Organic and Bio chem cumulative Final – Flashcards

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How do you name substituants and hydrocarbon chains?
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alphabetical WITHOUT existing prefixes
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how many degrees in a tetrahedral carbon?
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109°
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VESPR theory states that carbon compounds will form bonds that are...?
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as far apart as possible
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what is NH??
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an amine
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carbon atoms in saturated hydrocarbons...
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have ONLY single bonds
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organic compound with double or triple bonds are classified as? saturated or unsaturated?
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unsaturated compounds
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hydrogenation of 2-butene?
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CH?-CH?-CH?-CH?
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first step when drawing a compound?
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draw the carbon chain
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alkene contains what?
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both atoms of a double bond
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true or false: isomers have the same molecular formula?
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TRUE
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what type of structure does methane have?
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tetrahedral
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true or false: light induced cis-trans isomerization is an important step in vision?
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true
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true or false: functional groups are groups of atoms that act in predictable ways
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true
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true or false: hydrogenation is used to convert alkenes and alkynes to alkanes
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true
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true or false: hydrogenation of unsaturated vegtable oils raise the melting point and make them solid
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false.
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carbonyl groups consist of what?
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carbon-oxygen double bond
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conversion between a and b anomers is called?
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mutarotation
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ethylene glycol and methanol are toxic because they are?
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oxidized by the liver
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aldehydes have higher boiling points than alkanes of similar mass because of what?
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dipole-dipole
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sugars react with what to form hemiacetals?
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themselves.
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tertiary alcohols oxidized to form?
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none of the above
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under acid hydrolysis conditions, startch is converted to what?
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glucose
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hydrogen bonding is the strongest or weakest?
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strongest
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celluolse is not digestible by humans because it contains glucose units linked by ?
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B-1,4
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true or false: heptanol is water soluble?
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false
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true or false: glucose forms a cyclic hemiacetal
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true
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true or false: the product of oxidation of an aldose is a corboxilic acid
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true
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true or false: phenols behave as weak acids in water
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true
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true or false: enantiomer do not have different tastes/smells.
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false, they are different
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true or false: 2-butanol is a chiral molecule
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true
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true or false: sucrose is a disaccharide
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true
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what is the name of a nine carbon continuous chain alkane?
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nonane
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what determines the family name and chemical reactivity of the organic compound?
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functional group
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the reaction of butane with oxygen is called?
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combustion
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carbon atoms always have how many covalent bonds?
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4
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a hydrocarbon contains only the elements:
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carbon and hydrogen
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the balanced equation for the complete combustion of C5H12 will give which of these products?
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5CO2 + 6H20
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the funcitonal group contained in the compound CH3CH2NH2 is an:
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amine
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The IUPAC name of CH3CH=CHCH3 is:
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2-butene
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the carbon atoms in saturated hydrocarbons:
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have only single bonds
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organic compounds with double and triple bonds are classified as:
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unsaturated compounds
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long chain molecules that consist of many repeating units are called:
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polymers
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what is the condensed structural formulafor the product of the hydrogenation of 2-butene using a platinum catalyst?
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CH3CH2CH2CH3
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a compound that contains a benzene ring is called?
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aromatic compound
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how many isomers are there in dibromobenzene?
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5
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organic chemistry is the study of?
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the chemistry of carbon compounds
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products of the complete combustion are?
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CO2 AND H20
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isomers have the same:
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molecular formula
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when naming an alkane, the main chain is the longest chain regardless of bonds.
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...
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true/false: in a cis group, groups are on the same side of the double bond.
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true
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true/false: hydrogenation is used to convert alkenes to alkynes and alkanes.
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true
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in a tertiary alcohol, how many alkyl groups are attached to the carbon atom bonded to the -OH group?
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3
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the reduction of monosaccharides produces:
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sugar alcohols
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when 2-methyl-2-butanol undergoes dehydration in acid, one product is:
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2-methyl-2-butene
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how do sugars form cyclic hemiacetals?
