Chemistry 111 Test Questions – Flashcards
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Atom & composition |
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-basic unit of an element that can enter into a chemical combination -composed of protons, neutrons, and electrons |
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Protons(charge and mass) |
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- (+) or +1 - m=1837 times that of an electron - actual mass= 1.673 x10^(-24) |
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Electron(charge and mass) |
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-(-) or -1 - mass=9.110x10^(-28) - mass=1/1837 of a H atom |
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Ions (names of (+/-)) |
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- cations- (+) - loses electrons -anions- (-) - gains electrons |
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Atomic number is the number of.. |
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- number of protons |
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Mass number is the number of.. |
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- protons and neutrons |
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Isotopes |
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- atoms with the same number of protons/atomic# but has different mass numbers |
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Atomic weight |
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- average mass of all naturally occuring isotopes of that element - takes into account relative abundance of the elements isotopes |
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Percent abundance |
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- % of atoms of a natural sample of the pure element represented by a particular isotope to describe isotope composition for an element |
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Periodic Table (horiz/vert) |
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- Horizontal- period - Vertical- group |
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Group 1A |
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- alkali metals - very reactive -shiny solids that react vigorously with air, water, |
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Group 2A |
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- alkaline earth metals - not quite as reactive - react with water to form alkaline solutions |
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Group 6A |
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- chalogens |
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Group 7A |
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- halogens |
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Group 8A |
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- noble gases - rare gases/ inert gases - least reactive elements |
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Representative elements |
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- main group elements - group number followed by letter A |
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Transition metals |
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- Group # followed by letter B |
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Lanthanides and Actinides |
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- portions of periods 6 and 7 that are below the main body |
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Metal properties |
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- good conductors of heat and electricity -high luster (shiny) - high melting point - high density - solids at room temperature (Hg- mercury- liquid) |
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Nonmetal properties |
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-poor conductors of heat and electricity - no lustrous, relative dull - low melting point and density - C, P, S, SE, I are solids -Br- liquid - the rest are gases H, N, O, F, Cl, He, Ar, Kr, Xe, Ra |
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Metalloids or semimetals |
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- intermediate between properties of metal and nonmetals - raw materials or semiconductors device that make the electronic industry possible - B, Si, Ge, Te, Sb, As, Po |
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Molecules |
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- aggregate of at least 2 atoms in a definite arrangement held together by chemical forces/ chemical bonds -smallest unit of a compound |
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Diatomic molecule |
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- 2 atoms |
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Allotropes |
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- one or two or more distinct forms of an element - differ in chemical and physical propterties |
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Covalent (molecular) compound |
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- all elements in the compund are nonmetals - contain discrete molecular units - inorganic acids -many are binary compounds (02) |
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Molecular covalent compound |
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-molecule formed by covalent bonds in which atoms share one or more pairs of valence electrons |
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Network Covalent Compound |
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- chemical compound in which atoms are bonded by covalent bonds in a continuous network (SiO2) - there are no individual molecules and the entire crystal may be considered a macromolecule |
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Molecular vs Empirical formula |
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-Molecular- shows the exact # of atoms of each element in the smallest unit of a substance -Empirical- shows the simplest whole number ratio of the atoms in a substance molecule |
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Structural Forumula |
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-shows linkage of all the atoms in the molecule |
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Condensed structural forumla |
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-lists atoms present in groups to indicate connectivity between the atoms |
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Molecular Compound naming |
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- cation first, then anion -first element listed is the one "more metal like" -prefixes are written before the name of the element to indicate # of atoms present |
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Mono, Di, Tri, deca, tetra, penta, hexa, hepta, octa, nona, deca, dodeca |
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1,2,3,4,5,6,7,8,9 |
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Molecular compound exceptions-NH3 |
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-Ammonia |
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Molecular compound exceptions-CH4 |
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-methane |
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Molecular compound exceptions-H20 |
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-water |
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Molecular compound exceptions-PH3 |
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-phosphine |
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Molecular compound exceptions-H2S |
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-hydrogen sulfide |
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Molecular compound exceptions-B2H6 |
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- diborane |
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Hydrocarbon |
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-carbon and hydrogen compounds -simplest of all organic compounds -used as fuels starting material for chemistry industry |
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How are organic compounds determined |
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-by functional groups chemically bound to parents compound |
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Functional group -OH |
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-hydroxyl group -alcohol |
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Functional group -NH2 |
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- amino group -amine |
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Functional group -COOH |
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-carbonxyl group -carboxylic acid- organic acid |
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Organic chemistry |
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-the branch of chemistry that deals with carbon compound and functional groups |
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Alkanes |
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-have no branches -*SINGLE* carbon chain/bond -formula: CnH2n+2 where n is greater or equal to 1 |
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Alkenes |
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-contains *at least one* carbon-carbon *double bond* -formula: CnH2n where n is greater or equal to 1 |
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Alkynes |
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-contain at *least one* carbon-carbon *triple bond* -formula: CnH2n-2 where n is greater or equal to 1 |
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Acid |
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-produces H+ ions in water - any substance that dissolves and dissociated into ions and one is H+ |
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Naming acids |
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- H cation called hydro- - anion with the -ide ending becomes -ic |
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Rules to writing acids |
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-write the prefix hydro- - followed by the stem of the 2nd element of the suffix add ic -add the word acid -make sure to add aqueous (aq) after the word "acid" |
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Oxoacids |
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- acids where anion is polyatomic |
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How to name Oxoacids |
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-if the ending is -ite -> change to -ous if the ending is -ate -> change to -ic - if there are more than 2 ions in the series, prefixes "hypo" (less than) and "per" (more than) are used |
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NO3- (name and oxoacidic name & formula if applicable) |
