Chemistry Semester Exam – Flashcards

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What is the history of the word alchemy?
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Philosopher's Stone
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Where did alchemy start?
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India ; China
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Alchemy is of what use to science?
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Transforming common chemicals into gold creating the phillosphers stone
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Who was consider the first legit Chemist and Why?
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Robert Boyle; using experiment to measure relationship between pressure and volume of gas
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Who was the "father of modern chemistry" and why?
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Antoine Lavosien discovered that  matter may change it's shape or form
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What do Chemist do?
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apply information about matter and the changes it undergoes to improve our lives in different ways.
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Top Chemicals in the U.S.A.
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Sulfuric Acid, Nitrogen Ethyene, Oxygen, Propylene, Chlorine, Ethyene Dichloride, Phosphric Acid, Ammonia, Sodium Hydroxide
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Which greek Phillosphers were know as the "thinkers"; their experiments were based on logical thinking with no basis in experiment
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Socrates, Plsato, Aristotle
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Generic  Step of the Scientfic method
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1. find a Problem/ Research

2. Make a Hypothesis & test

3. Interpet Results

4.State Conclusion in a public form

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Serendipity
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chance and unexpected findings base on good observations have often moved science in unexpected and rewarding ways
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Hypothesis
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is an educated guess. it is normally formed in an "if-then" statement
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Varaibles
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Factors that effect the outcome of an experiment.
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Chenistry common varriables are . . .
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P, T,n,V
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Theory
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explanation for some phenomeon that is base on verified observation repeated experimentation and reasoning.
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Scientfic law
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represents descriptive facts of nature that are indisputed
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Experiment
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is a method of testing a hypothesis
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Controlled Experiment
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compares the result to a control sample, identical to the test sample- expect for one variable being tested.
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Models
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are simulations, subittiutes or stand ins for a process or obeject we are unable to directly observe
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In Science we measure data ________.
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Quantitatively
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Qualitative observations are __________.
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Non-Numerical
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Kilo
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K

1000

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Deci
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d

.1

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Centi
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c

.01

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Milli
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m

.001

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Matter
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anything having mass and volume
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volume
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space an object occupies
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Volume =
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L X W X H
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Mass
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quanity of matter contained in an object
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Weight
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A Measure of gravity on a given mass
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Temperature
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represent the average kentic energy of particles in a sample of matter.
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Heat
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is a movemnt of thermal energy of the particles in a sample of matter.
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atoms

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building blocks of matter
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Pure Substances
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can contain either a single element or a single compound .... they only have one type of atom
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Element
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pure substance with one type of atom
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Compound
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is a pure substance containing two or more atoms in a different reaction
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7 diatomics
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H2, N2, O2, F2, Cl2, Br2, I2
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Mixtures
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contain two or more pure substances that are not chemically combined.
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Gold  Alloys
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24 Karat is the maxium gold content (100% gold)
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Mixures are classified as ______ or _________
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Homogeous; Heterogeous
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Homogenous Mixtures
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same throughout
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Heterogenous Mixture
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part with different properties
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Allotropes
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mutiple forms of molecules of the same element
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Solids
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Constant volume and constant shape
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Liquid
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Constant volume and Variable shape
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Gases
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varaible volume and Shape
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Macroscropic Properties
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are observations with the naken eye - atoms in bulk show these properties
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Microscropic Properties
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show particles in layered form- too small to see with the naked eye must be observed indirectly.
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Physical Properties
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can be observed without changing the idenity of subsances changes of state.
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Chemical Properties
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Can only be obsevred when a substance is changed into a new substance
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Chemical Reaction
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Process by which one or more substances change into one or more new substances with new properties
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Energy
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ability to do work
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Energy forms are either _____ or ________
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Potential; Kinetic
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Potential Energy
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comes in forms that are stored including chemical, graduation, mechincal and nuclear
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Kinetic Energy
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forms are doing work involving movement or somekind - like electrical, heat, light, motion, and sound.
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Endothermic
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process invloving an absorption
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Exothermic
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Process involving a relase of energy
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Law of Conservsation of Energy
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durring any physical or chemical change energy is not created or destroyed
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The total amount of energy and matter in the universe is constant( does not change).
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System
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is the container and reaction under study
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Surroundings
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everything outside the system
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Heat is energy transfered . . .
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between objects atdifferent temperatures.
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Energy always . . .
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moves from the hot object to the cooler object.
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Conduction
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direct contact
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Convention
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little indirect contact
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Radiation
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little absorption
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Temperature
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is a measure of the Average kinetic energy of the particles in a sample of matter
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Kelvin =
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K= C+ 273.15
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Celius =
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C= K- 273.15
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Work
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is forced applied over a distance
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Work =
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W= Force(Distance)
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The Greeks Thought were four types of Atoms ____, ____, ____, _____.
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earth, air, water, fire
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Thompson viewws the atom as a ____ ____ containing an equal mix of changes in a _____ sphere. This is sometimes called the ____ pudding model.
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solid sphere; charges; positive; plum
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Daltons Theory: 5 Major Principles
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  1. all matter is made of indivisible and indestructive particles.
  2. like atoms have the same physical/chemical properties.
  3. different atoms have different phyiscal/chemical properties.
  4.  atoms combine in a wide-number of ratios to make compounds.
  5. atoms cannot be detrosted or created in chemical reactions.
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Cathode
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Negitive Electrode
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Anode
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Positive Electrode
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Law of Comipition
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Compounds have the same element in the same properties by mass no matter what the source.
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Law of Conservation of Mass
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Durring the chemical reaction the mass of the product equals the mass of the reactants.
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Law of Mutiple Proportions
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when two elements so make differrent compounds they combine in simple whole number ratios
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Nucleus
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is the centeral region of the atom. Very Desnsed,

