FINALAMENTE – Flashcards

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nitric acid
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HNO3
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phosphoric acid
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H3PO4
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Hydrogen Sulfate Ion
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HSO4-
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lactic acid
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C3H6O3
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Acetic acid
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CH3COOH
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Carbonic acid
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H2CO3
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Boric acid
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H3BO3
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hydrocyanic acid
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HCN
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Sodium Hydroxide
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NaOH

 

 

 

(base)

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Ammonia
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NH3

 

(base)

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1KWh = how many kJ; how many MJ?
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3600 kJ; 3.6 MJ
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what is a calorie?
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the energy needed to raise the temperature of 1 g of water by 1° C/K
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1 cal =
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4.184 J
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BOYLE'S LAW def
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Pressure and volume are inversely proportional, when the temperature and # moles are constant
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BOYLE'S LAW
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P1V1=P2V2= nRT at constant temp.
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CHARLE'S LAW def
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Volume and temp. are directly proportional when the pressure and number of moles are constant
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CHARLE'S LAW
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V1/T1 = V2/T2 = nR/P at constant pressure
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AVAGADRO's LAW def
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equal volumes of gas at the same temp. and pressure contain the same # of molecules
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AVAGADRO's LAW

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V1/n1 = V2/n2 = RT/P
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STP
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T=273° K; P=1atm
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standard molar volume
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22.4 L
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ideal gas law
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PV= nRT
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ethanol
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C2H5OH
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Ionic bond
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metal + nonmetal; transfer of e's takes place
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Covalent bond
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sharing of electrons;;uses prefixes
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Phosphate
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PO43-
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Nitrate
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NO3-
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Kinetic Molecular Theory
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;

  1. Large distance between particles
  2. Particles move in straight lines
  3. Kinetic energy is conserved
  4. Particles are tiny compared with distance btwn them

;

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Intermolecular bonds in order of strength
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Hydrogen

Dipole-dipole

Dispersion

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Intensive
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the amount does not matter, ex: temp
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Extensive
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the amount matters, ex: mass
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hydrogen bonds
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btwn H and strongly electroneg. atoms (O,N,F)
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dipole-dipole bonds
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btwn any 2 polarm molecules
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physical property
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properties that can be observed without changing the nature of the substance (ie: tasting an apple)
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dispersion/london forces
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nonpolar but temporary delocalization of electrons;;

although weak, many of them, keep liquid/solid together

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Anode
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positively charged electrode where oxidation occurs;
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Cathode
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negatively charged electrode where reductions occurs
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Ions: def/types
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atom(s) that carry a charge

;

ANIONS: negative

CATIONS:positive

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Dalton's postulates
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all elements are made of small indivisable particles:atoms

 

all atoms have almost identical (chemical) properties

 

atoms combine in whole number ratios to form compounds

 

atoms can't be created or destroyed in a chemical reaction

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prefixes
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1:mono, 2:di, 3:tri, 4:;tetra, 5:penta, 6:hexa, 7:hepta, 8:;octa, 9:nona, 10:deca
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When oxidation occurs, energy is usually________.
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released
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OIL-RIG
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Oxidation: electons/energy is lost

;

Reduction: electrons/energy is gained

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For reactions with oxygen, oxygen is always...
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reduced
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OXIDATION
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;electrons LOST;

hydrogen atoms lost;

gain of oxygen atoms

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A reducing agent is...
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a compound that gets oxidized
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atomic # is the _______
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# of protons OR #electrons
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How were electrons discovered?
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Crookes tubes- produced streams called cathode rays.
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Group 1
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Alkali metals
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Group 2
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Alkali earth metals (soapy)
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Group 6A
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Chalogens (most stable on earth)
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Group 7A
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Halogens (salt generators)
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SI units for mass
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grams; kg=1000g;;

;

mg=1/1000 g

;

;g=1/106 g

;

ng= 1/109 g

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pg= 1/1012 g

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Reduction
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the addition of hydrogen to a substance;

;

the gain of electrons

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Some catalysts used when hydrogen is added to a compound
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Pd (palladium)

Ni (nickel)

Pt (platinum)

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Acids are...
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proton donors.
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Bases are...
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proton acceptors.
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Weak acids produce...
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a relatively small fraction of the maximum number of possible hydronium ions.

