Chem 101 final exam – Flashcards
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Ionic Compound
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a compound composed of positive and negative ions that are combined so that the numbers of positive and negative charges are equal
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Covalent Compound
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a chemical compound formed by the sharing of electrons
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The Ideal Gas Law
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PV = nRT. Tells you how a gas responds to a change in its physical conditions. change P, V or T, and the others adjust
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Stoichiometry
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that portion of chemistry dealing with numerical relationships in chemical reactions; the calculation of quantities of substances involved in chemical equations
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Electrolytes
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chemical substances that develop an electric charge and are able to conduct an electric current when placed in water; ions
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Strong Acids
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HCl, HBr, HI, HNO3, HClO4, H2SO4 Dissociates completely in water
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Weak Acids
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HF, HCN, HC2H3O2, H2S, H2CO3, HClO Doesn't dissociate completely in water
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Net Ionic Equation
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an equation for a reaction in solution showing only those particles that are directly involved in the chemical change
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Spectator Ions
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ions that do not take part in a chemical reaction and are found in solution both before and after the reaction
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Acid
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a substance that increases the hydrogen ion concentration of a solution
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Base
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eat protons consume H+ ions when fin water metal hydroxides are the most common
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1st Law of Thermodynamics
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The principle of conservation of energy. Energy can be transferred and transformed, but it cannot be created or destroyed.
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2nd Law of Thermodynamics
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entropy of the universe is always increasing
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Kinetic Energy
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energy of motion
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Potential Energy
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energy stored due to an object's position or arrangement
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the amount of thermal energy emitted or absorbed by a chemical reaction, under conditions of constant pressure
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Endothermic Reaction
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a chemical reaction accompanied by the absorption of heat
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Exothermic Reaction
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a reaction that releases energy in the form of heat
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Specific Heat
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the heat required to raise the temperature of one gram of a substance one degree centigrade
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Wavelength
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The distance between crests of waves, such as those of the electromagnetic spectrum. Lambda
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Speed
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v symbol
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Frequency
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Mu symbol u
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The Bohr Model
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Bohr proposed that an electron is found only in specific circular paths, or orbits, around the nucleus.
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3 Quantum Numbers
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n=size l=shape and m=position
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Paui Exclusion Principle
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no Two electrons in the same atom can have the same quantum numbers No more than two electrons of the opposite spin in an orbital
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Aufbau Principle
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states that each electron occupies the lowest energy orbital available
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Hund's Rule
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orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all electrons in singly occupied orbitals must have the same spin
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Ionization Energy
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the energy required to remove an electron from a gaseous atom; generally increases in moving from left-to-right across a period and decreases in moving down a group
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3 Situations that Violate the octet rule
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1. An odd number of electrons 2. More than 8 electrons (PCL5, SF6) 3. Fewer than 8 electrons (Be, B, and Al)
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Formal Charge
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The charge assigned to an atom in a molecule or poly atomic ion, Molecules containing atoms with lower formal charges tend to be more stable than those with higher formal charges
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Resonance
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condition that occurs when more than one valid Lewis structure exists for the same molecule
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Bond Energies
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The energy that is required to break a bond Bond Breaking is Endothermic (Negative outcome)
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VSEPR
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Valence shell electron pair repulsion theory; because electrons repel; molecules adjust their shapes so molecules can be as far apart as possible
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Electron Domain Geometry
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the arrangement of electron domains about the central atom Lone Pairs and Bonding Pairs
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Electron Domain Geometry 2 Domains
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Linear 180 degree angles
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Electron Domain Geometry 3 Domains
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Planar Triangular 120 degree angles
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Electron Domain Geometry 4 Domains
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Tetrahedral 109.5 degree angles
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Electron Domain Geometry 5 Domains
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Trigonal Bipyramidal 120,90, and 180 degree angles
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Electron Domain Geometry 6 Domain
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Octahedral 90, and 180 degree angles
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Molecular Geometry
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the geometry of a molecule or ion described by the bonded atoms. it does not include the unshared pairs of electrons.
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Molecular Geometry 3 Bonded Pairs, 1 lone pair
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Trigonal Pyramidal 109.5 degree angles
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Molecular Geometry 2 Bonded Pairs, 2 lone pairs
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Angular or Bent 109.5 Degree angles
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Molecular Geometry 4 Bonded Pairs, 0 lone pairs
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Tetrahedral 109.5 degree angles
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Molecular Geometry 5 Bonded Pairs, 0 lone pairs
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Trigonal Bipyramidal 120,90,and 180 degree angles
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Molecular Geometry 4 Bonded pairs, 1 lone pair
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Seesaw 120,90, and 180 degree angles
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3 Bonded pairs, 2 lone pairs
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T-shaped 90, and 180 degree angles
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2 bonded pairs, 3 lone pairs
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Linear 180 degree angles
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6 bonded pairs, 0 lone pairs
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Octahedral 90, and 180 degree angles
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5 Bonded pairs, 1 lone pair
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Square Pyramidal 90 degree angles
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4 Bonded Pairs, 2 Lone pairs
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Square Planar 90 Degree angles
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Polarity
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uneven distribution of charges in a molecule Often when there is a lone pair, it is polar When a molecule is not surrounded by the same element equallly it is polar
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Sigma Bond
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a single covalent bond that is formed when an electron pair is shared by the direct overlap of bonding orbitals
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Pi Bond
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A bond formed when parallel p orbitals overlap creating two regions of electron density, one above and one below the internuclear axis. Formed when there is a double bond or triple, etc
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Orbital Hybridization
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The combination of atomic orbitals to form a set of equivalent hybrid orbitals.
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Valence Bond Theory
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An advanced model of chemical bonding in which electrons reside in quantum-mechanical orbitals localized on individual atoms that are a hybridized blend of standard atomic orbitals; chemical bonds result from an overlap of these orbitals.
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Intermolecular Forces
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the forces of attraction between molecules In order from Weakest to strongest 1. London Dispersion 2. Dipole-induced dipole 3.Dipole-dipole (Hydrogen Bonds) 4. Ion-dipole 5. Ion-Ion
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Viscosity
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a measure of a fluid's resistance to flow
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Surface Tension
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the result of an inward pull among the molecules of a liquid that brings the molecules on the surface closer together