Chemistry Final Test Questions – Flashcards

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chemistry
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the scientific study of the composition, structure, and properties of matter and the changes that matter undergoes
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hypothesis
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an explanation that is based on prior scientific research or observations and that can be tested
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mass
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a measure of the amount of matter in an object
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weight
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a measure of the gravitational force exerted on an object
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density
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the ratio of the mass of a substance to the volume of the substance
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basic research
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carried out for the sake of increasing knowledge
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applied research
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carried out to solve a problem
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organic chemistry
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focuses on most carbon-containing compounds
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inorganic chemistry
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focuses on non-organic substances
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biochemistry
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focuses on processes occuring in living things
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analytical chemistry
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focuses on composition of materials
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SI base units
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meter-length; kilogram-mass; second-time; kelvin-temperature; mole-amount of substance; ampere-electrical current; candela-luminous intensity
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formula of density
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D=M/V
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accuracy
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a description of how close a measurement is to the true value of the quantity measured
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precision
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the exactness of a measurement
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uncertainty
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the lack of certainty
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significant digit
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any digit of a number that is known with certainty
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significant zeros
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in between significant numbers and final zeros after the decimal point
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scientific notation
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45,600,000=4.56x10^8
.00000526=5.26x10^-7
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matter
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anything that has mass and takes up space
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element
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a substance that cannot be separated or broken down into simpler substances by chemical means
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compound
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a substance made up of atoms of two or more different elements joined by chemical bonds
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mixture
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a combination of two or more substances that are not chemically combined
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matter and energy are conserved
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energy is transformed into another so it's never destroyed. matter can be changed into energy so it can continue to exist in other forms
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homogenous mixture
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uniform
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heterogenous mixture
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different components
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states of matter
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solid, liquid, gas, and plasma
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solid
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definite volume and shape
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liquid
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definite volume but indefinite shape
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gas
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neither definite volume nor shape
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plasma
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high temperature, atoms lose most of their electrons
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physical change
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a change of matter from one form to another
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chemical change
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a change that occurs when one or more substances change into new substances with different properties
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atom
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the smalles unit of an element that maintains the chemical properties of that element
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nucleus
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the positively-charged dense center of an atom
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ion
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an atom, radical, or molecule that has gained or lost one or more electrons and has a negative or positive charge
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isotope
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an atom that has the same number of protons as other atoms of the same element but different number of neutrons
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atomic number
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the number of protons in the nucleus of an atom
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atomic mass
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the mass of an atom of a chemical element expressed in atomic mass units
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subatomic particles
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protons, neutrons, and electrons
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protons
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in the nucleus with a positive charge (same as atomic number)
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neutrons
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in the nucleus with a neutral charge (same as protons)
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electrons
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in the electron cloud with a negative charge (protons+electrons/2)
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molar mass
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same as atomic mass . g/mol
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frequency
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the number of waves produced in a given amount of time
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wavelength
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the distance from any point on a wave to an identical point on the next wave
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amplitude
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the height of a wave from its trough or crest to its midpoint
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electromagnetic radiation
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the radiation associated with an electric and magnetic field
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quanta
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the basic unit of electromagnetic energy
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photon
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a unit or quantum of light
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ground state
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the lowest energy state of a quantized system
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electromagnetic spectrum
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red, orange, yellow, green, indigo, violet
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speed of light (3x10^8 m/s)
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frequency x wavelength
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energy
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60.626x10^-3 x wavelength
Max Planck
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photoelectric effect
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refers to the emission of electrons from a metal when light shines on the metal
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principal energy level
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the energy level denoted by the principal quantum number
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sublevel
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a part of a level which can hold a different number of electrons
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orbital
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a region in an atom where there is a high probability of finding electrons
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sublevels
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s, p, d, f
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# of orbitals
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s=1(2), p=3(6), d=5(10), f=7(14)
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Aufbau Principle
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an electron occupies the lowest-energy orbital that can receive it
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Pauli Exclusion Principle
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no two electrons in the same atom can have the same set of four quantum numbers
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Hunds Rule
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orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron and all electrons in singly occupied orbitals must have the same spin state
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aufbau
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1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 4f 5d 6s 6p
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periodic table
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an arrangement of the elements in order of their atomic numbers
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period
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a horizontal row of elements in the periodic table
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group
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a vertical column of elements in the periodic table
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valence electrons
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electrons that are found in the outermost shell of an atom
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octet rule
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atoms tend to gain, lose, or share electrons to have eight electrons in the outer shell
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metals
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elements that are shiny and conduct heat and electricity well
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non-metals
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elements that conduct heat and electricity poorly
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Mendeleev
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credited for developing the modern periodic table
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alkali metals
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first column
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alkaline-earth metals
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second column
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transition metals block
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middle
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halogens
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second to last column
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noble gases
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last column
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s block
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first columns
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p block
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last part
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lanthanides and actinides block
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bottom two rows
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atomic radius
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one-half of the distance between the center of identical atoms that are not bonded together
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ionization energy
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the energy required to remove an electron from an atom or ion
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electron affinity
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the energy needed to remove an electron from a negative ion to form a neutral atom or molecule
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electronegativity
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a measure of the ability of an atom in a chemical compound to attract electrons
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ionic bond
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a force that attracts electrons from one atom to another which transforms neutral to ions
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covalent bond
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a bond formed when atoms share one or more pairs of electrons
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polar covalent bond
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a covalent bond in which a pair of electrons shared by two atoms is held more closely by one atom
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non-polar covalent bond
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a covalent bond in which the bonding electrons are equally attracted to both bonded atoms
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molecule
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the smallest unit of a substance that keeps all the physical and chemical properties of that substance
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oxidation number
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the number of electrons that must be added to or removed from an atom in a combined state to convert the atom into the elemental form
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ions
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NH4 +, OH-, NO3 -, C2H3O2 -, SO4 2-, PO4 3-
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polyatomic ions
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ions made up of two or more elements covalently-bonded
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cations
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positive ions
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anions
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negative ions
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to become stable compounds
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why do atoms bond to form compounds?
