chem 111 study guide – Flashcards

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sig fig zeros
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1. zeros at beginning NOT signif 2. zeros between ARE SIGNIF 3. zeros at end of number are signif if number contains a decimal point
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3.489 x (5.67-2.3)
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3.489 x 3.(3)7 11.75793 12
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matter
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composed of mass and must occupy space
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scales of matter
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macroscopic, microscopic, particulate. scientists think on a particulate scale, observe macroscopically
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states of matter
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1. change from solid to liquid to gas as temp increases 2. motion of particles increase as temp increases 3. distance between particles increases as temp increases
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matter
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-pure substance 1. element 2. compound -mixtures 1. homogeneous 2. heterogeneous
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physical properties
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the atoms or molecules in the matter do not change (color, taste, melting point, boiling point, odor, density)
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chemical properties
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molecules react, composition of matter changes (flammability, oxidation, corrosiveness)
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physical changes
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appearance change but not comp (change in state, change in shape)
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chemical changes
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chem reaction occurs, so comp changes... reactants and products
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mass is always conserved
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matter can not be created nor destroyed
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energy
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the other main component of our universe, if something has energy it can do work
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energy is also conserved
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it can be transformed or converted to a different form but the total energy stays the same
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4 energy types
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kinetic potential chemical electrical
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calorie
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amount of energy to raise temp of 1 gram of water by 1 degree Celsius
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1 calorie = ? J
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4.184 J = ? cal
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energy and chemical changes
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1. chemical reactions often have associated energy changes 2. reactions that give off heat = exothermic (burning) 3. reactions that absorb heat = endothermic (chem ice pack)
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as temp increases the movement of the atoms or molecules in the substance increase
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-move fastest in gas phase -molecules in a solid don't move they just vibrate around a fixed point
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heat is...
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a transfer of energy between 2 temps
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physical changes require...
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energy
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liquid to gas is
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endothermic, water is gaining energy from the surroundings
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gas to liquid is
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exothermic, heat is given off
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water melts
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273 K
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water boils
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373 K
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heat capacity
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1. all substances change temp when they absorb and give off heat (the amount of change varies between substances) 2. heat capacity shows how much energy needed to raise temp of a substance 1 degree cel 3. water has a very high heat capacity (changing temp has a lot of energy)
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Dalton
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-each element made of indivisible particles called atoms -all atoms of a single element have the same mass which are different from other elements -atoms combine in single whole ratios to form compounds
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Thompson
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found the electron -plum pudding model -believed subatomic particles made up atoms
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Rutherford and gold foil
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shot alpha particles at gold foil and predicted that all would pass through, some bounced back!
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a real atom...
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1. mostly empty space 2. dense core of protons and neutrons 3. cloud of electrons
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to sum up the sizes of p, e, n
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protons and neutrons have almost identical masses and make up the positive nucleus while electrons have almost no mass and a negative charge
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amu
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100 amu = 1/12 carbon 12 atom
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matter is usually neutral
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number of electrons and protons are equal
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elements are defined by # of protons
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aka atomic number
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atoms do vary in mass
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mass number = protons and neutrons (the nucleus)
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isotope
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different number of neutrons
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left v. right
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metals on left. non metals on right. staircase with metalloids on either side
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1A
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alkali metals, lose 1 electron
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2A
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alkaline earth metals, lose 2 electron
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3A
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lose 3 electrons (except B)
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5A
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gain 3 electrons
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6A
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gain 2 electrons
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7A
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halogens, gain 1 electron
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8A
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noble gases
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protons-electons=
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charge
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Ag is always
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+1
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Zn is always
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+2
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how do ions form?
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atoms can form ions by gaining or losing electrons
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main group elements what does group # represent?
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group # represents # of outer electrons
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diatomic molecules
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Br, O, H, F, Cl, I, N
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cation
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positive ion
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ion
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charge elements
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anion
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negative ion, have an ide ending
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transition elements...
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can form more than one ion, if so this is designated with roman numerals
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compounds are represented by chemical formulas
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formula has symbol for each element with a subscript for # of atoms
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chemical formulas start with the most metallic elements first
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move from left to right. H position is unpredictable, depends on compound.
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molecular
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no metal elements
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ionic
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have a metal
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molecular/ non metal
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use prefixes if more than one of an element is present. mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca
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ionic / metal
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2 types. 1. the charge of the metal is known 2. the charge of the metal is unknwon
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ionic, charge known
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1A, 2A, most of 3A. just say it how it is
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ionic, charge NOT known
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use roman numerals for metals that can have different charges. the positive charges on the metal equal to the negative charge on the group 7A/8A element
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chromium (III) oxide
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Cr3+ does NOT = O2- so cross multiply, must have 2Cr and 3O so that they both total 6, so Cr2O3
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polyatomic ions
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more than one element forms an ion, these atoms move as a unit, just like the single element ions
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using polyatomic ions
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use parentheses, to keep the ion together if it is multiplied
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polyatomic ions with hydrogen in the name
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they have one more H, and one less charge than the parent ion
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polyatomic ions ate vs. ite
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ate has one more Oxygen than ite
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