General Chemistry 131 – Flashcards

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Chemistry
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the study of matter and its properties, the changes that matter undergoes, and the energy associated with those changes
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matter
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anything that has mass and volume
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composition
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the types and amounts of simpler substances that make something up
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properties
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characteristics that give each substance its unique identity
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physical properties
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characteristics a substance shows by itself, without changing into or interacting with another substance
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physical change
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occurs when a substance alters its physical properties not its composition

same substance before and after
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chemical properties
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characteristics a substance shows as it changes into or interacts with another substance or substances
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chemical change is also called a
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chemical reaction
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chemical change
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occurs when a substance or substances is converted into a differenet substance

different substance before and after
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solid are not defined by
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rigidity or hardness
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liquid shape
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conforms to the container's shape
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liquid surface
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an upper surface
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gas shape
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conforms to the container's shape
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gas surface
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gas does not have a surface
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in a solid, the particles lie
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next to each other in a regular, three- dimensional array
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in a liquid, the particles lie
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close together but move randomly around each other
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in a gas, the particles
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have large distances between them and move randomly throughout the container
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a physical change caused by eating can generally be
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reversed by cooling
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composition ultimately depends on
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the makeup of substances at the atomic scale
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we study observable changes in matter in order to
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undertand their unobservable causes
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energy
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the ability to do work
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the total energy an object possesses is
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the sum of its potential energy and its kinetic energy
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potential energy
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is the energy due to the position of the object relative to other objects
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kinetic energy
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is the energy due to the motion of the object
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when energy is converted from one form to another, it is
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conserved, not destroyed
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situations of lower energy are more
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stable
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situations of ____ energy are favored
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low
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due to electrostatic forces
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opposite charges attract each other and like charges repel each other
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changes in matter are accompanied by
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changes in energy
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scientific method steps
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observation
hypothesis
experiment
model
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data
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pieces of quantitative information
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natural law
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when the same observation is made by many investigators in many situations with no clear exceptions
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observation that mass remains constant during chemical change
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law of mass conservation
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credited with the law of mass conservation
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Antonie Lavoisier
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hypothesis
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proposal made to explain an observation
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hypothesis must be
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testable by experimentation
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variables
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quantities that can have more than one value
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controlled experiment
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measures the effect of one variable on another while keeping all other variables constant
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1 mile = ____ ft
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5280 ft
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mass
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kilogram (kg)
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length
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meter (m)
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time
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seconds (s)
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temperature
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kelvin (K)
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electric current
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ampere (A)
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amount of substances
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moles (mol)
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1 L= _____ mL
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1000 mL
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1 m = _____ cm
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100 cm
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1 kg = _____ g
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1000 g
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1 g = ___ mg
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1000 mg
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mass
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quantity of matter an object contains
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mass is constant because
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an object's quantity of matter cannot change
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weight is variable because
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it depends on the local gravitational field
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density =
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mass / volume
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mass =
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volume x density
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volume =
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mass x (1 / density)
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density of water
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0.998 g/cm^3
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temperature
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measure of how hot or cold one object is relative to another
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heat
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the energy that flows from the object with the higher temperature to the object with the lower temperature
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T in K = _____ T in *C
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*C + 273.15
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T in *C = ______ T in K
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T in K - 273.15
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extensive properties
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variables dependent on the amount of substance present
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intensive properties
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independent of the amount of substance
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every measurement includes come
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uncertainty
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all digits are significant except
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zeros use only to position the decimal point
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sig figs for multiplication and division
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fewest number of sig figs
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sig figs for addition and subtraction
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fewest decimal places
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precision
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how close the measurement in a series are to each other
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accuracy
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how close the measurement is to the actual value
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precise measurements have low
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random errors
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accurate measurements have low
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systematic errors and low random errors
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calibration
