Chem 101 Exam 1 – Flashcards

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what two items is chemistry concerned with?
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matter and energy
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example of physical property
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melting point
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chemical properties
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changed by interactions with another substance, like rust
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two kinds of pure substances
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elements and compounds
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compounds
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more than one element in a compound, molecules
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about how many elements exist on earth?
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90
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most of the atoms in the body are...
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oxygen
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life is what based?
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carbon
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how does the periodic table categorize elements?
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by certain physical chracteristics
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degrees C= (5/9) times (degrees F -32)
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(5/9) times (degrees F -32)
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density =
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mass/ volume
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precision
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measure of reproducibility
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accuracy
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how close is a measurement to the true value
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Democrates
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idea of atoms
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Milliken
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measured the charge on an electron
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Roeutgen
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Cathode-ray tube
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Becquerel
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radioactivity
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Rutherford
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gold foil experiment, angular distribution of particles
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isotopes
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atoms with the same number of protons
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isotones
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atoms with equal number of neutrons
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isobars
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atoms that have the same weight (number of protons + number of neutrons)
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(X) ^=A, =N
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A = mass number, Z = protons, N = neutrons
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arrangement based on number of protons in nucleus
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periodic table
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columns in the periodic table
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have similar properties
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diatomic molecule example
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H2
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triatomic molecule examples
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H2O or HCN
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simplest formula
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empirical formula, smallest whole number ratios of atoms in a molecule
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molecular formula
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shows the actual number of atoms in the compound
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structural formulas
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shows the arrangement and connections of atoms in a molecule
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ions
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atoms that have fewer or more electrons present than protons
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stoiciometry
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quantitative relationships in Chemistry
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law of conservation of mass (energy)
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atoms are neither created or destroyed in any chemical process
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atomic weight
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a relative mass scale that relates one kind of atom to that of a specific kind of atom (Carbon 12)
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1 mole
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is the amount of substance that contains avogadros number entities
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avogadros number
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6.022 times 10 ^23
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way to figure out molecular formula from elemental percentages
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element, relative mass of element (out of 100g), relative number of atoms, divide by smallest number, convert to whole #... to find molecular formula MW/FW
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percent yield
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actual yield/ theoretical yield
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solution
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homogeneous mixture at the molecular level between 2 or more substances
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solute
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minor component that is dissolved in the other component
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solvent
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major component that something dissolves in
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molarity
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number of moles solute/ number of liters solution
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volume 1 times molarity 1=
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volume 2 times molarity 2
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electrical conduction
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movement of ions in aqueous solution -> the strength of conduction is proportional to the tendency of the solute to ionize
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dissociation
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process by which a solid ionic compound separates into ions in a solution
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ionization
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process by which a molecular compound separates into ions in a solution
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anions
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negatively charged ion
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cations
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ions that have a positive charge
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types of strong electrolytes
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strong acids, strong bases, salts
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strong acids
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completely ionize in dilute solutions
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Strong acids
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HCl, HBr, HI, HNO3, HClO4, HClO3, H2SO4
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are strong bases soluble?
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yes
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strong bases...OH and
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first column, not hydrogen and second row Ca(OH)2, Sa(OH)2, and Ba(OH)2
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how many salts are there?
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LOTS
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acid
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substance that produces H+ in aqueous solutions
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salt
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compound that contains a cation other than H+ and an anion other than OH- or O2-
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base
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substance that produces OH- in aqueous solutions
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most salts are
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strong electrolytes
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total ionic equation
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shows the predominate form of all species of in aqueous solution
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net ionic equation
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cancel spectator ions from total ionic equation
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combustion reactants
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A+B -> C, two reactants are going to produce one product
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decomposition reaction
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C-> A + B,
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metathesis reactions
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ionic reactions which involve the removal of ions from the solution AX + BY -> AY + BX
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three types of metathesis reactions
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precipitation, produce soluble/ weak/ or non-electrolyte (neutralization reaction), gas formation (acid-base reactions)
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displacement reactions
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only metals considered. one element replaces another in a compound
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displacement reactions equations
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(more active metal) + (salt of less active metal) -> (less active metal) + (salt of more active metal)

AND

(active metal) + (non-oxidizing acid) -> H2(g) + (salt of the acid)
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redox reactions
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reactions involving either oxidation or reduction
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oxidation
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redox reaction with a loss of electrons
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reduction
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redox reaction with a gain of electrons
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oxidation numbers
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book-keeping chore to keep track of e transfer in chemical reactions
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oxidation numbers
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+1(electron), +2 -> (B) +3, +/-4, -3, -2, -1(electron) (F)
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sum of oxidation numbers of all atoms in a compound =
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charge on the compound or ion
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what changes in redox reactions?
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oxidation numbers
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how to use table 4.5
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metal found higher in the table will displace the metal ion from the salt of another metal found lower in the table
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solution stoiciometry
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chemical equations relate the mols of product sand reactants regardless of whether they are in solution or not
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titration
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method which is used to assay the concentration solutions
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soluble compounds
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compounds containing NO3-, CH3COO-, Cl-, Br-, I-, SO4^2-
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most easily oxidized...
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use table in book
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the gold foil experiment performed in Rutherford's laboratory...
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lead to the discovery of the atomic nucleus
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how many protons, neutrons, and electrons are in an ion?
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protons on periodic table, neutrons are atomic weight minus number of protons, electrons are number of protons minus the charge
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