Chapter 15: Energy and Chemical Change – Flashcards

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the study of energy changes that occur during chemical reactions and changes in state
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Thermodynamics
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energy stored in chemical bonds
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Chemical Potential Energy
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When breaking bonds, it uses (costs) energy. When creating bonds, it releases (gives) energy.
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Energy exchange
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A mixture or compound
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What has a higher potential energy than an element?
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Heat released.
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Exothermic
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Heat gained
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Endothermic
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H
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Enthalpy is what letter?
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S
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Entropy is what letter?
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G
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Gibb's Free Energy is what letter?
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A system wants to decrease its energy, which is stressful to hold.
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What is the principle of natural order?
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At constant pressure, a change in enthalpy equals the energy flow as heat
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Enthalpy definition
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Endothermic
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If heat is added to the right of an equation, it is. . .
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Exothermic
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If heat is added to the left of an equation, it is. . .
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Exothermic
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-ΔH ("If Delta H is negative")
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Endothermic
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+ΔH ("If Delta H is positive")
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A law used to determine the ΔH of a problem by combining several more manageable equations into one.
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Hess' Law
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ΣΔHd (reactants) - ΣΔHd (products) ("The Sum of the change of the empalthy of the dissociation energies of the reactants minus the The Sum of the change of the empalthy of the dissociation energies of the products")
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What is the equation to find a ΔH?
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The tendency for all things in the universe to go into chaos.
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Entropy definition
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The Universe is becoming constantly more chaotic.
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The Second Law of Thermodynamics
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Reaction occurs automatically and quickly
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Spontaneity
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Reaction occurs only with energy and often occurs slowly.
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Non-Spontaneity
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S*Solid < S*Liquid << S*Gas
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What is the order of the spontaneity of the phases of matter?
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A mixture of gases
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What is more entropic than a binary gas?
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Enthalpy
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What fights Entropy?
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Entropy
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What fights Enthalpy?
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ΣΔS (products) - ΣΔS (reactants)
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What is the equation for ΔS?
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Spontaneity
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What does a large ΔS favor?
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Non-Spontaneity
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What does a small ΔS favor?
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Gibb's Free Energy Equation
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What equation does one use to figure out "fo-sho legit" what is the spontaneity?
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It becomes spontaneous
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What happens when you flip a non-spontaneous reaction?
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Non-spontaneous
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-ΔG means?
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Spontaneous
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+ΔG means?
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