Organic Carey 7 -Chapter 14

Carbanion

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Organolithium Reactions

[image]

Lithium Dialkylcuprates
[image]
Organolithiums to Alcohols
[image]
Iodomethylzinc Iodide
[image]
Grignard Reaction

RX + Mg → RMgX

 

 [image] + Mg [image] [image]

 

Grignard Reagents
[image]
Grignard Reagents with Carbonyl Compounds

[image] -Et2O, H+->[image]

Grignards with Esters
[image]
Grubbs’ Catalyst

[image]

;

[Ru]

Ring-Closing Metathesis

[image]-[Ru],CH2Cl2-;[image]

;

Acetylenic Alcohol Synthesis

[image]-1.NH3, 2.H+-; [image]

Sodium Acetylide
NaC=CH
Alkanes from Lithium Dialkylcuprates
[image];-Et2O-; [image]
Simmons-Smith Reaction

[image]-CH2I2, Zn(Cu); Et2O-; [image]

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