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comparing the measuring device with a known standard
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precision
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how close the measurement in a series are to each other
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systematic error
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produces values that are either all higher or all lower than the actual value
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random error
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produces values that are higher and lower than the actual value
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precise measurements have _____ error
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low random error
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accurate measurements have _____ error
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low systematic and low random error
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substance
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matter whose composition is fixed
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element
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simplest kind of matter with unique physical and chemical properties
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elements consist of
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only one kind of atom
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molecule
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independent structure of two or more atoms bound together
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compound
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consists of two or more different elements that are bound chemically
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elements are present in compounds in
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fixed parts by mass
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the properties of a compound are
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different from the properties of its component elements
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mixture consists of
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two or more substances that are physically intermingled
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a mixture is not
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a substance
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the components of a mixture can
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vary in their parts by mass
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a mixture retains
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many of the properties of its components
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law of mass conservation
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the total mass of substances does not change during the chemical reaction
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the law of definite composition
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no matter what its source, a particular compound is composed of the same elements in the same parts (fractions) by mass
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fraction by mass (mass fraction)
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the part of the compound's mass that each element contributes
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percent by mass (mass recent)
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is the fraction by mass expressed as a percent (multiplied by 100)
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mass of element in sample =
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(mass of compound in sample)x(mass of element in compound/mass of compound)
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law of multiple proportions
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if elements A and B react to form two compounds, the different masses of B that combine with a fixed mass of A can be expresses as a ratio of small whole numbers
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atoms
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tiny indivisible particles of an element than cannot be created or destroyed
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postulates of the atomic theory
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1) all matter consists of atoms
2) atoms of an element cannot be converted into atoms of another element
3) atoms of an element are identical in mass and other properties and are different from atoms of any other element
4) compounds result from the chemical combination of a specific ratio of atoms of different elements
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who discovered the atomic theory
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dalton
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cathode rays were given their name because
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the rays originated at the negative electrode (cathode) and moved to the positive electrode (anode)
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mass/ charge ratio of an electron was discovered by
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JJ Thomson
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charge of the electron was discovered by
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Robert Millikan
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an atom is electronically
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neutral
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the nucleus of an atom is
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positively charged
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the number of protons in the nucleus is equal to the
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number of electrons surrounding the nucleus
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atomic number (Z)
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equal the number of protons in the nucleus of each of its atoms
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mass number (A)
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the total number of protons and neutrons in the nucleus of each atom
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atomic symbol (element symbol)
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based on the English Latin, or Greek name, such as C for Carbon
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atomic number often written as a
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left subscript
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mass number often written as a
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left superscript
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number of neutrons=
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mass number - atomic number
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all atoms of an element have the same _____, but not the same ______
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atomic number, mass number
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isotopes
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are atoms in an element, that have different numbers of neutrons and therefore different mass number
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atomic mass unit (amu)
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is 1/12 the mass of a carbon-12 atom
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the isotope makeup of an element is determined by
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mass spectrometry
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mass spectrometry
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a method for measuring the relative masses and abundances of atomic-scale particles and molecules, very precisely
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atomic mass (atomic weight)
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the average of the masses of its naturally occurring isotopes weighted according to their abundances
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who published the original periodic table of elements
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Dmitri Mendeleev
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periodic table arranged according to
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increasing atomic numbers
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horizontal rows
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periods
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vertical columns
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groups
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the eight A groups contain
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the main group elements
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the ten B groups contain
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the transition elements
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metals lie where on the periodic table
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in the lower left portion
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nonmetals lie where on the periodic table
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in the small upper right portion
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metalloids lie where on the periodic table
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along the staircase line
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elements in a group have
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similar chemical properties
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elements in a period have
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different chemical properties
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Group 1A
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except hydrogen, alkali metals
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Group 2A
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alkaline earth metals
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Group A7
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Halogens
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ionic compounds
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transferring electrons from one element to another to form a bond
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covalent compounds
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sharing electrons between two atoms of different elements to form a bond
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chemical bonds
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forces that hold atoms together in a compound
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ionic compounds are composed of
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ions
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ions
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charged particles that form when an atom gains or loses one or more electrons
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binary ionic compounds
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simplest type of ionic compound
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cation
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metal ion that loses one or more electrons and becomes a positively charged ion
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anion
