Chapter 6 – Chemistry Test Questions – Flashcards

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A mutual electrical attraction between the nuclei and valence electrons of different atoms that binds atoms together
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Chemical Bond
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Metals tend to _____ electrons and become _______; Nonmetals tend to _________ electrons and become _______
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Lose/Cations;Gain/Anions
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Chemical bonding that results from the electrical attraction between cations and anions;give up electrons to other atoms
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Ionic Bonding
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Sharing of electron pairs between two atoms; electrons "owened" equally by bonded atoms
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Covalent Bonding
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How do you determine the type of bond?
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The difference in eectronegativity
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Bonding between two atoms of the same element is completely _______
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Covalent
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Covalent bond in which the bonding electrons are shared equally by the bonded atoms, resulting in balanced distribution of electrical charge
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Nonpolar-covalent bond
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Have uneven distribution of charge
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Polar
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Covalent bond in which the bonded atoms have unequal attraction for the shared electrons
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Polar-covalent bond
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0-.3=_______
.3-1.7=________
1.7-...=__________
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Nonpolar-covalent;polar-covalent;ionic
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Neutral group of atoms that are held together by covalent bonds
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Molecule
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Chemical compound whose simplest units are molecules
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Molecular Compound
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Composition of a compound is given by the __________ ________
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Chemical Formula
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Indicates the relative numbers of atoms of each kind in a chemical compound by using atomic symbols and numerical subscripts
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Chemical Formula
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Shows the types and numbers of atoms combined in a single molecule of a molecualr compound
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Molecular Formula
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Molecule containing only two atoms
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Diatomic Molecule
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Potential energy ________ as the attraction gets stronger and _______ as the repulsion gets stronger
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Decreases;Increases
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Distance between two bonded atoms
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Bond Length
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Energy is ________ when bonded
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Released
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The energy required to break a chemical bond and form neutral isolated atoms
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Bond Energy
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As length _______ energy _______ and visa versa
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Increases;Decreases
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Chemical compounds tend to form so that each atom, by gaining, sharing, or losing electrons has an octet of electrons in its highest energy level
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Octet Rule
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Exceptions to the octet rule
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Boron can only have 6 VE;Expanded Valence(More than eight electrons esp. when bonded with F,O, or Cl)
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An electron-configuration notation in which only the valence electrons of an atom of a particular element are shown, indicated by dots placed around the element's symbol
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Electron-dot notation
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Pair of electrons that is not involved in bonding and that belongs exclusively to one atom
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Unshared(Lone) pair
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Formulas in which atomic symbols represent nuclei and inner-shell electrons, dot pairs or dashes between two atomic symbols represent electron pairs in a covalent bonds, and dots adjacent to only one atomic symbol represent unshared electrons
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Lewis Structures
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A covalent bond in which one pair of electrons is shared between two atoms
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Single Bond
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Covalent bond in which two pairs of electrons are shared between two atoms, esp. C,N,O
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Double Bond
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Covalent bond in which three pairs of electrons are shared between two atoms
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Triple Bond
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________ get shorter
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Stronger
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Bonding in molecules or ions that cannnot be correctly represented by a single lewis structure
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Resonance
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Composed of positive and negative ions that are combined so that the numbers of positive and negative charges are equal
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Ionic Compound
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Simplest collection of atoms from which an ionic compound's formula can be established
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Formula unit
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Ratio of ions in a compound depend on the _______ of the ions combined
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Charges
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Orderly arrangement in which ions are combined to minimize potential energy
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Crystal Lattice
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The energy released when one mole of an ionic crystalline compound is formed from gaseous ions
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Lattice Energy
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Bond between molecules determine _______/_________ and ________ (Stronger equals ______)
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Melting point/boiling point and hardness;Higher
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Ionic compounds are ______ but ________
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Hard but Brittle
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Ionic compounds are only conductors in _________ state or in ________
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Molten/Water
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What two things are required for conductors
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Ions and movability
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A charged group of covalently bonded atoms
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Polyatomic ions(have characteristics of Molecular and ionic)...for lewis structures, if pos, subtract....if neg add
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Do not belong to any one atom but move freely about the metal's empty atomic orbitals
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Delocalized
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The chemical bonding that results from the attraction between metal atoms and the surrounding sea of electrons
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Metallic Bonding
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Properties of metals(4)
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Good thermal/electrical conductors;Strong absorbers/reflectors of light
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Ability of a substance to be hammered into thin sheets
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Malleability
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Ability of a substance to be drawn through a small opening to produce wire
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Ductility
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The amount of energy absorbed as heat when a specified amount of a substance vaporizes at constant pressure
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Enthalpy(heat) of vaporization
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5 bond sites 5 bonds
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triginal bipyramidal
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5 bond sites 4 bonds
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seesaw
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5 bond sites 3 bonds
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T shape
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5 bond sites 2 bonds
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linear
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6 bond sites 6 bonds
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octahedral
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6 bond sites 5 bonds
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square base pyramid
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6 bond sites 4 bonds
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square planar
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3 bond sites 3 bonds
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triginal planar
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4 bond sites 4 bonds
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tetrahedral
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4 bond sites 3 bonds
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triginal pyramidal
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4 bond sites 2 bonds
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bent
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2 bond sites 2 bonds
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linear
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VSEPR stands for...
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Valance shell electron pair repulsion
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states that repulsion between the sets of valance electrons surrounding an atom causes these sets to be oriented as far apart as possible
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VSEPR theory
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The mixing of two or more atomic orbitals of similar energies on the same atom to produce new hybrid atomic orbitals of equal energy
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hybridization
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Intermolecular forces
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Dipole-dipole;Hydrogen;London dispersion forces
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