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Amine salts are odorless and usually highly water soluble. t/f
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true
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What kind of amine cannot form intramolecular hydrogen bonds?
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tertiary
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Amine salts are usually liquid at room temperature.
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false
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Cyclic compounds that contain a nitrogen atom are called
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heterocyclic compounds
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With the correct choice of acid, acid hydrolysis of acetamide could produce
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acetic acid and ammonium chloride
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Caffeine is not an alkaloid. t/f
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false
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Aniline is a primary amine. t/f
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true
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Which of the following is NOT an alkaloid?
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diethylamine
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what are alkaloids?
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physiologically active nitrogen compounds derived from plants
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Among the choices below, identify the heterocyclic amine found in DNA.
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purine
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How many alkyl substituents does N-ethyl-N-methylaniline have?
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2
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Physiologically active nitrogen-containing compounds produced by plants are called
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alkaloids
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In what kind of amine is the nitrogen directly bonded to two carbon atoms?
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secondary
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Aniline is the IUPAC approved name for aminobenzene. t/f
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true
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What kind of compound is urea?
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amide
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Amines can form __________ bonds with other molecules.
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hydrogen
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Which of the following compounds is an amine?
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(CH3CH2)2NH
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When ethylamine dissolves in water, a solution of __________ is produced
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ethylammonium hydroxide
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Amines do not form hydrogen bonds. t/f
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false
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Amines contain the element t/f
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nitrogen
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The amine functional group is rarely found in pharmacologically active compounds
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false
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Nicotine, coniine, quinine, atropine, and morphine are all examples of
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alkaloids
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When amides are hydrolyzed in basic solution, the products are an ammonium salt and a carboxylic acid. t/f
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false
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Amines with more than six carbon atoms are soluble in water. t/f
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false
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Which of the following compounds canot form hydrogen bonds with water?
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(CH3CH2)3N
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When naming amines according to the IUPAC system, the -e in the corresponding alkane is replaced with
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amine
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Identify the heterocyclic amine in the choices below
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purine
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When amides are hydrolyzed in acidic solution, the products are an amine and a carboxylic acid. t/f
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false
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Primary amines contain two carbon-containing groups bonded to the nitrogen atom. t/f
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false
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Diethylamine and HCl react to produce
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diethylammonium chloride
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When acetic acid reacts with ammonia, NH3, the reaction called amidation yields
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acetamide
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