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nonmetal gains one or more electrons and becomes a negatively charged ion
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monoatomic ion
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cation or anion derived from a single atom
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coulomb's law
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the energy of attraction (or repulsion) between two particles is directly proportional to the product of the charges and inversely proportional to the distance between them
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energy = (charge 1 x charge 2)/ distance
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ions with higher charges
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attract (or repel) each other more strongly than ions with lower charges
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smaller ions
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attract (or repel) each other more strongly than larger ions, because their charges are closer together
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ionic compounds are
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neutral
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covalent bond
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a pair of electrons mutually attracted by the two nuclei
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most covalent substances consist of
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molecules
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polyatomic ions consist of
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two or more atoms bonded covalently and have a net positive or negative charge
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chemical formulas show
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the type and number of each atom in the smallest unit of the substance
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formula unit
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the relative numbers of cations and anions in the compound
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Cr3+
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Chromium (III)
Chromic
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Cu+
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copper (I)
cuprous
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Cu2+
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copper (II)
cupric
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Fe2+
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iron (II)
ferrous
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Fe3+
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iron (III)
ferric
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Pb2+
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lead (II)
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Hg2+
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mercury (II)
mercuric
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Sn2+
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tin (II)
stannous
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suffix -ous for the ion with the
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lower charge
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suffix -ic for the ion with the
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higher charge
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binary covalent compound are typically formed by
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the combination of two nonmetals
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molecular mass =
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sum of atomic masses
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molecular formula
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uses element symbols and numerical subscripts to give the actual number of atoms of each element in a molecule of the compound
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H2O is an example of a
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molecular formula
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structural formula
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shows the relative placement and connections of atoms in the molecule
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H:O:H is an example of
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structural formula
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H-O-H is an example of
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structural formula
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heterogeneous mixture
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has one or more visible boundaries between the components; it is not uniform
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homogeneous mixture
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has no visible boundaries because the component are individual atoms, ions, or molecules; it is uniform
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another name for a homogeneous mixture
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solution
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mixtures differ from compounds in three different ways
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1) proportions of the components can vary
2) individual properties of the components are observable
3) components can be separated by physical means
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properties
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the characteristics that give each substance its unique identity
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kinetic molecular theory of matter
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all matter consists of tiny particles, which are in constant motion
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scientific method
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observations, hypothesis, experiment, model
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when conducting an experiment always have a
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control
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1 km =
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1000 m
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1 m =
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1 x 10^9 nm
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1 L =
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1000 mL
10 dL
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1 kg =
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1000g
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1 g =
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1000 mg
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error =
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experimental value- accepted value
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percent error =
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(experimental value/ accepted value) x 100
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standard deviation =
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(SQRT( sum of differences/ ( # or trials -1))
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calcagens
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'stinky elements'
sulfur, selenium
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nobel gases have a
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full outer valence shell and don't form bonds
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# protons =
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atomic #
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# neutrons =
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total # - atomic #
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# electrons = same # as protons
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molar ratio how to
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divide each number of moles by the smallest number of moles calculated
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avagadro's number
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6.022 x 10^23
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the molar mass is the
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mass in grams of one mole of any element
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how many molecules in one mole of a substance
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6.022 x 10 ^23
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Anything that has mass and volume
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matter
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Simpler substances that make up matter
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composition
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Type of matter that has a defined, fixed composition
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substance
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The characteristics that give each substance its unique identity.
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properties
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examples of physical changes
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Making ice cubes
Boiling water
Dissolving sugar into water
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examples of chemical changes
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2H2(gas) + O2(gas) ------> H2O
Burning wood
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gas particles
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total disorder
much empty space
particles have complete freedom of motion
particles are far apart
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liquid particles
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disorder
particles are free to move relative to each other
particles are close together
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solid particles
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ordered arrangement
particles are essentially in fixed positions
particles are close together
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qualitative and quantitative data
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observations
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A tentative explanation or prediction based on experimental observations
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hypothesis
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clear set of steps that test the hypothesis. Consist of variables and controls
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experiment
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formulating theories based on experiments. Can be used to make predictions about related phenomena
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model
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laws
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A concise verbal or mathematical statement of a behavior or a relation that is consistently observed in nature without contradiction
Allows scientists to make new predictions
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theory
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Well-tested, unifying principle that explains a body of facts and the laws based on them
Sometimes used to imply a guess but to scientists, theories are based on reproducible evidence.
