Chemistry 111 Test Questions – Flashcards
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| Atom & composition |
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| -basic unit of an element that can enter into a chemical combination -composed of protons, neutrons, and electrons |
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| Protons(charge and mass) |
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| - (+) or +1 - m=1837 times that of an electron - actual mass= 1.673 x10^(-24) |
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| Electron(charge and mass) |
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| -(-) or -1 - mass=9.110x10^(-28) - mass=1/1837 of a H atom |
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| Ions (names of (+/-)) |
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| - cations- (+) - loses electrons -anions- (-) - gains electrons |
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| Atomic number is the number of.. |
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| - number of protons |
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| Mass number is the number of.. |
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| - protons and neutrons |
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| Isotopes |
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| - atoms with the same number of protons/atomic# but has different mass numbers |
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| Atomic weight |
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| - average mass of all naturally occuring isotopes of that element - takes into account relative abundance of the elements isotopes |
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| Percent abundance |
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| - % of atoms of a natural sample of the pure element represented by a particular isotope to describe isotope composition for an element |
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| Periodic Table (horiz/vert) |
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| - Horizontal- period - Vertical- group |
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| Group 1A |
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| - alkali metals - very reactive -shiny solids that react vigorously with air, water, |
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| Group 2A |
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| - alkaline earth metals - not quite as reactive - react with water to form alkaline solutions |
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| Group 6A |
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| - chalogens |
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| Group 7A |
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| - halogens |
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| Group 8A |
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| - noble gases - rare gases/ inert gases - least reactive elements |
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| Representative elements |
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| - main group elements - group number followed by letter A |
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| Transition metals |
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| - Group # followed by letter B |
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| Lanthanides and Actinides |
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| - portions of periods 6 and 7 that are below the main body |
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| Metal properties |
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| - good conductors of heat and electricity -high luster (shiny) - high melting point - high density - solids at room temperature (Hg- mercury- liquid) |
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| Nonmetal properties |
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| -poor conductors of heat and electricity - no lustrous, relative dull - low melting point and density - C, P, S, SE, I are solids -Br- liquid - the rest are gases H, N, O, F, Cl, He, Ar, Kr, Xe, Ra |
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| Metalloids or semimetals |
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| - intermediate between properties of metal and nonmetals - raw materials or semiconductors device that make the electronic industry possible - B, Si, Ge, Te, Sb, As, Po |
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| Molecules |
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| - aggregate of at least 2 atoms in a definite arrangement held together by chemical forces/ chemical bonds -smallest unit of a compound |
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| Diatomic molecule |
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| - 2 atoms |
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| Allotropes |
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| - one or two or more distinct forms of an element - differ in chemical and physical propterties |
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| Covalent (molecular) compound |
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| - all elements in the compund are nonmetals - contain discrete molecular units - inorganic acids -many are binary compounds (02) |
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| Molecular covalent compound |
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| -molecule formed by covalent bonds in which atoms share one or more pairs of valence electrons |
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| Network Covalent Compound |
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| - chemical compound in which atoms are bonded by covalent bonds in a continuous network (SiO2) - there are no individual molecules and the entire crystal may be considered a macromolecule |
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| Molecular vs Empirical formula |
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| -Molecular- shows the exact # of atoms of each element in the smallest unit of a substance -Empirical- shows the simplest whole number ratio of the atoms in a substance molecule |
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| Structural Forumula |
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| -shows linkage of all the atoms in the molecule |
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| Condensed structural forumla |
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| -lists atoms present in groups to indicate connectivity between the atoms |
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| Molecular Compound naming |
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| - cation first, then anion -first element listed is the one "more metal like" -prefixes are written before the name of the element to indicate # of atoms present |
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| Mono, Di, Tri, deca, tetra, penta, hexa, hepta, octa, nona, deca, dodeca |
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| 1,2,3,4,5,6,7,8,9 |
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| Molecular compound exceptions-NH3 |
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| -Ammonia |
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| Molecular compound exceptions-CH4 |
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| -methane |
