Quantum/Mechanical Model – Flashcards

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The vertical height of a wave is called
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amplitude
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The number of cycles that pass through a stationary point is called
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frequency
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Place the following types of electromagnetic radiation in order of increasing wavelength. ultraviolet light gamma rays radio wave
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gamma rays < ultraviolet light < radio waves
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) Place the following types of electromagnetic radiation in order of decreasing energy. ultraviolet light radio waves microwaves
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ultraviolet light > microwaves > radio waves
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On the electromagnetic spectrum, visible light is immediately between two other wavelengths. Name them.
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infrared and ultraviolet
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Identify the color that has a wavelength of 700 nm.
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red
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Identify the color that has a wavelength of 460 nm.
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blue
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9) Which of the following visible colors of light has the highest frequency?
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red
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Which of the following colors of electromagnetic radiation has the shortest wavelength?
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violet
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Which of the following types of electromagnetic radiation has the lowest frequency?
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orange
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Calculate the wavelength (in nm) of a the red light emitted by a neon sign with a frequency of 4.74 × 1014 Hz.
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633 nm
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A sunburn is caused by overexposure to __________ radiation.
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ultraviolet
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Food can be cooked by __________ radiation.
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microwave
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When waves of equal amplitude from two sources are out of phase when they interact, it is called __________.
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destructive interference
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Calculate the wavelength (in nm) of the blue light emitted by a mercury lamp with a frequency of 6.88 × 1014 Hz.
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436 nm
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Which of the following occur as the energy of a photon increases?
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the wavelength gets shorter.
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Which of the following occur as the wavelength of a photon increases?
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the frequency decreases
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Calculate the frequency of the red light emitted by a neon sign with a wavelength of 659.9 nm.
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4.55 × 1014 s-1
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Calculate the energy of the green light emitted, per photon, by a mercury lamp with a frequency of 5.49 × 1014 Hz.
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3.64 × 10-19 J
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Calculate the energy of the orange light emitted, per photon, by a neon sign with a frequency of 4.89 × 1014 Hz.
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3.24 × 10-19 J
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Calculate the frequency of the green light emitted by a hydrogen atom with a wavelength of 486.1 nm.
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6.17 × 1014 s-1
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Calculate the energy of the red light emitted by a neon atom with a wavelength of 703.2 nm.
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2.83 × 10-19 J
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Calculate the energy of the violet light emitted by a hydrogen atom with a wavelength of 410.1 nm.
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4.85 × 10-19 J
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How many photons are contained in a burst of yellow light (589 nm) from a sodium lamp that contains 609 kJ of energy
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1.80 × 1024 photons
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How many photons are contained in a flash of green light (525 nm) that contains 189 kJ of energy?
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4.99 × 1023 photons
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How much energy (in kJ) do 3.0 moles of photons, all with a wavelength of 655 nm, contain?
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548 kJ
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Determine the shortest frequency of light required to remove an electron from a sample of Ti metal, if the binding energy of titanium is 3.14 × 103 kJ/mol.
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7.87 x 1015 Hz
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What total energy (in kJ) is contained in 1.0 mol of photons, all with a frequency of 2.75 × 1014 Hz?
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10 kJ
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Determine the longest wavelength of light required to remove an electron from a sample of potassium metal, if the binding energy for an electron in K is 1.76 × 103 kJ/mol.
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68.0 nm
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Identify the color of a flame test for potassium.
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violet
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Identify the color of a flame test for sodium.
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yellow
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Which of the following statements is TRUE?
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All of the above are true.
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Calculate the wavelength of an electron (m = 9.11 × 10-28 g) moving at 3.66 × 106 m/s.
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1.99 × 10-10 m
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Calculate the wavelength of a baseball (m = 155 g) moving at 32.5 m/s.
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1.32 × 10-34 m
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Determine the velocity of a marble (m = 8.66 g) with a wavelength of 3.46 × 10-33 m.
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22.1 m/s
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Determine the velocity of a medicine ball (m = 10.0 kg) with a wavelength of 1.33 × 10-35 m.
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4.98 m/s
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Determine the mass of a ball with a wavelength of 3.45 x 10-34 m and a velocity of 6.55 m/s.
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293 g
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Determine the mass of a ball with a velocity of 35.1 m/s and a wavelength of 8.92 x 10-34 m.
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21.2 g
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It is possible to determine the ionization energy for hydrogen using the Bohr equation. Calculate the ionization energy for an atom of hydrogen, making the assumption that ionization is the transition from n=1 to n=∞.
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+2 .18 × 10-18 J
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Which of the following transitions (in a hydrogen atom) represent emission of the longest wavelength photon?
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n = 5 to n = 4
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Which of the following transitions (in a hydrogen atom) represent absorption of the smallest frequency photon?
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n = 5 to n = 6
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Choose the transition (in a hydrogen atom) below that represents the absorption of the shortest wavelength photon.
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n = 1 to n = 2
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Which of the following transitions represent the emission of a photon with the largest energy?
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n = 3 to n = 1
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For n = 3, what are the possible sublevels?
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0, 1, 2
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What are the possible orbitals for n = 3?
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s, p, d
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What value of l is represented by a d orbital?
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2
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Each of the following sets of quantum numbers is supposed to specify an orbital. Which of the following sets of quantum numbers contains an error?
