Chemistry Semester 1 Study Guide – Flashcards

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7 types of chemistry
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Organic Chemistry Inorganic Chemistry Physical Biochemistry Analytical Medicinal Pharmaceutical
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Organic Chemistry
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deals with elements containing carbon (which is pretty much everything living)
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Inorganic Chemistry
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deals with noncarbon compounds and non-living matter.
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Physical Chemistry
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deals with the relations between the physical properties of substances and their chemical formations along with their changes.
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Biochemistry
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deals with the composition and changes in the formation of living species.
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Analytical Chemistry
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deals mostly with the composition of substances.
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Pharmaceutical
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chemistry behind pharmaceutical preprations.
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Medicinal Chemistry
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study of structure-activity relationship, pharamacological activities.
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What is the difference between hypothesis theory and law?
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Law- Exact rule Hypothesis- May or may not be occur Theory- similar to law but not exclamatory
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Two types of Mater
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Mixtures and Pure Substances
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Two types of Mixtures
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Heterogeneous and Homogeneous
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Two types of Pure Substances
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Element and Compound
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Heterogeneous
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You can differentiate different parts (visibly/with a microscope)
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Homogeneous
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Solution; can't differentiate between materials
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Element
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Just a pure, simple element
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Compound
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Contains more than one element 2 or more different elements chemically bonded together
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3 ways to separate mixtures
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Filtration Distillation Chromatography
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Filtration
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To separate heterogeneous mixtures
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Distillation
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To separate homogeneous mixtures
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Chromatography
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To separate volatile gasses
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Solid, liquid, and gas on a molecular level
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solid- molecules are tightly compacted and do not move liquid- molecules able to move around but not completely freely gas- molecules able to move freely and fast
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Law of Conservation of Matter
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In Chemical reactions, mass in the beginning and mass after are same, mass is neither lost nor gained
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Law of Definite Properties
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Elements in compound are present in fixed proportions by weight (e.g. Water is always H₂O)
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Law of Multiple Proportions
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Many elements combine in more than one ratio (e.g. H₂O water is 2:1, H₂O₂ is Hydrogen Peroxide 1:1)
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Physical properties
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Does not change chemical identity or make-up
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Examples of Physical properties
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Melting Point Boiling Point Color Taste (e.g. Whether Nitrogen freezes of Boils it is still nitrogen)
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Solubility
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Process or Extent to which a solute (the one being devolved) dissolves in a solvent (one doing the dissolving)
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Solubility example question: (487g sugar dissolves completely in 100g water at 100°C, and 247g dissolves in 100g water at 20°C, How much water does it take to devolve 100g of sugar at 100°C)
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Solubility example answer: (100g sugar × (100g water/487g sugar) = 20.5 grams of water) (If cooled to 20°C: 20.5g water × (204g sugar/100g water) = 41.8g if sugar is in the water and the remaining 58.2 crystalizes)
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4 Types of Solubility
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Saturated Unsaturated Supersaturated Crystallization (Ex. a solution that is saturated at 30g sugar/100g sugar is instead mixed with 35g sugar/100g water. So, when shaken, some of the mixture crystallizes. To find the amount, (35/100) - (30/100) = 5g sugar crystallizes)
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Saturated (Solubility)
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completely disolved
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Unsaturated (Solubility)
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not enough solute
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Supersaturated (Solubility)
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too much solute
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Crystallization (Solubility)
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mixture tries to correct imbalance
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Density
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Doesn't matter the amount of something density is still the same. Density decreases as temperature increases. D=m/v (Density = mass / volume)
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10⁶ [Give metric prefix]
