Chapter 6 Test Review – Flashcards

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question
What is the mutual electrical attraction between the nuclei and valence electrons of different atoms that bind the atoms together?
answer
Chemical bond
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Why do atoms bond together?
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To stabilize the valence shell and to decrease energy
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What type of bond results from the electrical attraction between charged atoms?
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Ionic bond
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What will be the difference in electronegativiy between the atoms involved in an ionic bond?
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1.7 or greater
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What is the term given to the positive ion?
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Cation
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What is the term given to the negative ion?
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Anion
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What type of bond results from the sharing of electrons?
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Covalent
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What are the two types of covalent bonds?
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Polar and nonpolar
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What type of covalent bond shares the electrons equally?
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Nonpolar
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What type of covalent bond does not share the electrons equally?
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Polar
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What is the difference in electronegativity between the two atoms involved in a nonpolar covalent bond?
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0-.3
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What is the difference in electronegativity between two atoms in a polar covalent bond?
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.3-1.7
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What is the term used to describe the ability of an atom to attract electrons?
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Electronegativity
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What is the neutral group of atoms that are held together by covalent bonds?
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Molecule
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Describe the importance of a chemical formula
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Chemical formulas indicate the relative numbers of atoms in each chemical compound
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What types of atoms are bonding to form a molecule?
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Nonmetal and nonmetal
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How many diatomic atoms are there? What are the names of them?
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7- H2, O2, N2, F2, Cl2, Br2, and I2
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Describe the formation of a covalent bond
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Two nonmetals share electrons to fill both of their outermost energy levels
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As bond length decreases in covalent bond, what happens to the strength (bond energy)
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It increases because the shorter the bond length, the harder it is to break
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What is the octet rule?
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Chemical compounds tend to form so that each atom has an octet of electrons in their highest energy level
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Give 4 exceptions of the octet rule
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Beryllium-4 valence
Boron-6 valence
Phosphorus-10 valence
Sulfur-12 valence
Hydrogen-2 valence
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What is the name given to the unshared pair of electrons in a lewis structure?
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Lone pair
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What is the difference between a lewis structure and a structural formula?
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Lewis structures show electron dot pairs while structural formulas show don't show unshared pairs
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What type of covalent bond involves the sharing of 1 pair of electrons? 2 pairs? 3 pairs?
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Single. Double. Triple.
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What is a formula unit?
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The simplest collection of atoms from which an ionic compound's formula can be established
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What is the relationship between ionic bond strength and lattice energy?
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Bond strength increases as lattice energy becomes more negative
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NaCl and Al2O3 are both examples of (ionic/covalent) bonds
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Ionic bonds
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(ionic/covalent) bonds have low melting and boiling points
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covalent
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(ionic/covalent) bonds are conductors in water
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ionic
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(ionic/covalent) bonds are a network of + and - ions
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ionic
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(ionic/covalent) bonds are hard and brittle solids
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ionic
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(ionic/covalent) bonds are non-conductors in water
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covalent
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H2O and CO2 are examples of (ionic/covalent) bonds
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covalent
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What is a polyatomic ion?
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A charged group of covalently bonded atoms
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What is the term used to describe the electrons of metals?
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Delocalized
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What does "delocalized" mean?
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Electrons do not belong to any one atom
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Because they don't belong to any one atom, what phrase describes a metal's electrons?
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Sea of electrons
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What are some properties of metals?
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High electrical and thermal conductivity, luster, malleable, and ductile
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Why do metals have luster?
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Metals absorb light and re-radiate this light in a frequency similar to the absorbed frequency
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What is the relationship between enthalpy of vaporization and the bond strength of metals?
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The stronger the bond, the greater the enthalpy of vaporization
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Molecular shape: linear
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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180 degrees, 2, 0.
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Molecular shape: trigonal planar
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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120 degrees, 3, 0.
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Molecular shape bent or angular:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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<120 degrees, 2, 1.
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Molecular shape tetraheadral:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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109.5 degrees, 4, 0.
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Molecular shape trigonal pyramidal:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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107 degrees, 3, 1.
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Molecular shape bent or angular with 2 lone pairs:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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104.5 degrees, 2, 2.
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Molecular shape trigonal bipyramidal:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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90 and 120 degrees, 5, 0.
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Molecular shape octaheadral:
Name the bond angle, # of atoms bonded to central atom, and # of lone pairs of electrons
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90 degrees, 6, 0.
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What does V.S.E.P.R. stand for?
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Valence Shell Electron Pair Repulsion
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What is a hybrid orbital?
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Orbitals of equal energy produced by the combination of two or more orbitals on the same atoms
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What are the three types of intermolecular forces?
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Dipole-dipole- two polar molecules
Hydrogen bonding-occurs between H and F, O, or N
London dispersion-two nonpolar molecules
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What is isomerism?
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Substances that have the same molecular formula as another substance but differ in structure
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Name four types of isomers
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Structural, geometric, positional, functional
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What happens in structural isomers?
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The carbon chain is altered
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What happens in geometric isomers?
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They differ in the arrangement around double bonds
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What happens in positional isomers?
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They differ in position of double bond or atom other than C or H
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What happens in functional isomers?
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An element other than C or H is bonded in a different way
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The hybrid sp:
Name the # of orbitals produced, bond angle, and basic shapes
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2, 180 degrees, linear
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The hybrid sp2:
Name the # of orbitals produced, bond angle, and basic shapes
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3, 120 degrees, trigonal planar.
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sp3 hybrid:
Name the # of orbitals produced, bond angle, and basic shapes
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4, 109.5 degrees, tetraheadral
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