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| Molecular compound exceptions-H20 |
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| -water |
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| Molecular compound exceptions-PH3 |
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| -phosphine |
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| Molecular compound exceptions-H2S |
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| -hydrogen sulfide |
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| Molecular compound exceptions-B2H6 |
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| - diborane |
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| Hydrocarbon |
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| -carbon and hydrogen compounds -simplest of all organic compounds -used as fuels starting material for chemistry industry |
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| How are organic compounds determined |
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| -by functional groups chemically bound to parents compound |
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| Functional group -OH |
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| -hydroxyl group -alcohol |
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| Functional group -NH2 |
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| - amino group -amine |
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| Functional group -COOH |
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| -carbonxyl group -carboxylic acid- organic acid |
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| Organic chemistry |
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| -the branch of chemistry that deals with carbon compound and functional groups |
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| Alkanes |
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| -have no branches -*SINGLE* carbon chain/bond -formula: CnH2n+2 where n is greater or equal to 1 |
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| Alkenes |
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| -contains *at least one* carbon-carbon *double bond* -formula: CnH2n where n is greater or equal to 1 |
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| Alkynes |
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| -contain at *least one* carbon-carbon *triple bond* -formula: CnH2n-2 where n is greater or equal to 1 |
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| Acid |
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| -produces H+ ions in water - any substance that dissolves and dissociated into ions and one is H+ |
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| Naming acids |
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| - H cation called hydro- - anion with the -ide ending becomes -ic |
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| Rules to writing acids |
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| -write the prefix hydro- - followed by the stem of the 2nd element of the suffix add ic -add the word acid -make sure to add aqueous (aq) after the word "acid" |
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| Oxoacids |
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| - acids where anion is polyatomic |
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| How to name Oxoacids |
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| -if the ending is -ite -> change to -ous if the ending is -ate -> change to -ic - if there are more than 2 ions in the series, prefixes "hypo" (less than) and "per" (more than) are used |
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| NO3- (name and oxoacidic name & formula if applicable) |
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| -Nitrate -HNO3 nitric acid |
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| oxoanions |
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| - polyatomic ions containing oxygen - contain different numbers of oxygen -are named by the number of oxygen in the ion -if there are 2 in series, the one with more oxygen atoms ends in -ate -the one with few ends with -ite -more than 2 ions in the series, "hypo" and "per" are used |
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| Ionic Compounds |
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| -formed from cations and anions -species that carry a net (+) or(-) charge -most are solids with a high melting point - |
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| Monatomic ion |
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| -single atom ion -EX:K+, O-2, Al3+ |
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| Polyatomic ion |
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| - two or more ions |
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| Polyatomic ion: SO42- |
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| -sulfate |
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| Polyatomic ion:No3- |
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| -nitrate |
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| Polyatomic ion: NH4+ |
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| -Ammonium |
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| Polyatomic ion: OH- |
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| -hydroxide |
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| Elements in the same group have... |
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| -similar chemical and physical properties |
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| A groups |
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| -are the main-group elements -also called the representative elements |
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| B groups |
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| -are transition metals |
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| Crisscross rule |
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| -the subscript on the cation is numerically equal to the charge of the anion and the subscript of the anion is numerically equal to the charge of the cation |
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| Polyatomic ions |
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| -groups of covalently bonded ions |
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| Carbonate Formula |
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| CO32- |
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| Hydrocarbonate or bicarbonate Formula |
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| HCO3- |
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| Nitrate Formula |
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| NO3- |
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| Permaganate Formula |
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| KMnO4 |
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| Phosphate Formula |
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| PO43- |
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| Ionic compund rules and properties |
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| -formula written in the empirical -they are 3-D crystal networks -formula tells cations to anions -charges in ionic compounds MUST equal 0 |
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| Chemical forumlas |
