Acids and Bases – Flashcards

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question
Write a balanced equation for the dissociation of the Bronsted-Lowry acid HSO4- in water.
answer
HSO4-(aq) + H2O(l) <--> SO4^2-(aq) + H3O+(aq)
question
What is the concentration of the hydronium ions in a neutral solution?
answer
1.0 x 10^-7
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What is the hydronium ion concentration of a 0.1 M hypochlorous acid solution with Ka= 3.5 x 10^-8? The equation for the dissociation of hypochlorous acid is: HOCl(aq) + H2O(l) <--> H3O+(aq) + OCl-(aq)
answer
5.9 x 10^-5
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A 25.0 ml sample of .105 M HCl was titrated to the equivalence point with 31.5 mL of NaOH. What is the concentration of the NaOH?
answer
.0833 M
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What are the conjugate acid-base pairs in the following chemical reaction: NH3(aq) + H2O(l) <--> NH4+(aq) + OH-(aq)
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NH3, NH4+ and H2O, OH-
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The pH of .255 M HCN is 4.95. What is the value of Ka for hydrocyanic acid?
answer
4.9 x 10^-10
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What is the hydronium ion concentration of acid rain sample that has a pH of 3.15?
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7.08 x 10^-4 M
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In order for a solution to be acidic: A) [H3O+] = [OH-] B) [H3O+] < [OH-] C) pH = pOH D) [H3O+] > [OH-] E) None of the above
answer
D
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What is the concentration of hydronium ions in a solution given that the concentration of hydroxide ions is 2.31 x 10^-4 M?
answer
4.33 x 10^-11 M
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What is the strongest monophonic acid of the following set if all the acids are at 0.100 M concentration? A) hydrofluoric acid with Ka = 3.5 x 10^-4 B) hypochlorous acid with Ka = 3.5 x 10^-8 C) acetic acid with Ka = 1.8 x 10^-5 D) benzoin acid with Ka = 6.5 x 10^-5
answer
A
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Which Brønsted-Lowry acid has the strongest conjugate base? A) HF B) HClO4 C) HI D) HBr
answer
A
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A 35.0 mL sample of .225 M HBr was titrated with 42.3 mL of KOH. What is the concentration of the KOH?
answer
0.186 M
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Which solution below has the highest concentration of hydronium ions? A) pH = 7.00 B) pH = 9.82 C) pH = 7.93 D) pH = 3.21 E) pH = 12.6
answer
D
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Indicate all the Brønsted-Lowry acids in the following chemical reaction: HCl(aq) + H2O(aq) <--> H3O+(aq) + Cl-(aq)
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HCl, H3O+
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The Bronsted-Lowry definition of a base is:
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A proton acceptor
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An aqueous solution contains 0.10 M NaOH. The solution is A) very dilute B) Neutral C) basic D) acidic E) highly colored
answer
C
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Which of the following is not an acid-base conjugate pair? A) H2S and OH- B) H2CO3 and HCO3- C) NH4+ and NH3 D) H2O and OH- E) none of the above
answer
H2S and OH-
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Which of the following Brønsted-Lowry acids does not behave as a strong acid when it is dissolved in water? A) HClO4 B) HCl C) HNO2 D) HBr
answer
HNO2
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The magnitude of Ka indicates that:
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Water auto-ionizes only to a very small extent
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Nitric acid is a strong acid. This means that A) aqueous solutions of HNO3 contain equal concentrations of H+(aq) and OH-(aq) B) HNO3 produces a gaseous product when it is neutralized C) HNO3 does not dissociate at all when it is dissolved in water D) HNO3 cannot be neutralized by a weak base E) HNO3 dissociates completely to H+(aq) and NO3-(aq) when it dissolves in water
answer
E
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In the following reaction: HCO3-(aq) + H2O(aq) -> H2CO3(aq) + OH-(aq) A) H2O is an acid and HCO3- is its conjugate base B) HCO3- is an acid and OH- is its conjugate base C) H2O is an acid and H2CO3 is its conjugate base D) HCO3- is an acid and H2CO3 is its conjugate base E) H2O is an acid and OH- is its conjugate base
answer
E
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What solution below has the highest concentration of hydroxide ions? A) pH = 12.49 B) pH = 10.12 C) pH = 7.93 D) pH = 7.00 E) pH = 3.21
answer
A
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The Arrhenius definition of an acid is:
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Produces H+ in solution
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The Bronsted-Lowry definition of an acid is:
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A proton donor
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What is the equilibrium constant expression (Ka) for the acid dissociation of hydrocyanic acid HCN? The equation of interest: HCN(aq) + H2O(l) <--> H3O+(aq) + CN-(aq)
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Ka = ([H3O+][CN-]/[HCN])
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What is the hydroxide ion concentration of a lye solution that has a pH of 11.20?
