Chemistry exam ch 14 – Flashcards
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catalyst
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a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change
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chemical equilibrium
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the state in which both reactants and products are present in concentrations which have no further tendency to change with time
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equilibrium constants
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the name of the value of the reaction quotient when the reaction has reached equilibrium
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equilibrium expression
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When the reaction quotient, or in this deifnition - the equilibirum constant (K) - is in equilibrium
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Haber process
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an industrial process for producing ammonia from nitrogen and hydrogen, using an iron catalyst at high temperature and pressure
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heterogeneous equilibrium
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when all reagents and products are found in different phases (solid, liquid, or gas)
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homogeneous equilibrium
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when all reagents and products are found in the same phase (solid, liquid, or gas)
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LeChatelier's principle
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can be used to predict the effect of a change in conditions on chemical equilibrium
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reaction quotient, Q
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aids in figuring out which direction a reaction is likely to proceed, given either the pressures or the concentrations of the reactants and the products; is not in equilibrium
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Differences between equilibrium and reaction quotient
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The difference between the reaction quotient and the equilibrium constant is that, at a given temperature, the equilibrium constant has only one value and it specifies the relative amounts of reactants and products at equilibrium. The reaction quotient, by contrast, depends on the current state of the reaction and has many different values as the reaction proceeds.
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In a reaction mixture containing only reactants, the reaction quotient is.... (0/x), where x is some number
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Q = 0
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In a reaction mixture containing only products, the reaction quotient is.... (x/0), where x is some number
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Q = infinity
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In a reaction mixture containing both reactants and products, each at a concentration of 1 M
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Q = 1
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equilibirum shift
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When dynamic equilibrium is disturbed, related to the Chatelier's principle, there is a tendency to reestablish equilibrium.