 Positive Charged

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Protons
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Heavy and charged particles found in the nucleus. Nutral
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Nuetron
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negitivly charged particle, found in nucleus
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Electron
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negitive charged small particles orbiting at relatively large distance from the Nucleus. Aka Beta Particles.

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Alpha Particles
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positive two charged particles emitted from the nucleus of large unstable atoms. it has two protons and two neutrons. 

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The ____ _____ _______ acts like an atomic velcro ______ the same charged particles from ______ on another.
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Strong Nucleus force; kepping; rerepelling
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Atomic Number
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is the number of protons in an atom.
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Mass Number
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the sum of the number of protons and neutrons in an atom's nucleus.
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Isotopes
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are elements with the same number of protons but different number of neutrons
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Atomic Mass
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is the average mass of all the isotopes of an element
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It is the element _____ that determines the chemical properties of an atom
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arrangement
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______ do not orbit the nucleus in nice circular orbits.
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Electrons
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______ can be describe as particles and waves.
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Electrons
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a _____ is a region around a nucleus where electrons are likely to be found.
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Orbital
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a ____ _____ electron is in its lowest energy state.
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Ground State
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Exicited state electrons =
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e-
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exicited electron is _____ and re-emits Energy as it ______ to the ground state.
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unstable;relaxes
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The Entire spectrum contains . . .
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Gamma Rays,X-Rays, UV, Visible, IR, Microwaves, Radiowaves
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Frequency
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number of waves/second
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Wavelength
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distance between peeks on adjacent waves
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high frequency waves have _____ wavelength
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short
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Principle Quantum Number
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indicates the main energy level
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Angular Momentum
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the main energy levels are divied into sublevels of that electron
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S orbitial =
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2 electrons
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P orbital =
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6 electrons
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D orbital =
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10 electrons
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F orbital =
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14 electrond
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1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d
7s 7p
8s
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half-life
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the time required for half of the atoms in sny given quanity of a radioactive isotope to decay is the half life of that isotope. each particular isotope jad its own unique half-life.
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i have 300 donuts. how many dozen is this?
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300 1dozen
_____________ = 25 Donuts
12 dounts
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The Standard isotope for measuring mass is the ______ isotope
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C-12
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one Mole =
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6.022 X 10^ 23
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mole is also know as
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Avogadro's number
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bubba has 1.256 X 10^24 atoms of Zn.
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1.256 X 10^24 1 mol
____________________________ = 2.08 mol
6.022 X 10^24
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When elements are arranged by the ___ ___, several trends are apparent. Trends are ______ in the physical and chemical properties id the elements. these trnds become apparents in the ______ and the ______ of the table.
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atomic number; patterns; families; series
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Atomic radius
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half the distance between the center of two like atoms. atomic radius increases down a family
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atomic radius _____ across
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decreases
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Atomic Radius Trends:
the ____ gas configuration is a _______ condition for an atom. _____ atoms tend to ____ or ____ electrons to obtain a Noble Gas Electron Configuration.
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Noble;stable;Neutal; lose, gain
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Ions
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An atom or a group of atoms that has gained or lost electrons and become positivly or negitively charged
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Ionic radius Graphical Trend:
They _____ down a family ionic size _____ generally. Across a peroid, ionic size radius _____ grenerally.
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move; increase; decreases
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Ionization Energy
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Energy required to remove an electron from an atom or ion. as you go down a family the ionization decrases. As you move across a peroid the ionization of energy increases.
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Electonegitivly
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This measures the attraction an atom has for electrons while its bonding with another atom. down a family this decrease across a peroid this increases.
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Shielding effect
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as an atom gets larger with the addition of extra energy levels, the affect increases. this is because they are "shielded" from a strong attraction by the nucleus due to the extra layers of the outer electrons and the nueclus. shielding effect increases down a family. it remains contstant within a peroid.
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Most ____ Seek lost their Electrons
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Metals
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_______ tend to seek to gain electrons
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nonmetals
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8 electrons is a . . .
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Octlet
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most reactive elements are the . . .
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Alkalimetals and the halogens
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Metals ____electrons
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lose
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nonmetals ____electrons
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gain
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ions have unique properties unrelated to the properties if the element
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"Octet Rule"
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Cations
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+
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Anions
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-
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salt is a _____ compound formed by negitivly and positive charged ions
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ionic
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There are _____ types of salts
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thousands
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Most _____ & _____ are ionic compounds
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rocks minerals
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ionic compounds are _____ ______ ______ as molecules
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not the same
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Acetate
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C2H3O2-1
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Chlorate
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ClO3-1
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HYDROXIDE
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OH-1
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NITRATE
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NO3-1
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NITRITE
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NO2-1
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SULFATE
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SO4-2
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SULFITE
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SO3-2
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CARBONATE
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CO3-2
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PHOSPHATE
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PO4-3
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AMMONIUM
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NH4+1
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Covelant bonds
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these form between nonmetals
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Attractive forces are ____ ____ ____ particles
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between oppsite charged
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Repulsive forces are ____ ____ ____ particles
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between like charged
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Molecular Compounds
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compounds formed from covalent bonds
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0.0 to 0.5
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nonpolar covalent
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0.6 to 2.1
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polar covalent
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2.2 to 3.3
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ionic
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mono =