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1 mile = ____ km
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1.609 km
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1 inch = _____cm
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2.54 cm
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1 oz = _____ g
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28.53 g
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density =
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mass / volume
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density
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the ratio of the mass of an object to its volume
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*F = _____ *C
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(9/5)*C + 32
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K= ____ *C
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*C + 273
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the simplest type of matter with unique physical and chemical properties
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element
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matter whose composition is fixed
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substance
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independent structure consisting of two or more atoms chemically bound together
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molecule
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composed of two or more different elements that are chemically bound together
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compound
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a group of two or more substances that are physically intermingled
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mixture
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NH4+1
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ammonium
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NO2-1
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nitrite
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NO3-1
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nitrate
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SO3-2
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sulfite
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SO4-2
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sulfate
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ClO-1
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hypochlorite
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ClO2-1
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chlorite
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ClO3-1
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chlorate
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ClO4-1
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perchlorate
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MnO4-1
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permananate
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OH-1
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hydroxide
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H3O+1
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hydronium
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PO4-3
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phosphate
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CO3-2
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carbonate
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CN-1
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cyanide
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CrO4-2
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chromate
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Cr2O7-2
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dichromate
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C2H3O2-1
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acetate
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O2-2
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peroxide
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NaCl
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Sodium Chloride
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MgBr2
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Magnesium Bromide
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Extended 3-D network of an ionic solid
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Crystal Lattice
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The attraction of opposing forces and the repulsion of like forces.
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Electrostatic forces
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Binary Acids form when
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certain gases dissolve in water
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acids which contain oxygen
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oxoacids
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Mole
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The SI unit for measuring an amount of a substance
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The simplest, whole number ratio of atoms in a formula
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Empirical Formula
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Hydrated Compounds
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Compounds in which molecules of water are associated with the ions of the compounds
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Reactants
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Substances combined in the reaction, written to the left of the arrow.
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Products
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The substances produced in the reaction, written to the right of the arrow
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State of Matter
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Physical states of the reactants and products are also included in the chemical equation
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Balancing Chemical Equations
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Step 1: Write the correct formula for the reactants and products

Step 2: Balance each atom individually

Step 3: Verify that the number of atoms of each element is balanced
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Indicates the number of moles involved in the reaction
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Coefficients
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Stoichiometric Factor
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Also known as the mole ratio. A ratio of the coefficients from two molecules in the balanced equation
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Limiting Reactant
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The reactant, that limits the amount of product produced.
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Theoretical Yield
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The maximum mass of a product that can be obtained from a chemical reaction
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Actual Yield
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The actual amount of a material obtained in a laboratory experiment
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Percent Yield =
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(actual yield/ theoretical yield) x 100
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Solution
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Homogeneous mixture of two or more substances
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Solvent
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The medium in which another substances is dissolved
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Solute
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The substance that is being dissolved
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Aqueous Solutions Reactions
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Many of these reactions are exchange reactions in which the ions of the reactants change partners.
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Electrolytes
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Compounds whose solutions conduct electricity
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All ionic compounds that are soluble in water are
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Electrolytes
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Molarity
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The amount of solute in moles per liter of solution
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Molarity =
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(amount of solute (mols)/ volume of solution (liters))
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stoichometry
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the study of the quantitative aspects of formulas and reactions
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mole
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the amount of substance that contains the same number of entities as the number of atoms
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chemist's dozen
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mole
6.022 X 10^23
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molar mass (M)
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the mass per mole of its entities and has units of grams per mole
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how many molecules in a mole
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6.022 x 10^23 molecules/ mole
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from moles to atoms
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amount (mol) x (6.022 x 10^23) = number of atoms
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mass (g) to number of molecules
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mass (g) / molar mass (M) = number moles
number moles x (6.022 x 10^23) = number of molecules
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mass of element =
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mass of compound x (mass of element in 1 mol of compound/ mass of 1 mol of compound)
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empirical formula is derived from
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mass analysis
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empirical formula shows
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the lowest whole number of moles, and thus the relative number of atoms, of each element in the compound
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molecular formula shows
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the actual number of atoms of each element in a molecule
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structural formula shows
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the relative placement and connections of atoms in the molecule
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combustion analysis is used to
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measure the amounts of carbon and hydrogen in a combustible organic compound
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