Organic Chemistry 343 – Flashcards
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E and Z
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E: trans- Z: cis-
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R and S
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R: Clockwise order S: Counter-clockwise order
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X2 Addition (Br, Cl) Regio/stereo-chemistry
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Regiochemistry: N/A Stereochemistry: Anti
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Halohydrin Formation (-X and -OH addition) Regio/stereo-chemistry
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Regiochemistry: Markovnikov (for -OH addn) Stereochemistry: Anti
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Catalytic Hydrogenation Regio/stereo-chemistry
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Regiochemistry: N/A Stereochemistry: Syn
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H2O addition (cat. H3O+) Regio/stereo-chemistry
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Regiochemistry: Markovnikov Stereochemistry: Syn & Anti
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Oxymercuration/Reduction Regio/stereo-chemistry
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Regiochemistry: Markovnikov Stereochemistry: Syn & Anti
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Hydroboration/Oxidation (H2O addn.) Regio/stereo-chemistry
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Regiochemistry: Anti-Markovnikov Stereochemistry: Syn
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Hybroboration/Oxidation mechanism
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http://www.kshitij-iitjee.com/Study/Chemistry/Part2/Chapter2/79.jpg
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HX Addition (No ROOR) (HCl, HBr, HI) Regio/stereo-chemistry
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Regiochemistry: Markovnikov Stereochemistry: Syn & Anti
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HBR radical addition (w/ ROOR) Regio/stereo-chemistry
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Regiochemistry: Anti-Markovnikov Stereochemistry: Syn & Anti