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n = 3, l =3 , ml = -2
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Each of the following sets of quantum numbers is supposed to specify an orbital. Choose the one set of quantum numbers that does not contain an error.
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n = 4, l = 3, ml =-2
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How many orbitals are contained in the third principal level (n=3) of a given atom?
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9
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How many sublevels are contained in the second shell (n=2) of a given atom?
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2
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Which of the following statements is TRUE?
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Atoms are roughly spherical because when all of the different shaped orbitals are overlapped, they take on a spherical shape
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Which of the following quantum numbers describes the shape of an orbital?
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angular momentum quantum number
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Which of the following quantum numbers describes the orientation of an orbital?
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magnetic quantum number
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Which of the following quantum numbers describes the size and energy of an orbital?
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principal quantum number
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How many different values of ml are possible in the 4f sublevel?
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7
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How many different values of l are possible in the third principal level?
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3
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How many different values of ml are possible in the 3d sublevel?
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5
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How many different values of ml are possible in the 2p sublevel?
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3
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Give all possible values of l for a 3 sublevel.
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0, 1, 2
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Give the value of l for a 3p sublevel.
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1
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Identify the correct values for a 1s sublevel.
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n = 1, l = 0, ml = 0
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Identify the correct values for a 2p sublevel.
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n = 2, l = 1, ml = 0
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Identify the correct values for a 3p sublevel.
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n = 3, l = 1, ml = 0
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Identify the correct values for a 4f sublevel.
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n = 4, l = 3, ml = -2
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If two electrons in the same atom have the same value of "l", they are
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in the same sublevel, but not necessarily in the same level.
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In which orbital below would an electron (on average) be farthest from the nucleus?
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4f
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In which orbital below would an electron (on average) be closest to the nucleus?
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2s
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Determine the energy change associated with the transition from n=2 to n=5 in the hydrogen atom.
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+4.58 × 10-19 J
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Determine the energy change associated with the transition from n=3 to n=2 in the hydrogen atom.
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-3.03 × 10-19 J
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Calculate the energy change associated with the transition from n=4 to n=1 in the hydrogen atom.
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-2.04 × 10-18 J
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Which of the following statements is TRUE?
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The magnetic quantum number (ml) describes the orientation of the orbital.
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It is possible to determine the ionization energy for hydrogen using the Bohr equation. Calculate the ionization energy (in kJ) for a mole of hydrogen atoms, making the assumption that ionization is the transition from n=1 to n=∞.
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1.31 × 103 kJ
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Calculate the wavelength of light associated with the transition from n=1 to n=3 in the hydrogen atom
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103 nm
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Calculate the frequency of light associated with the transition from n = 2 to n = 3 in the hydrogen atom.
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4.57 × 1014 s-1
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How much energy (in kJ) is required to ionize 2.78 moles of hydrogen atoms?
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3.65 × 103 kJ
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Determine the end (final) value of n in a hydrogen atom transition, if the electron starts in n = 4 and the atom emits a photon of light with a wavelength of 486 nm.
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2
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Determine the end (final) value of n in a hydrogen atom transition, if the electron starts in n = 2 and the atom absorbs a photon of light with a frequency of 4.57 × 1014 Hz.
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3
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Determine the end (final) value of n in a hydrogen atom transition, if the electron starts in n = 1 and the atom absorbs a photon of light with an energy of 2.044 × 10-18 J.
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4
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Describe the shape of a p orbital.
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two balls
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Describe the shape of a s orbital.
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a ball
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Give the numbers for ml for a d orbital.
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-2, -1, 0, 1, 2
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What is the maximum number of s orbitals that are possible?
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1
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What is the maximum number of p orbitals that are possible?
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3
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What is the maximum number of d orbitals that are possible?
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5
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What is the maximum number of f orbitals that are possible?
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7
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Electromagnetic radiation with a wavelength of 525 nm appears as green light to the human eye. The frequency of this light is __________ s-1.
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5.71 × 1014
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An FM radio station broadcasts electromagnetic radiation at a frequency of 100.6 MHz. The wavelength of this radiation is __________ m.
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2.982
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Electromagnetic radiation with a wavelength of 525 nm appears as green light to the human eye. The energy of one photon of this light is __________ J.
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3.79 × 10-19
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Electromagnetic radiation with a wavelength of 531 nm appears as green light to the human eye. The energy of one photon of this light is 3.74 × 10-19 J. Thus, a laser that emits 1.3 × 10-2 J of energy in a pulse of light at this wavelength produces __________ photons in each pulse.
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3.5 × 1016
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The de Broglie wavelength of an electron with a velocity of 6.00 × 106 m/s is __________ m. The mass of the electron is 9.11 × 10-28 g.
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1.21 × 10-10
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What are the possible values of n and ml for an electron in a 4d orbital?
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n = 5 and ml = -2, -1, 0, +1, +2
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How many subshells are there in the shell with n = 4?
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4
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What are the possible values of l if n = 6?
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0, 1, 2, 3, 4, or 5
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9) How many orbitals are there in the fourth shell?
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16
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For a hydrogen atom, which electronic transition would result in the emission of a photon with the highest energy?
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6p → 4s
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For hydrogen, what is the wavelength of the photon emitted when an electron drops from a 4d orbital to a 2p orbital in a hydrogen atom? The Rydberg constant is 1.097 × 10-2 nm-1.
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486.2 nm
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