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VSEPR
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predicts some molecular shapes based on the idea that pairs of valence electrons surrounding an atom repel each other (linear, bent, trigonal planar, tetrahedral)
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linear
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atoms connected together in a straight line; bond angle=180 degrees; occurs in compounds consisting of only two atoms and three if middle has no unshared electrons
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bent
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atoms connected in an angled fashion; bond angle=105 degrees; occurs in compounds consisting of three atoms if the central atoms has unshared electrons
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trigonal planar
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occurs in compounds consisting of four atoms bonded together
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tetrahedral
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occurs in compounds consisting of five atoms bonded together; no unshared electrons; bond angle=109.5 degrees
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hybrid orbital
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an orbital formed by the combination of multiple atomic orbitals on the same atom
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polar molecule
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different polarities which attract each other
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non-polar molecule
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same polarities which repel each other
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intermolecular forces
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repulsion between atoms, dipole-dipole, induced dipole
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mixtures
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non-chemical combinations of elements or compounds; no chemical change that occurs among the combining materials
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heterogeneous mixture
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have different amounts of substances dispersed; don't totally dissolve; maintain their original states; will separate over time
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homeogeneous mixture
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have the same amount throughout; one substance becomes completely dissolved in another; dissolved substance takes on the state of what it is dissolved in; mixed substances stay together
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solute
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substance that gets dissolved
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solvent
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substance that does the dissolving
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solid solution
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solid/liquid/gas dissolved in a solid
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aqueous solution
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solid/liquid/gas dissolved in a liquid
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gaseous solution
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solid/liquid/gas dissolved in a gas
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alloy
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a solution made of two or more metals mixed together
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colloids
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have properties in between those of suspensions and solutions
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sol
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more liquid than solid
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gel
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more solid than liquid
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electrolyte
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solute that when dissolved, makes its solvent more conductive to electricity; solutes that when dissolved, break up into ions
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solvation
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process of a solute being dissolved by a solvent; has to be able to "pull apart" the solute
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effects of solvation
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nature of the solute and solvent "like dissoves like"; temperature of the solution; pressure; heat of the solution
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increases solubility
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raising the temperature of a solution witha solid solute..
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decreases solubility
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raising the temperature of a solution with a gaseous solute..
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does not change solubility
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raising the temperature of a solution with a liquid solute..
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pressure
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changes in this will affect solubility only when the solute is a gas
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Henry's Law
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pressure above a gas is directly proportional to the solubility of the gas
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endothermic solution
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has an increase in solubility when the temperature increases
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exothermic solution
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has a decrease in solubility when the temperature increases
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heat of solution
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amount of energy produced or consumed by the formation of the solution
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saturated solution
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a solution with the max amount of solute that can be dissolved
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unsaturated solution
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a solution with less than the max amount of solute that can be dissolved
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supersatured solution
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a solution with more than the max amount of solute
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surface area
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the larger available for dissolving, the faster the solute will dissolve
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stirring
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puts more solute particles into contact with solvent, therefore increasing rate of dissolving
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dissociation
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ionic compounds that dissolve will actually be separated into the ions that make them up
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insoluble
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some ionic compounds don't dissolve at all in water
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precipitation
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process of solids forming in a solution
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spectator ions
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ions that don't take part in a chemical reaction
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ionization
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formation of ions in solution from molecules
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concentration
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measure of how much solute is dissolved in a solution
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colligative properties
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change as a result of the concentration of solute particles but are independent of the nature of the solute
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freezing point depression
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a colligative property that drops in freezing point of a solution when a solute is added
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