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Period v.s. Group
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period = Row, across, in the periodic table.

;

group = verticle grouping, columns

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Sig.figs
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Leading zeroes are NOT sig.

;

Trailing zeroes after the decimal point ARE.

;

Internal zeroes ARE.

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Whole numbers ending in zeroes are ambiguous;

solved by placing a . or converting to scientific notation

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Exact numbers
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no uncertainty; infinate # of significant figures
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xRAYs
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Alpha = 2+ positive; 4g

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Beta= 1- negative; 1/2000 g

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Gamma= neutral; no mass

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isotopes def.
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atoms with the same number of protons, but different number of neutrons

;

;

(same place on periodic table)

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Ground state; Realxation
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ground state: when the electrons stay close to nucleus

;

;

relaxation: after excitation, the electrons come close

again; energy is given back during this state

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How do you find the # possible electrons per orbit level?
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2n2

;

n being the orbit level

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When electrons jump from a higher to lower orbit,
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there is an emission of light.
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Ag is...
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Silver; always 1+
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Zinc always has a charge of
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2+
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Naming covalent compounds
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Most Metallic element is first (CO2)

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Oxygen is always last.

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Use prefixes!

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ends in -ide.

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Guessing polarity based on electronegativity scale
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NONpolar: difference is ; 0.5

;

polar: 0.5 ; difference ;2

;

ionic: if difference is ; 2

;

;

the higher the EN#, the more love for electrons; the higher EN is the neg. end and the lower is the + end.

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carbonate
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CO32-
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Lewis formulas (HONC)
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hydrogen has 1 bond

oxygen has 2 bonds

nitrogen has 3

carbon has 4

;

if there are several atoms the least electronegative will be in the cener (except H)

;

distribute to peripheral e's first, then central

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free radical
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have odd # of electrons; very reactive
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electron geometry v.s. molecular shape
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each pair of e's = an electron set

*a double bond counts as 1 set

;

;

E.G refers to central atom, bonding; nonbinding

;

M.S. refers to bonded atoms ; 3Dshape

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electron domain
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1 pair of electrons, bonding or nonbinding; could be a;double bond; a triple bond
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Avagadro's #
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6.022 x 1023 atoms
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Molar mass v.s. formula mass
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molar mass is in g/mol

 

formula (molecular) mass is in amu

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Stoichiometry
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In balenced chemical equations: A,B, and C are equivalent

 

A+B =C

 

A/B is an ex: the stoichiometric factor

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temperature
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measure of kinetic energy of atoms and molecules INSIDE an object

 

kelvin is the SI unit. 

K° = C° + 273°

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Exothermic
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heat is produced; hot to the touch
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Endothermic
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Heat is required for the process; feels cold to the touch
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photovoltaic energy is derived from
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the sun; solar converted to electrical energy
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intRAmolecular forces v.s. intERmolecular
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A. what keeps atoms together in molecules;

covalent and ionic bonds

 

B. what keeps molecules together

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electrolytes
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solutions of ionic substances that conduc electricity

 

 

if dissociation is complete: they're strong electrolytes

if dissociation is partial: they're weak electrolytes

if no dissociation, they're NONelectrolytes

;

not all ionic substances are soluble ; not all soluble substances are electrolytes

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ion-dipole interaction
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in solutions of polar solvent + ionic solute, the STRONG force between the dipoles of solvent and the ions
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ANHYDRIDES
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react with water to form acids/bases

;

metal oxides are basic anhydrides

nonmetal oxides are acidic anhydrides

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How are antioxidants recuding agents?
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They prevent the oxidation of other* molecules in the body by being oxidized themselves.
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convert grams --> mol
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divide by molar mass
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mol --> grams
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multiply by molar mass
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