Sarah’s Chemistry Chapter 17 – Flashcards

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Thermochemistry
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the study of energy changes that occur during chemical reations and changes in state.
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Chemical potential energy
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the energy stored in the chemical bonds of a substance.
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Heat
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represented by q, energy that transferse from one object to another because of temperature difference between them.
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System
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the part of the universe on which you focus your attention.
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Surroundings
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everything else in the universe.
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Law of consevation of energy
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in any chemical or physical process, energy is neither created nor destroyed. 1st law of thermodynamics.
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Endothermic process
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absorbs heat from its surroundings. POSITIVE.
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Exothermic process
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realses heat to its surroundings. NEGATIVE.
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Specific heat
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the amount of heat it takes to raise the temperature of 1g of the substance 1 degree C
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Heat capacity
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the amount of heat needed to increase the temperature of an object exactly 1 degree C
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In what direction does heat flow?
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Heat always flows from a warmer object to a cooler object.
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What happens in enothermic process?
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In an enothermic process, the system gains heat as the surroundings cool down.
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What happens in exothermic process?
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In an exothermic process, the system loses heat as the surroundings heat up.
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In what units is heat flow measured?
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Heat flow is measured in two common units, the calorie and the joule.
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On what two factors does the heat capacity of an object depend?
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The heat capacity of an object depends on both its mass and its chemical composition.
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Calorimetry
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the precise measurement of the heat flow into or out of a system for chemical and physical procesesses.
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Calorimeter
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The insulated device used to measure the absorption or release of heat in chemical or physical processes.
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Enthalpy
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The heat content of a system at constant pressure is the same as a property. (H)
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Thermochemical equation
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A chemical equation that includes the enthalpy change.
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Heat of reaction
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the enthalpy change for the chemical equation exactly as it is written.
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Heat of combustion
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the heat of reaction for some complete burning of one mole of a substance.
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What basic concepts apply to calorimetry?
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In calorimetry, the heat released by the system is equal to the heat absorbed by its surroundings. Conversely, the heat absorbed by a system is equal to the heat relased by its surrounding.
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How can you express the enthalphy change for a reaction in a chemical equation?
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In a chemical equation, the enthalpy change for the reaction can be written as either a reactant or a product.
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Molar heat of fusion
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The heat absorbed by one mole of a solid substance as it melts to a liquid at a constant temperature.
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Molar heat of solidification
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The heat lost when one mole of a liquid solidifies at a constant temperature.
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Molar heat of vaporization
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The amount of heat necessary to vaporize one mole of a given liquid.
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Molar heat of condensation
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The amount of heat released when 1 mol of vapor condenses at the normal boiling point.
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Molar heat of solution
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The enthalpy change cause by dissolution of one mole of substance.
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How does the quantity of heat absorbed by a melting solid compare to the quantity of heat released when th eliquid solidifies?
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The quantity of heat absorbed by a melting solid is exactly the same as the quantity of heat released when the liquid solidifies, that is ......
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How does the quantity of heat absorbed by a vaporizing liquid compare to the quantity of heat released when the vapor condenses?
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The quanity of heat absorbed by a vaporizing liquid is exactly the same as the quantity of heat released when the vapor condenses, that is ..............
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What thermochemical changes can occur when a solution forms?
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During the formation of a solution, heat is either released or absorbed.
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