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a molecule of sugar acts with ITSELF
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tertiary alcohols are oxidized to form? secondary alcohols aldehydes carboxylic acids ketones none of the above
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none of the above
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how to determine an ether?
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has an O in the middle of the longest chain
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chirality occurs when stereoisomers have mirror images that are:
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not superimposable
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under acid hydrolysis conditions, starch is converted to:
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glucose
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aldehydes and ketones may be reduced to:
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alcohols
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how many different substituants are required on carbon atom for it to be chiral?
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4
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what intermolecular force is strongest between individual molecules of ALCOHOLS?
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hydrogen bonding
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in a dissaccharide, two monosaccharides join together by what type of bond?
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glycosidic
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a glycosidic bond between two monosaccharides can also be classified as an:
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ether bond
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the compound CH3-CH2-SH is in the organic family known as:
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thiols
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the sugar also known as dextrose and blood sugar is:
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glucose
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true/false: heptanol is a water soluble alcohol:
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false
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true/false: sucrose is a dissacharide:
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true
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true/false: alcohols form hydrogen bonds; this accounts for their higher boiling points when compared to similar sized alkanes
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true
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the splitting apart of an ester in the presence of a strong acid in water is called:
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hydrolysis
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commercially, liquid vegetable oils are converted to solid fats such as margarine by:
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hydrogenation
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what kind of intermolecular bonding occurs between CARBOXYLIC ACIDS?
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hydrogen bonding
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why do carboxylic acids have higher boiling points that similar alcohols of aldehydes?
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they form dimers that are relatively stable
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what is the name of the structure formed when a soap coats on oily particle to make it water soluble?
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micelle
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the products of the acid catalyzed hydrolysis of a triglyceride are:
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fatty acids and glycerol
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a triacylglycerol that is solid at room temp is called:
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fat
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compared to saturated fatty acids, unsaturated fatty acids have? (higher or lower melting points)
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lower melting points
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true/false: sodium benzoate is a common preservative.
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true
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true/false:the interior of a lipid bilayer is the hydrophillic region
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false
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true/false: the tail of a triacylglycerol is the nonpoar end
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true
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true/false: carboxylic acids are strong acids.
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false, they are weak.
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true/false: the catalyst needed for saponification is H+ ion.
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false
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true/false: polyesters are plastics that are used to make fabrics, bottles, and medical devices such as heart valves.
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true
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true/false: soaps are salts of long chain fatty acids
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true
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true/false: long chain carboxylic acids are also known as fatty acids
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true
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true/false: in the fluid-mosaic model of cell membranes, the lipid molecules are oriented with their heads to the outside of the membrane.
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true
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true/false: many sex hormones are steroids.
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true
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diethylamine and HCL react to produce?
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diethylammonium chloride
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which of the following cannot form hydrogen bonds with water?
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ch3ch2ch3
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what kind of amine can NOT for hydrogen bonds?
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tertiary
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amides having fewer than ______ carbons are generally water soluble.
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6
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amino acids that are not synthesized in the body and must be obtained from the diet are called:
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essential
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in what kind of amine is the nitrogen directly bonded to two carbon atoms?
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secondary
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the peptide bonds that combine amino acids in a protein are
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amine bonds
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which of the following compounds is an amine?
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(CH3CH2)2NH
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heat denatures a protein by disrupting:
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hydrophobic bonds and hydrogen bonds
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amines are:
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bronsted lowry bases
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the structual formula of amino acids are the same except for:
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the side R group
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physiologically active nitrogen containing compounds produced by plants are called:
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alkaloids
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denaturation of a protein:
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disrupts the secondary, tertiary, or quaternary structure of a protein
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one heavy metal that can cause denaturation of a protein is:
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silver
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cyclic compounds that contain a nitrogen atom are called:
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heterocyclic compounds
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a chain made of more than 50 amino acids is usually referred to as a:
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protein
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the interactions that are important in the secondary structure of a protein are:
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hydrogen bonds
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what type of interaction would you expect between the following R groups in the tertiary structure of a protein?
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salt bridges
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what kinds of interactions are not part of tertiary protein structures?
