chpt 12 biochem – Flashcards
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The standard free energy change for the hydrolysis of ATP to ADP and inorganic phosphate (Pi) is about -30 kJ/mol but in the red blood cell the actual free energy change for this reaction is about -52 kJ/mol. This means that:
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The concentration of ATP is greater than the product of the concentrations of ADP and Pi.
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Which of the following is FALSE for catabolic pathways?
They extract usable chemical energy from fuel molecules.
They are oxidative.
They generate ATP.
They generate oxidized enzyme cofactors.
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They generate oxidized enzyme cofactors.
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Biological oxidation-reduction reactions always involve
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transfer of electrons
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what is the common requirement in all anabolic pathways
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energy
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T or F: The hydrolysis of phosphoanhydride bonds in ATP releases large amounts of free energy.
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T
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Which of the following terms accurately describes enzyme-catalyzed pathways that yield energy and breakdown complex molecules to simpler precursors?
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catabolic pathways
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T or F: A coupled reaction in which one reaction is endergonic and one is exergonic will proceed as long as the overall pathway is exergonic.
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True
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T or F: Metabolism is the overall process through which living systems acquire and use free energy to carry out various functions.
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True
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T or F: The equilibrium constant can be calculated from standard state free energy data.
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True Because ∆G¡ = RTlnKeq
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Energy is generated during _____, the breakdown of larger molecules into smaller while energy is consumed during _____, the building of larger molecules from smaller ones.
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catabolic reactions; anabolic reactions
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When ΔG >>0:
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Reaction is not spontaneous.
Reaction is unfavorable.
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When ΔG<<0:
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Reaction is spontaneous.
Reaction is favorable.
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The three destinations for absorbed monosaccharides
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1.Immediate usage through
glycolysis
2. Synthesis of glycogen in the
liver and muscle
3. Turned into fat for energy storage