ochem chapter 5 – Flashcards

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question
An increase in which of the following results in a decrease in the rate of the chemical reaction? Select one: a. temperature b. concentration c. collision frequency d. energy of activation e. fraction of collisions with proper orientation
answer
d. energy of activation
question
Give the degree of unsaturation for benzene. Select one: a. 2 b. 3 c. 5 d. 1 e. 4
answer
E.4
question
Give the general formula for a cyclic alkene. Select one: a. CnH2n b. CnH2n-2 c. CnH2n+2 d. CnH2n-4 e. CnH2n+2
answer
b. CnH2n-2
question
Give the possibilities in structure for a compound with a formula of C6H10. Select one: a. no rings, no double bonds, no triple bonds b. three rings, three double bonds, two double bonds + one ring, one ring + two double bonds, one triple bond + one ring, or one double bond + one ring c. one double bond, or one ring d. benzene e. two rings, two double bonds, one double bond + one ring, or one triple bond
answer
e. two rings, two double bonds, one double bond + one ring, or one triple bond
question
Name the structure. H2CCHCH2I Select one: a. allyl iodide b. 1-iodo-2-propene c. vinyl iodide d. 2-iodo-1-propene e. iodomethylethene
answer
a. allyl iodide
question
What is the value of ?H in kcal/mole for the reaction shown? (CH3)3CH + ClCl ? (CH3)3CCl + HCl Bond energies are: (CH3)3CH = 91 kcal/mole (CH3)3CCl = 78.5 kcal/mole ClCl = 58 kcal/mole HCl = 103 kcal/mole Select one: a. -8.5 b. -57.5 c. +32.5 d. +57.5 e. -32.5 Correct
answer
e. -32.5
question
Which of the following is an allylic alcohol? Select one: a. CH3CH=CHCH2OH b. HOCH=CHCH2CH3 c. CH2=CHCH2CH3 d. CH2=CHCH2OCH3 e. CH2=CHCH2CH2OH
answer
a. CH3CH=CHCH2OH
question
Which of the following is not an electrophile? Select one: a. Fe+3 b. H+ c. +NO2 d. CH2CH2 e. BF3 Check
answer
d. CH2CH2
question
Which of the following statements about ethene, C2H4, is incorrect? Select one: a. All of the hydrogen atoms are in the same plane. b. The H-C-H bond angles are approximately 109.5°. c. There is a total of five sigma bonds. d. The carbon atoms are sp2 hybridized. e. The H-C-H bond angles are approximately 120°.
answer
b. The H-C-H bond angles are approximately 109.5°.
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