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peptide bonds
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in response to an allergic reaction or injury of cells...
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histamine
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aniline:
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primary aromatic amine
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which of the following is NOT a function of proteins?
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stores genetic info of a living organism
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which of the following is an example of a secondary protein structure?
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helix
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true/false: disulfide bonds stabilize the tertiary structure of a protein.
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true
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true/false: caffine is not an alkaloid.
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false
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true/false: neurotransmitters are chemicals that transmit a nerve impulse.
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true
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true/false:crack coccaine is produced by the neutralization and extraction of cocaine from its hydrochloride
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true
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true/false: the peptide structure gly-gly-gly gives the primary structure of a tripeptide.
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...
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true/false:when amides are hydrolyzed in acidic solution the products are an ammonium salt and a carboxylic acid
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false
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true/false: lead ions disrupt hydrophobic interactions.
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false
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true/false: upon hydrolyze, the dipeptide abbreviated as gly-lys will yield the same products.
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true
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true/false: zwitterions have an overall positice charge.
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false
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which of the following cannot be found in a nucleotide of RNA?
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deoxyribose
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the polymerase chain reaction is used in:
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DNA fingerprinting
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a _________ consists of a nitrogen containing base, a sugar, and a phosphate
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nucleotide
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metal ions such as Zn2+ and Fe3+ are often needed by enzymes as:
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cofactors
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the hydrolysis of ester bonds in triglycerides is catalyzed by:
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a lipase
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the general function of an enzyme in the body is to:
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catalyse chemical reactions
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lock and key model of enzyme action, the enzyme active site is thought of as:
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a rigid, nonflexible, shape that fits the substrate.
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what is the process of DNA double helix unfolds, and each strand serves as a template for the synthesis of a new strand?
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replication
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when a substrate bonds to an enzyme for reaction its place of bonding is the:
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active site
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which statement is true?
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thymine and adenine are a complementary base pair that forms 2 hydrogen bonds.
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when DNA replicates, a guanine forms a base pair with:
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cytosine
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which of the following is NOT a step in protein synthesis?
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unwinding of two strands of mRNA.
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a virus that contains RNA as its genetic material is a
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retrovirus
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which of the following is found in RNA but not DNA?
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uracil
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which of the following is NOT a step in the enzyme-catalyzed conversion of a substrate to product?
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the substrate changes its shape so it can bind at the active site.
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how many generalized steps are there in the reaction of an enzyme?
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3
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the function of the enzyme-substrate complex is to provide an alternative reaction pathway that:
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decreases the activation energy for the reaction
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an irreversible inhibitor is one that:
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binds covalently to the enzyme active site.
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the B vitamins are examples of:
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water soluble vitamins
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the optimum temperature for sucrase activity is 37° C. hydrolysis of sucrose is SLOWEST at:
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0° C.
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some sections of DNA molecules do not code for protein synthesis. these segments are called:
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introns
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in the study of genetics, PCR means:
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polymerase chain reaction.
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a _______ consists of a nitrogen-containing base and sugar.
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nucleoside
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the bonds that link the base pairs in DNA double helix are:
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hydrogen bonds
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translation is the process whereby
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protein is synthesized from mRNA.
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when mRNA is synthesized using the info from DNA?
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transcription
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PH 7 and 37°
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reactions for the body
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true/false: enzymes cofactors are always metal ions, such as Zn2+ and Fe3+
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false
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true/false: a nucleotide consists of only a base and a sugar.
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false
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true/fa;se: insulin and digestive enzymes are produced as inactive forms called zymogens.
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true
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true/false: DNA is a protein.
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false
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true/false: aniline transaminase is an example of a transferase enzyme.
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true
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true/false:mRNA is the smallest unit of RNA.
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false
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true/false: if DNA double helix in humans contains 20% guanine, the percentage of adenine is 30%.
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true
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true/false: DNA fingerprinting is not yet used to detect genes for cancer
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false
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true/false: enzymes always require a cofactor.
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false
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true/false: Urease is an example of an oxidoreductase enzyme.
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false
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