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| - express the composition of molecules and ionic compounds in terms of chemical symbols -indicates number of elements and relative number of atoms in a compound -change the number in a subscript and you change the compound |
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| Ionic Compound naming rules |
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| -write the name of the cation -write the name of the stem for the anion and add the suffix "-ide" |
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| Name the polyatomic ion: KNO3 |
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| -KNO3= potassium nitrate |
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| Name the polyatomic ion: Fe(OH)2 |
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| - iron(II) hydroxide |
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| Name the polyatomic ion: KNO2 |
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| - Potassium nitrite |
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| Inorganic compounds |
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| - formed from more than 3 elements -one or more of the ions is polyatomic |
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| Only metal liquid at RT |
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| -mercury (Hg) |
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| Only liquid nonmetal at RT |
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| -bromine Br |
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| 11 gases at RT |
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| -hydrogen, nitrogen, oxygen, fluorine, chlorine, helium, neon, argon, krypton, xenon, and radon |
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| Naming Inorganic Compounds |
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| -identify the ions -name the cations in order given and follow with the names of the anions |
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| NaHCO3 |
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| Sodium Hydrogen carbonate |
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| NaHSO4 |
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| Sodium hydrogen sulfate |
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| Transition metals |
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| -uses the stock |
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| Stock system |
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| - for transition metals -when a compound contains a metal that forms more than one cation, the charge on the cation or the metal is designated by a roman numeral immediately following the name of the metal |
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| Transition metals naming rules |
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| -Write the name of the cation -write the charge of the cation as roman numerals in (...) - write the stem of the anion and add "-ide" |
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| Copper(II) oxide |
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| -CuO |
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| Iron(III) chloride |
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| FeCl3 |
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| Chromium(VI) sulfide |
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| CrS3 |
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| Classical nomenclature |
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| -when a metaalic ion has only 2 types of cations, the name of the metal is modified with suffixes -ous (for the lower charge) and "-ic" (for the higher charge) |
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| Covalent |
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| -contain only nonmetals -are named using prefixes to indicate # of each element in the formula |
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| Ionic |
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| -contain monatomic and polyatomic ions -usually contain metals and nonmetals -NEVER named using prefixes -sometimes name with cation charge in roman numerals |
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| n |
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| Wedge-and-dash Model |
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| -is a two-dimensional representation of a three-dimensional structure that can easily be drawn on paper - bonds are represented by lines (bonds that lie in the plane of the paper) -wedges (bonds that lie in front of the plane of the paper) -dashes (bonds that lie behind the plane of the paper) |
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| Ball and-stick Model |
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| -shows atoms as colored spheres connected by sticks that represent covalent bonds. |
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| Space-filling model |
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| -interpenetrating spheres represent the relative amount of space occupied by each atom in the molecule |
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| Most common covalent bond categories |
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| -binary nonmetals and inorganic acids |
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| Binary nonmetal compounds |
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| -consist of only two elements, both nonmetals - named using prefixes and -ide |
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| Hydrogen peroxide |
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| -H2O2 |
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| Hydrazine |
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| -N2H4 |
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| Nitric oxide |
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| NO |
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| Inorganic acids |
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| -form H+ ions when dissolved in water -compounds that contain hyderogen and one or more nonmetals |
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| Inorganic acids are named... |
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| -like binary compounds but without prefixes |
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| hydrogen halides are named... gas phase...aqueous phase.... |
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| -like binary compounds *when in gas form* - are named with common names when aqueous |
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| Metals in Groups 1A, 2A, and 3A form.... ions and there charge is |
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| -equal to the group number of the element. |
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| Nonmetals in Groups 5A, 6A, and 7A form....ions and there charge is |
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| -equal to 8 minus the group number of the element. |
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| CN2- |
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| -Cyanide |
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| CH3CO2- |
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| -Acetate |
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| S2O3^2- |
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| -Thiosulfate |