di=

tri=

tetra=

penta=

hexa=

hepta=

octa=

nona=

deca=

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mono =1

di=2

tri= 3

tetra=4

penta=5

hexa= 6

hepta= 7

octa=8

nona=9

deca= 10

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 covalent compounds are correctly called _______, while ionic are correctly called "_______ ______"

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Molecules; " Formula Units"
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The atomic mass of their compound is the ____ of all the atomic masses in the compound

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SUM
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The Percentage composition Calculation allows is to calculate the ______ of ________ for each element in a compound.
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Percentage of mass
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Percentage composition of Magensium hydroxide

 

MgOH2

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24.3/58.3 X 100 =41.6%

32/58.3 X 100= 54.8%

2/58.3 X 100= 3.43%

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Remeber to add the mass of Water !!!!!! :)
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Emprical Formual
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is the mathematically reduce formula of a chemical formual.
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In emprical formula percentage convert to _____
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grams
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find the emprical formual for the compouind containing 46.7% Si and 53.3% O2.
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46.7g Si    1mole


                 28.086g

= 1.66

 


 

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Properties of Solids
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  • particles close together
  • ordely fixed arrangement
  • particles wobble into place
  • ionic solids are unsually crysaliione material
  • covalent solids varry from damonds to waxes to greases
  • density relavitly high
  • hardness depends on substance  
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Properties of Liquids
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  • have a random arragment of particles
  • held by attractive forces
  • similar density to solid
  • slide past each other
  • viscostiy= restanice flow
  • coplairy action
  • attractive to glass surface
  • surfacetension 

 

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Example of Liquds
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propane

melted solid

gasoline

oil

alochol

milk

juice

vingear

ammoniuia

anti-freeze

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Properties of gases
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  • particles are relvatively far apart 
  • they dont have much attraction towards each other
  • fill any conatainer placed in
  • varraible shape and volume   
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Freezing/Melting
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Liquid <-> Solid
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evaporation/bolling/condensation
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Liquid <-> gas
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Sublimation / depsoition
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solid <-> gas
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Most substances can contain in all three states of matter
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Intermolecular forces
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attractions between oppositively charged ions
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Dipole-Dipole
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polar molecules are those that do not share thier electrons well. As a result they have "partial" charges which allow them to attract to their neighbors.
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Solution
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homogenous mixture of substance
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Suspension
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mixture where particles settle out
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heterogenous
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different throughout
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homogenous
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same throughout
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Solvent
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greater amount
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Solute
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less amount
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alloy
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mixture of two or more elements
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alloy
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mixture of two or more elements
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colliod
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mixture where the particles reflect light
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Decant
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fdraw off a liquid sediment
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Tyndall Effect
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scattering of light by particles
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Filteration
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seperation of solids from fluids
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Chromatograpghy
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seperation of mixtures
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Distillation
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Evaporation and subsequent collection of a liquid by condensation as a means of purification.
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Solubility
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max amount of a substance that will disslove at a specfic Temperature.
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Polar
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Not symmetric
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