Chemistry Chapter 12 Test Questions – Flashcards

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Heterogeneous Mixture:
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compositon not uniform
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Homogeneous Mixture
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composition uniform throughout
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Soluble:
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ability of being dissolved
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Solution
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homogeneous mixture of two or more substances
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Solvent
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Dissolving medium in a solution(thing its dissolved in)
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Solute
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substance dissolved in solution(Dissolv-ie)
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When a solution is passed through filter paper with the individual components seperate?
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no, usual not b/c uniformed throughout
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Solutions can happen in gasses, liquids, and solids? T or F
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True
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Alloys:
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solid solutions in which atoms of two or more metals are uniformly mixed
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Does changing the proportions of each metal in the alloy create wanted properties?

Take gold, if mixed with copper and silver will it be stronger?

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yes

yes

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Suspension
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particles in solvent so large they settle unless mixture is constantly stirred
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Colloids
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mixture formed by particles that are perfectly sized(not to big or small)
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Do colloidal particles seperate when filtered?
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no, b/c small enough
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Dispersed phase:
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colloidal particles
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Dispersing medium:
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water
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Sol
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Solid Dispered in liquid

 

paints, mud

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Gel
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solid network extending throughout liquid

 

gelatin

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Liquid Emulsion
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liquid dispered in a liquid

 

milk, mayo

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Foam
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gas dispered in liquid

 

shaving cream, mousse

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Solid Aerosol
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solid dispered in gas

 

smoke, auto exhaust

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Liquid Aerosol
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liquid dispered in gas

 

fog, mist, clouds

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Solid Emulsion
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liquid dispered in solid

 

cheese, butter

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Properties of solutions:
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  • Homogeneous
  • particle size(0.01-1 atm);can be atoms, ions, molecules
  • Don't seperate on own
  • cant be seperated by filtering
  • dont scatter light
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Colloid properties:
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  • Heterogeneous
  • particle size 1-1000 nm, dispersed; can be aggregates of lrg molecules
  • dont seperate on own
  • cant be seperated by filtration
  • scatter light(Tyndall effect)
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Suspension properties:
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  • Heterogeneous
  • particle size over 1000 nm, suspended; can be lrg particles or aggregates
  • particles settle on own
  • can be filtered
  • may scatter light, but not transparent

;

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Tyndall Effect
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when light is scattered by colloidal particles dispersed in a transparent medium
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Brownian Motion
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when particles are seen moving when light is shone upon them at a right angle
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What happens to the negative and positive ions when an ionic compound is dissolved?
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seperate from eachother and get surrounded by water molecules
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Describe the process in which an ionic compund enables a solution to conduct electric current.
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When dissolves, compounds positive and negative ions seperate causing them to be surrounded by the H2O molecules. These ions are then free to move, enabling electric current to pass through
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Electrolyte
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substance that dissolves in water to give a solution that conducts electric current
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Can certain high polar molecular compunds be electrolytes?
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yes. look at HCl
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A substance that dissolves in water to give a solution that doesnt conduct electric current is called a(n):
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nonelectrolyte
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An apparatus glows brightly. The solution is:

a)semiconductor

b)electrolyte

c)non electrolyte

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b
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Ways that affect the rate of dissolution are:
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  • increase surface area
  • Stirring
  • heating
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Is there a limited amount of a solid solute to solvent combination at a given T that can dissolve?
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yes
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solution equillibrium:
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physical stare in which the opposing processes of dissolution and crystalization of a solute occur at = rates
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A solution that contains the max. amnt of dissolved solute is:
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saturated solution
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A solution that contains less solute than a saturated solution under the exsisting conditions is a(n):
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unsaturated solution
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Supersaturated solution is when:
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a solution contains more dissolved solute than a saturated solution contains under same conditions. So if substance is heated so everythng is dissolved, is then coolde, naturally it will seperate, however w/o disturbance it wont seperate
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solubility of substance:
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amnt of that substance required to form a saturated solution w/ specific amnt of solvent at a specified temp
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"Like dissolves like" means:
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similar substances, such as types of bonding, polarity, etc. are capable of dissolving on another.

Rouch general rule. not true for sure!

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Why doesthe polarity of the water molecules play such and important role in formation of solutions w. ionic compounds?
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b/c the slightly charges particles of water attract ions from ionic compund, therefore causing them to seperate from the crystal(aka dissolving)
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Hydration:
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is the solution process w/ water as the solvent
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What is ment when you say "the ions are hydrated" ?
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means that the hyrdated h20 ions are drwing ionic compounds ions away from crystal resultion in dissolution
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What are hydrates?
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crystalline compunds that incorperate water molecules and maintain same ratios throughout
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Whats an immiscible liquid?
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Liquids that are not soluble in eachother.

;

look at some PB and salad dressings. Its the seperation!

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nonpolar substances with nonpolar liquids are:

a) soluble

b)insoluble

c)mixed but unevenly; not uniform

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a. NP have london Disperssion forces =; relativly weak =; molecules from both substances free to intermingle and mix
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Liquids that dissolve freely in one another in any proportion are _______.
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miscible
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Pressure effects solubility very little for:

a)Solids

b)Liquids

c)Gasses

d) Solids ; Liquids

e) Liquids and Gasses

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d
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Explain process in which P effects solubility.
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By ^P it puts stress on the equillibrium, therefore more collisions =; faster rate b/w evaporation and dissolving = equillibrium reached at higher gas solubility
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The solubility of a gas in a liquid is directly proportional to the partial P of that gas on the surface of the liquid is____ ____. Which applies to G-L solutions 2 constant T
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Henrys Law
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That is a perfect example of EFFERVESCENCE in your everyday life?
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opening a can of soda. the rapid escape of G from L in which it is dissolved. thats the tssstttt sound when u open a can! this is what causes the 'fizzy-ness'
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Which is easier to predict?

Effects ofSolubility on L and S. or just G?

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G
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Solvated:
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a solute particle that is surrounded by slvent molecules
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Enthalpy of solution:
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net amnt of E absorbed as heat by the solution when a specific amnt of solute dissolves in solvent
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If enthalpy of solution is___ then the rxn is ____.

a) positive; ____

b) negative; ____

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a) exo

b) endo

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When is E released in enthalpy of solution for gasses?
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when a G dissolves in L b/c attraction b/w solute gas and solvent molecules outweighs the E needed to seperate solvent molecules
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The ___________ of a solution is a measure of the amnt of solute in a given amnt of solvent or solution
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concentration
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Molarity is:
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the # moles of solute in one L of solution
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________ is the concentration of a solution expressed in moles of solute per kilogram of solvent
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Molality
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