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Mega (M)
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10³ [Give metric prefix]
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Kilo (k)
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10² [Give metric prefix]
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hecto (h)
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10¹ [Give metric prefix]
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deka (d)
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10⁻¹ [Give metric prefix]
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Deci (d)
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10⁻² [Give metric prefix]
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centi (c)
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10⁻³ [Give metric prefix]
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milli (m)
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10⁻⁶ [Give metric prefix]
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micro (μ)
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10⁻⁹ [Give metric prefix]
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nano (n)
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10⁻¹² [Give metric prefix]
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pico (p)
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Precision (for measurements)
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(basically) how many decimal places your measurement has (e.g. 4.125 is more precise than 4.1)
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Accuracy (for measurements)
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how well your measurement agrees with right (or defined) answer
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Leading Zeros (Significant Digits) [are significant or not significant]
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not significant (e.g. in 0.00025 only 2 and 5 are significant)
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Captive Zeros (Significant Digits) [are significant, not significant, or both]
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are significant (e.g. 1.008 or 1105, in both all # are significant)
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Trailing Zeros (Significant Digits) [are significant, not significant, or both]
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both [Explanation: When number does not have a decimal (150) = not significant, but when number does (1.0500), trailing zeros are significant]
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Addition and Subtraction (with Significant Digits)
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Result can only contain as many decimal places as number with least decimal places
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Multiplication and Division (with Significant Digits)
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Result can only have as many significant digits as number with least amount of significant digits. (501× 25 = 12500 but = 1.3×10⁴ because 25 only has 2 significant digits)
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Temperature °F to °C (conversion)
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T°F = (9/5*T°C) [T stands for Temperature]
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Temperature °C to °F (conversion)
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T°C = (5/9)(T°F-32°) [T stands for Temperature]
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How to get temperature K (conversion
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T°K = T°C + 273.15
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Absolute zero
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0 K (on the Kelvin scale) [also: −273.15 °C (on the Celsius scale) −459.67 °F (on the Fahrenheit scale) ]
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Democritus (state his Theory)
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indivisible particles, atoms from atoms
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Aristotle (state his Theory)
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matter is infinitely divisible; 4 elements (earth, wind, fire, water)
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Lavosisier (who is he)
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the father of modern analytical chemistry
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Dalton Atomic Theory (4)
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(a) elements are made from atoms (b) Atoms of an element are the same mass (except for isotopes) (c) Atoms of different elements have different masses (except for isobars) (d) Atoms combine in small number ratios (1:1, 1:2)
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Components of the Atom
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Electrons, Protons, Nutrons (discovered in that order)
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A cathode ray
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an electron beam
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Molar Mass
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(Molar Mass =) Atomic weight of an element, converted to grams (e.g. Molar Mass of ¹⁵⁹⁹⁴O = 15994 grams)
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Calculating Atomic Mass from Isotopes with abundances
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Multiply each of the Isotope's weight by their abundances, and add [Ex. Oxygen exists in 3 isotopes ¹⁶O (99.76%), ¹⁷O (.04%), and ¹⁸O (.2%) 16(.9976) + 17(.0004) + 18(.002) = 16amu]
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Calculate Isotope Abundance
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(Set up algebraic equation): mass of element = isotope1 weight(x) + isotope weight 2(x-1) [Ex. Oxygen (atomic mass = 15.9994amu) exists in 3 isotopes with masses 15.9949amu, 16.9993amu, and 17.9992amu occurring .204%: • 15.9994 = 16.9993x + 15.9949(1-x) + 17.9992(.00204) • 15.9582 = 16.9993x + 15.9949 - 15.9949x • -.0367 = 1.0044x • x = 3.65% = O^ 16.9993 • O^15.9949 = 100% - 3.65% -.204% = 99.76% * each orbital can contain a maximum of 2 electrons, so S can have 2, P can have 6, D can have 10]
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Aufbau Principle
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Electrons fill energy positions from lowest to highest
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Hund's rule
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when filling orbitals with in an energy sub level, electrons fill orbital signally before pairing
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Pauli Exclusion Rule
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No two electrons in a given atom can possess the same set of four quantum numbers, opposite
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All the sublevels in order
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1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p
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