answer
1.58 x 10^-3
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In the following reaction: NH4+(aq) + H2O(aq) -> NH3(aq) + H3O+(aq) A) H2O is a base and NH3 is its conjugate acid B) Nah4+ is an acid and H2O is its conjugate base C) NH4+ is a base and H2O is its conjugate acid D) NH4+ is an acid and H3O+ is its conjugate base E) H2O is a base and H3O+ is its conjugate acid
answer
E
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The pH of 0.150 M CH3CO2H, acetic acid, is 2.78. What is the value of Ka for acetic acid?
answer
1.9 x 10^-5
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In which of the following aqueous solutions does the weak acid exhibit the lowest percentage ionization? A) .01 M HNO2 (Ka = 4.5 x 10^-4) B) .01 M HClO (Ka = 3.0 x 10^-8) C) .01 M HC2H3O2 (Ka = 1.8 x 10^-5) D) .01 M HF (Ka = 6.8 x 10^-4) E) These will all exhibit the same percentage ionization
answer
B
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Calculate the pH for an aqueous solution of pyridine that contains 2.15 x 10^-4 M hydroxide ion.
answer
10.33
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What is the pH of a .020 Ba(OH)2 solution?
answer
12.6
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In a solution that has a pH = 7.0, A) [H3O+] > [OH-] B) [H3O+] + [OH-] = Kw C) [H3O+] < [OH-] D) [H3O+] = [OH-] E) none of the above
answer
D
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What is the second stepwise equilibrium constant expression for phosphoric acid H3PO4?
answer
Ka2 = ([H3O+][H2PO4-])/([H3PO4])
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What is the value of the ion product constant for water (Kw) at 25*C?
answer
1.0 x 10^-14
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At 25*C, the pH of a vintage solution is 2.60. What are the values [H3O+] and [OH-] in the solution?
answer
2.5 x 10^-3 M, 3.98 x 10^-12 M
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The pH of a solution is 5.00. Which of the following is TRUE about the solution? A) it's [H3O+] is 1.0 x 10^5 M B) it's [H3O+] is 1.0 x 10^-5 M C) it's [H3O+] is 1.0 x 10^-9 D) it's more acidic than a solution whose pH is 4.00 E) none of the aboce
answer
B
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What is the pOH of a solution that has a OH- concentration equal to 1.3 x 10^-10 M?
answer
9.88
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What statement is most consistent for an acid with a pH = 3? A) one hundred times as strong as an acid with a pH = 5 B) one one-hundredth as strong as an acid with a pH of 5 C) twice as strong as an acid with a pH of 5 D) half a strong as an acid with a pH = 5
answer
A
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What is the hydronium ion concentration of a 0.100 M acetic acid solution with a Ka = 1.8 x 10^-5? The equation for the dissociation of acetic acid is: CH3CO2H(aq) + H2O(l) <--> H3O+(aq) + CH3CO2-(aq)
answer
1.3 x 10^-3 M
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What is the [H+] in a solution that has pH of 3.35?
answer
4.5 x 10^-4 M
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What is the pH of a solution prepared by diluting 25.00 mL of 0.10 M HCl with enough water to produce a total volume of 100.00 mL?
answer
1.60
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Calculate the pH for an aqueous solution of acetic acid that contains 2.15 x 10^-3 M hydronium ion.
answer
2.67
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Which of the following acids is diprotic? A) H2SO4 B) HNO3 C) HI D) HClO4 E) none of the above
answer
H2SO4
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What is the concentration of the hydroxide ion given that the concentration of the hydronium ion is 1.5 x 10^-5 M?
answer
6.7 x 10^-10 M
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Using the data in the table, which of the conjugate bases below is the weakest base? HOAc: Ka = 1.8 x 10^-5 HC7H5O2: Ka = 6.3 x 10^-5 HNO2: Ka = 4.5 x 10^-4 HF: Ka = 6.8 x 10^-4 CHOICES: A) OAc- B) F- C) NO2- D) C7H5O2
answer
B
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