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-Nitrate -HNO3 nitric acid |
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oxoanions |
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- polyatomic ions containing oxygen - contain different numbers of oxygen -are named by the number of oxygen in the ion -if there are 2 in series, the one with more oxygen atoms ends in -ate -the one with few ends with -ite -more than 2 ions in the series, "hypo" and "per" are used |
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Ionic Compounds |
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-formed from cations and anions -species that carry a net (+) or(-) charge -most are solids with a high melting point - |
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Monatomic ion |
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-single atom ion -EX:K+, O-2, Al3+ |
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Polyatomic ion |
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- two or more ions |
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Polyatomic ion: SO42- |
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-sulfate |
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Polyatomic ion:No3- |
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-nitrate |
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Polyatomic ion: NH4+ |
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-Ammonium |
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Polyatomic ion: OH- |
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-hydroxide |
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Elements in the same group have... |
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-similar chemical and physical properties |
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A groups |
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-are the main-group elements -also called the representative elements |
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B groups |
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-are transition metals |
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Crisscross rule |
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-the subscript on the cation is numerically equal to the charge of the anion and the subscript of the anion is numerically equal to the charge of the cation |
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Polyatomic ions |
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-groups of covalently bonded ions |
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Carbonate Formula |
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CO32- |
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Hydrocarbonate or bicarbonate Formula |
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HCO3- |
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Nitrate Formula |
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NO3- |
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Permaganate Formula |
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KMnO4 |
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Phosphate Formula |
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PO43- |
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Ionic compund rules and properties |
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-formula written in the empirical -they are 3-D crystal networks -formula tells cations to anions -charges in ionic compounds MUST equal 0 |
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Chemical forumlas |
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- express the composition of molecules and ionic compounds in terms of chemical symbols -indicates number of elements and relative number of atoms in a compound -change the number in a subscript and you change the compound |
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Ionic Compound naming rules |
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-write the name of the cation -write the name of the stem for the anion and add the suffix "-ide" |
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Name the polyatomic ion: KNO3 |
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-KNO3= potassium nitrate |
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Name the polyatomic ion: Fe(OH)2 |
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- iron(II) hydroxide |
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Name the polyatomic ion: KNO2 |
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- Potassium nitrite |
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Inorganic compounds |
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- formed from more than 3 elements -one or more of the ions is polyatomic |
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Only metal liquid at RT |
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-mercury (Hg) |
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Only liquid nonmetal at RT |
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-bromine Br |
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11 gases at RT |
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-hydrogen, nitrogen, oxygen, fluorine, chlorine, helium, neon, argon, krypton, xenon, and radon |
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Naming Inorganic Compounds |
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-identify the ions -name the cations in order given and follow with the names of the anions |
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NaHCO3 |
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Sodium Hydrogen carbonate |
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NaHSO4 |
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Sodium hydrogen sulfate |
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Transition metals |
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-uses the stock |
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Stock system |
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- for transition metals -when a compound contains a metal that forms more than one cation, the charge on the cation or the metal is designated by a roman numeral immediately following the name of the metal |
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Transition metals naming rules |
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-Write the name of the cation -write the charge of the cation as roman numerals in (...) - write the stem of the anion and add "-ide" |
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Copper(II) oxide |
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-CuO |
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Iron(III) chloride |
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FeCl3 |
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Chromium(VI) sulfide |
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CrS3 |
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Classical nomenclature |
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-when a metaalic ion has only 2 types of cations, the name of the metal is modified with suffixes -ous (for the lower charge) and "-ic" (for the higher charge) |
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Covalent |
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-contain only nonmetals -are named using prefixes to indicate # of each element in the formula |
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Ionic |
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-contain monatomic and polyatomic ions -usually contain metals and nonmetals -NEVER named using prefixes -sometimes name with cation charge in roman numerals |
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n |
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Wedge-and-dash Model |
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-is a two-dimensional representation of a three-dimensional structure that can easily be drawn on paper - bonds are represented by lines (bonds that lie in the plane of the paper) -wedges (bonds that lie in front of the plane of the paper) -dashes (bonds that lie behind the plane of the paper) |
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Ball and-stick Model |
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-shows atoms as colored spheres connected by sticks that represent covalent bonds. |
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Space-filling model |
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-interpenetrating spheres represent the relative amount of space occupied by each atom in the molecule |
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Most common covalent bond categories |
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-binary nonmetals and inorganic acids |
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Binary nonmetal compounds |
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-consist of only two elements, both nonmetals - named using prefixes and -ide |
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Hydrogen peroxide |
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-H2O2 |
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Hydrazine |
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-N2H4 |
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Nitric oxide |
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NO |
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Inorganic acids |
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-form H+ ions when dissolved in water -compounds that contain hyderogen and one or more nonmetals |
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Inorganic acids are named... |
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-like binary compounds but without prefixes |
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hydrogen halides are named... gas phase...aqueous phase.... |
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-like binary compounds *when in gas form* - are named with common names when aqueous |
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Metals in Groups 1A, 2A, and 3A form.... ions and there charge is |
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-equal to the group number of the element. |
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Nonmetals in Groups 5A, 6A, and 7A form....ions and there charge is |
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-equal to 8 minus the group number of the element. |
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CN2- |
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-Cyanide |
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CH3CO2- |
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-Acetate |
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S2O3^2- |
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-Thiosulfate |